Phenothiazines, Dihydrophenazines, and Phenoxazines: Sustainable Alternatives to Precious-Metal-Based Photoredox Catalysts.

IF 2.2 3区 化学 Q2 CHEMISTRY, ORGANIC Aldrichimica Acta Pub Date : 2019-01-01
Daniel A Corbin, Chern-Hooi Lim, Garret M Miyake
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Abstract

The application of photoredox catalysis to atom-transfer radical polymerization (ATRP) has resulted in the development of strongly reducing organic photoredox catalysts (PCs) that are some of the most reducing catalysts known. The objectives of this review are to highlight these PCs with regard to their development and applications in polymer and organic synthesis, as well illuminate aspects of these PCs that remain to be studied further.

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吩噻嗪、二氢吩嗪和吩恶嗪:贵金属基光氧化还原催化剂的可持续替代品。
光氧化还原催化在原子转移自由基聚合(ATRP)中的应用已经导致了强还原性有机光氧化还原催化剂(PC)的开发,这些催化剂是已知的还原性最强的催化剂之一。本综述的目的是强调这些PC在聚合物和有机合成中的发展和应用,并阐明这些PC有待进一步研究的方面。
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来源期刊
Aldrichimica Acta
Aldrichimica Acta 化学-有机化学
CiteScore
7.60
自引率
0.00%
发文量
0
期刊介绍: For over 50 years, the Aldrichimica Acta has been a leading, open-access, international forum for the frontiers of chemical research. It publishes topical and insightful reviews, written by prominent chemists from around the world and covering a variety of topics usually based on a synthetic theme in organic, organometallic, and bio-organic chemistry.
期刊最新文献
Phenothiazines, Dihydrophenazines, and Phenoxazines: Sustainable Alternatives to Precious-Metal-Based Photoredox Catalysts. Photocatalytic C-F Reduction and Functionalization. Catalytic C-C Bond Formation and the Hendricksonian Ideal: Atom- and Redox-Economy, Stereo- and Site-Selectivity. "Designer"-Surfactant-Enabled Cross-Couplings in Water at Room Temperature. Asymmetric N-Heterocyclic Carbene (NHC) Catalyzed Acyl Anion Reactivity.
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