Recent advances in visible light mediated photoinduced aryl radical generation and its application in synthesis

Tubai Ghosh , Sougata Santra , Grigory V. Zyryanov , Brindaban C. Ranu
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引用次数: 0

Abstract

The reactions involving aryl radicals is an efficient strategy for the synthesis of a wide variety of important molecules. We have highlighted here recent developments on the generation of aryl radicals from various substrates by visible light mediated photocatalysis and their reactions with different substrates to produce a library of arylated and het-arylated compounds. These reactions are performed at room temperature using LED bulbs. Thus, this strategy is green involving less energy.

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可见光介导光诱导芳基自由基生成及其在合成中的应用研究进展
涉及芳基自由基的反应是合成多种重要分子的有效策略。我们在此重点介绍了通过可见光介导的光催化从各种底物生成芳基自由基的最新进展,以及它们与不同底物的反应,以产生芳基化和半芳基化化合物库。这些反应是在室温下使用LED灯泡进行的。因此,这种策略是绿色的,涉及较少的能源。
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