Evaluation of Lead (Pb(II)) Removal Potential of Biochar in a Fixed-bed Continuous Flow Adsorption System.

IF 2.4 Q1 Medicine Journal of Health and Pollution Pub Date : 2020-12-07 eCollection Date: 2020-12-01 DOI:10.5696/2156-9614-10.28.201210
Pushpita Kumkum, Sandeep Kumar
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引用次数: 3

Abstract

Background: Lead (Pb(II)) exposure from drinking water consumption is a serious concern due to its negative health effect on human physiology. A commercially available filter uses the adsorption potential of activated carbon for removing heavy metals like Pb(II). However, it has some constraints since it uses only surface area for the adsorption of these contaminants. Biochar produced via slow pyrolysis of biomass shows the presence of oxygen-containing functional groups on its surface that take part in the adsorption process, with higher removal potential compared to activated carbon.

Objectives: The current study examined the adsorption kinetics and mechanisms of Pb(II) removing potential of biochar from water using a fixed-bed continuous flow adsorption system.

Methods: The effect of initial Pb(II) concentration, mass of adsorbent (bed depth), and flow rate on adsorption potential were evaluated. The Adams-Bohart model, Thomas model, and Yoon-Nelson model were applied to the adsorption data.

Results: The maximum removal efficiency of Pb(II) was 88.86 mg/g. The result illustrated that the Yoon-Nelson model is the best fit to analyze the adsorption phenomena of Pb(II) in a fixed-bed biochar column.

Conclusions: The breakthrough data obtained from this study can be utilized to design a point of use filter that would be able to effectively remove Pb(II) from drinking water.

Competing interests: The authors declare no competing financial interests.

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生物炭在固定床连续流吸附系统中去除铅(Pb(II))的潜力评价。
背景:饮用水中的铅(Pb(II))暴露由于其对人体生理健康的负面影响而受到严重关注。市售过滤器利用活性炭的吸附势去除重金属,如铅(II)。然而,它有一些限制,因为它只使用表面积来吸附这些污染物。通过生物质缓慢热解产生的生物炭,其表面存在含氧官能团参与吸附过程,与活性炭相比具有更高的去除潜力。目的:研究生物炭在固定床连续流吸附系统中的吸附动力学和去除水中铅(II)的机理。方法:考察Pb(II)初始浓度、吸附剂质量(床层深度)、流速对吸附势的影响。吸附数据采用Adams-Bohart模型、Thomas模型和Yoon-Nelson模型。结果:对Pb(II)的最大去除率为88.86 mg/g。结果表明,Yoon-Nelson模型最适合于分析固定床生物炭柱对Pb(II)的吸附现象。结论:本研究获得的突破性数据可用于设计一种能够有效去除饮用水中铅(II)的使用点过滤器。利益竞争:作者声明没有经济利益竞争。
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来源期刊
Journal of Health and Pollution
Journal of Health and Pollution Medicine-Public Health, Environmental and Occupational Health
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审稿时长
18 weeks
期刊介绍: The Journal of Health and Pollution (JH&P) was initiated with funding from the European Union and World Bank and continues to be a Platinum Open Access Journal. There are no publication or viewing charges. That is, there are no charges to readers or authors. Upon peer-review and acceptance, all articles are made available online. The high-ranking editorial board is comprised of active members who participate in JH&P submissions and editorial policies. The Journal of Health and Pollution welcomes manuscripts based on original research as well as findings from re-interpretation and examination of existing data. JH&P focuses on point source pollution, related health impacts, environmental control and remediation technology. JH&P also has an interest in ambient and indoor pollution. Pollutants of particular interest include heavy metals, pesticides, radionuclides, dioxins, polychlorinated biphenyls (PCBs), polycyclic aromatic hydrocarbons (PAHs), volatile organic compounds (VOCs), air particulates (PM10 and PM2.5), and other severe and persistent toxins. JH&P emphasizes work relating directly to low and middle-income countries, however relevant work relating to high-income countries will be considered on a case-by-case basis.
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