An evidence of electron donor behavior of single-walled carbon nanotube in photo-induced electron transfer

Koji Inada, Yasuyuki Araki, Atula S.D. Sandanayaka , Osamu Ito
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Abstract

The electron transfer reaction between C60 and SWCNTs in D2O was investigated. Repeated laser irradiation of water-soluble C60 encapsulated in γ-cyclodextrin and SWCNTs with carboxymethylcellulose dispersed in D2O resulted in the accumulation of C60 anion radicals and a decrease in the E11 absorption band of SWCNTs, strongly suggesting electron transfer between C60 and SWCNTs. Transient absorption techniques revealed that this electron transfer occurred through the excited triplet of C60.

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光致电子转移中单壁碳纳米管电子给体行为的证据
研究了C60与SWCNTs在D2O中的电子转移反应。用分散在D2O中的羧甲基纤维素反复激光照射包被γ-环糊精和SWCNTs的水溶性C60,可导致C60阴离子自由基积累,SWCNTs的E11吸收带减弱,强烈提示C60和SWCNTs之间存在电子转移。瞬态吸收技术表明,这种电子转移是通过C60的激发三重态发生的。
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