Enhanced Adsorption of Bisphenol A from Aqueous Solution with 2-Vinylpyridine Functionalized Magnetic Nanoparticles.

Abstract

In this study, a novel 2-vinylpyridine functionalized magnetic nanoparticle (Mag-PVP) was successfully prepared. The prepared Mag-PVP was characterized by transmission electronic microscopy (TEM), Fourier transform infrared spectrophotometry (FT-IR), vibrating sample magnetometry (VSM) and thermogravimetric analysis (TGA), and was used for the adsorption of bisphenol A (BPA) from aqueous solutions. Mag-PVP, which is composed of Fe₃O₄ nanoparticles and poly divinylbenzene-2-vinylpyridine (with a thickness of 10 nm), exhibited magnetic properties (M_s = 44.6 emu/g) and thermal stability. The maximum adsorption capacity (Q_m) of Mag-PVP for BPA obtained from the Langmuir isotherm was 115.87 mg/g at 20 °C, which was more than that of Fe₃O₄ nanospheres. In the presence of NaCl, the improved adsorption capacity of Mag-PVP was probably attributed to the screening effect of Mag-PVP surface charge and salting-out effect. In the presence of CaCl₂ and humic acid (HA), the adsorption capacity of BPA decreased due to competitive adsorption. The adsorption of BPA by Mag-PVP increased slightly with the increase in pH from 3.0 to 5.0 and obtained the largest adsorption amount at pH 5.0, which was probably attributed to hydrogen bonding interactions. Moreover, in actual water, Mag-PVP still showed excellent adsorption performance in removing BPA. The high adsorption capacity and excellent reusability performance in this work indicated that Mag-PVP was an effective adsorbent for removing BPA from aqueous solutions.