{"title":"Chemical Speciation and Potential Mobility of Heavy Metals in Forest Soil Near Road Traffic in Hafir, Algeria.","authors":"Fatima Zahra Benhachem, Djamila Harrache","doi":"10.5696/2156-9614-11.30.210614","DOIUrl":null,"url":null,"abstract":"<p><strong>Background: </strong>Different fractions of metals, of varying origin and reactivity, are present in sediments of forest soil. Forest ecosystems are privileged sites for the deposition of persistent organic pollutants carried by the atmosphere.</p><p><strong>Objectives: </strong>The present study describes the current state of metallic contamination around the Hafir forest, located southwest of Tlemcen, Algeria, based on analysis of total sediment mineralization and the speciation of each metal to examine the effects of emissions due to road traffic.</p><p><strong>Methods: </strong>The distribution and migration of ten heavy metals were studied, including cadmium (Cd), nickel (Ni), cobalt (Co), chromium (Cr), manganese (Mn), lead (Pb), copper (Cu), zinc (Zn), iron (Fe), and silver (Ag), and four major elements: potassium (K), sodium (Na), magnesium (Mg), and calcium (Ca) in the superficial horizon of forest soil (0-20 cm) at different road distances (0-1700 m), in two sampling campaigns in the dry and wet seasons around the Hafir forest, Algeria.</p><p><strong>Results: </strong>Bioavailability appears to be relatively low due to the small amount of metals present in the carbonate fraction and the alkaline pH. The impact of road traffic was observed in the variability of the concentrations of several trace elements in forest soil, such as Co, Mn, Ni, Zn, Pb, Ag, Cd. They were generally observed at very high levels along the roadside due to dry atmospheric deposition.</p><p><strong>Conclusions: </strong>The high levels of metals in the carbonate, reducible and residual phases indicate a direct influence on the environment stemming from road traffic near the forest as well as contamination from rainfall in the area.</p><p><strong>Competing interests: </strong>The authors declare no competing financial interests.</p>","PeriodicalId":52138,"journal":{"name":"Journal of Health and Pollution","volume":"11 30","pages":"210614"},"PeriodicalIF":2.4000,"publicationDate":"2021-05-28","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8276720/pdf/","citationCount":"0","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"Journal of Health and Pollution","FirstCategoryId":"1085","ListUrlMain":"https://doi.org/10.5696/2156-9614-11.30.210614","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"2021/6/1 0:00:00","PubModel":"eCollection","JCR":"Q1","JCRName":"Medicine","Score":null,"Total":0}
引用次数: 0
Abstract
Background: Different fractions of metals, of varying origin and reactivity, are present in sediments of forest soil. Forest ecosystems are privileged sites for the deposition of persistent organic pollutants carried by the atmosphere.
Objectives: The present study describes the current state of metallic contamination around the Hafir forest, located southwest of Tlemcen, Algeria, based on analysis of total sediment mineralization and the speciation of each metal to examine the effects of emissions due to road traffic.
Methods: The distribution and migration of ten heavy metals were studied, including cadmium (Cd), nickel (Ni), cobalt (Co), chromium (Cr), manganese (Mn), lead (Pb), copper (Cu), zinc (Zn), iron (Fe), and silver (Ag), and four major elements: potassium (K), sodium (Na), magnesium (Mg), and calcium (Ca) in the superficial horizon of forest soil (0-20 cm) at different road distances (0-1700 m), in two sampling campaigns in the dry and wet seasons around the Hafir forest, Algeria.
Results: Bioavailability appears to be relatively low due to the small amount of metals present in the carbonate fraction and the alkaline pH. The impact of road traffic was observed in the variability of the concentrations of several trace elements in forest soil, such as Co, Mn, Ni, Zn, Pb, Ag, Cd. They were generally observed at very high levels along the roadside due to dry atmospheric deposition.
Conclusions: The high levels of metals in the carbonate, reducible and residual phases indicate a direct influence on the environment stemming from road traffic near the forest as well as contamination from rainfall in the area.
Competing interests: The authors declare no competing financial interests.
期刊介绍:
The Journal of Health and Pollution (JH&P) was initiated with funding from the European Union and World Bank and continues to be a Platinum Open Access Journal. There are no publication or viewing charges. That is, there are no charges to readers or authors. Upon peer-review and acceptance, all articles are made available online. The high-ranking editorial board is comprised of active members who participate in JH&P submissions and editorial policies. The Journal of Health and Pollution welcomes manuscripts based on original research as well as findings from re-interpretation and examination of existing data. JH&P focuses on point source pollution, related health impacts, environmental control and remediation technology. JH&P also has an interest in ambient and indoor pollution. Pollutants of particular interest include heavy metals, pesticides, radionuclides, dioxins, polychlorinated biphenyls (PCBs), polycyclic aromatic hydrocarbons (PAHs), volatile organic compounds (VOCs), air particulates (PM10 and PM2.5), and other severe and persistent toxins. JH&P emphasizes work relating directly to low and middle-income countries, however relevant work relating to high-income countries will be considered on a case-by-case basis.