Chemical Speciation and Potential Mobility of Heavy Metals in Forest Soil Near Road Traffic in Hafir, Algeria.

IF 2.4 Q1 Medicine Journal of Health and Pollution Pub Date : 2021-05-28 eCollection Date: 2021-06-01 DOI:10.5696/2156-9614-11.30.210614
Fatima Zahra Benhachem, Djamila Harrache
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Abstract

Background: Different fractions of metals, of varying origin and reactivity, are present in sediments of forest soil. Forest ecosystems are privileged sites for the deposition of persistent organic pollutants carried by the atmosphere.

Objectives: The present study describes the current state of metallic contamination around the Hafir forest, located southwest of Tlemcen, Algeria, based on analysis of total sediment mineralization and the speciation of each metal to examine the effects of emissions due to road traffic.

Methods: The distribution and migration of ten heavy metals were studied, including cadmium (Cd), nickel (Ni), cobalt (Co), chromium (Cr), manganese (Mn), lead (Pb), copper (Cu), zinc (Zn), iron (Fe), and silver (Ag), and four major elements: potassium (K), sodium (Na), magnesium (Mg), and calcium (Ca) in the superficial horizon of forest soil (0-20 cm) at different road distances (0-1700 m), in two sampling campaigns in the dry and wet seasons around the Hafir forest, Algeria.

Results: Bioavailability appears to be relatively low due to the small amount of metals present in the carbonate fraction and the alkaline pH. The impact of road traffic was observed in the variability of the concentrations of several trace elements in forest soil, such as Co, Mn, Ni, Zn, Pb, Ag, Cd. They were generally observed at very high levels along the roadside due to dry atmospheric deposition.

Conclusions: The high levels of metals in the carbonate, reducible and residual phases indicate a direct influence on the environment stemming from road traffic near the forest as well as contamination from rainfall in the area.

Competing interests: The authors declare no competing financial interests.

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阿尔及利亚哈菲尔公路交通附近森林土壤中重金属的化学成分和潜在流动性。
背景:森林土壤沉积物中含有不同种类的金属,其来源和反应性各不相同。森林生态系统是大气携带的持久性有机污染物沉积的理想场所:本研究介绍了位于阿尔及利亚特莱姆森西南部的哈菲尔森林周围的金属污染现状,通过分析沉积物的总矿化度和每种金属的种类,研究道路交通排放的影响:研究了十种重金属的分布和迁移情况,包括镉 (Cd)、镍 (Ni)、钴 (Co)、铬 (Cr)、锰 (Mn)、铅 (Pb)、铜 (Cu)、锌 (Zn)、铁 (Fe) 和银 (Ag) 以及四种主要元素:在阿尔及利亚哈菲尔森林周围的旱季和雨季进行的两次取样活动中,对不同道路距离(0-1700 米)的森林土壤表层(0-20 厘米)中的钾(K)、钠(Na)、镁(Mg)和钙(Ca)进行了分析。结果显示由于碳酸盐部分含有少量金属,且 pH 值为碱性,因此生物利用率相对较低。道路交通的影响体现在森林土壤中几种微量元素浓度的变化上,如钴、锰、镍、锌、铅、银、镉。由于干燥的大气沉积,路边的微量元素含量普遍很高:结论:碳酸盐相、还原相和残留相中的高金属含量表明,森林附近的道路交通以及该地区的降雨污染对环境产生了直接影响:作者声明没有经济利益冲突。
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来源期刊
Journal of Health and Pollution
Journal of Health and Pollution Medicine-Public Health, Environmental and Occupational Health
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审稿时长
18 weeks
期刊介绍: The Journal of Health and Pollution (JH&P) was initiated with funding from the European Union and World Bank and continues to be a Platinum Open Access Journal. There are no publication or viewing charges. That is, there are no charges to readers or authors. Upon peer-review and acceptance, all articles are made available online. The high-ranking editorial board is comprised of active members who participate in JH&P submissions and editorial policies. The Journal of Health and Pollution welcomes manuscripts based on original research as well as findings from re-interpretation and examination of existing data. JH&P focuses on point source pollution, related health impacts, environmental control and remediation technology. JH&P also has an interest in ambient and indoor pollution. Pollutants of particular interest include heavy metals, pesticides, radionuclides, dioxins, polychlorinated biphenyls (PCBs), polycyclic aromatic hydrocarbons (PAHs), volatile organic compounds (VOCs), air particulates (PM10 and PM2.5), and other severe and persistent toxins. JH&P emphasizes work relating directly to low and middle-income countries, however relevant work relating to high-income countries will be considered on a case-by-case basis.
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