Fabrication of superparamagnetic adsorbent based on layered double hydroxide as effective nanoadsorbent for removal of Sb (III) from water samples

IF 3.8 4区 工程技术 Q1 BIOCHEMICAL RESEARCH METHODS IET nanobiotechnology Pub Date : 2021-12-02 DOI:10.1049/nbt2.12074
Rokhsareh Motallebi, Ali Moghimi, Hamidreza Shahbazi, Hakim Faraji
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引用次数: 2

Abstract

In this study, the superparamagnetic adsorbent as Fe@Mg-Al LDH was synthesised by different methods with two steps for the removal of heavy metal ions from water samples. An easy, practical, economical, and replicable method was introduced to remove water contaminants, including heavy ions from aquatic environments. Moreover, the structure of superparamagnetic adsorbent was investigated by various methods including Fourier transform infrared spectroscopy, field emission scanning electron microscopy, energy-dispersive X-ray spectroscopy, and vibrating sample magnetometer. For better separation, ethylenediaminetetraacetic acid ligand was used, forming a complex with antimony ions to create suitable conditions for the removal of these ions. Cadmium and antimony ions were studied by floatation in aqueous environments with this superparamagnetic adsorbent owing to effective factors such as pH, amount of superparamagnetic adsorbent, contact time, sample temperature, volume, and ligand concentration. The model of Freundlich, Langmuir, and Temkin isotherms was studied to qualitatively evaluate the adsorption of antimony ions by the superparamagnetic adsorbent. The value of loaded antimony metal ions with Fe@Mg-Al LDH was resulted at 160.15 mg/g. The standard deviation value in this procedure was found at 7.92%. The desorption volume of antimony metal ions by the adsorbent was found to be 25 ml. The thermodynamic parameters as well as the effect of interfering ions were investigated by graphite furnace atomic absorption spectrometry.

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基于层状双氢氧化物的超顺磁吸附剂的制备及其去除水样中Sb (III)的效果
本研究采用不同的方法合成了超顺磁吸附剂Fe@Mg-Al LDH,分两步去除水样中的重金属离子。介绍了一种简单、实用、经济、可复制的去除水中污染物(包括水中重离子)的方法。采用傅里叶变换红外光谱、场发射扫描电镜、能量色散x射线能谱和振动样品磁强计等方法研究了超顺磁吸附剂的结构。为了更好的分离,采用乙二胺四乙酸配体,与锑离子形成配合物,为锑离子的去除创造适宜的条件。采用该超顺磁吸附剂对镉、锑离子在水环境中的浮选进行了研究,研究了pH、超顺磁吸附剂用量、接触时间、样品温度、体积和配体浓度等因素的影响。采用Freundlich、Langmuir和Temkin等温线模型对超顺磁吸附剂对锑离子的吸附进行了定性评价。Fe@Mg-Al LDH负载锑金属离子的值为160.15 mg/g。本方法的标准偏差值为7.92%。结果表明,该吸附剂对锑金属离子的解吸量为25 ml。采用石墨炉原子吸收光谱法考察了吸附过程的热力学参数和干扰离子的影响。
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来源期刊
IET nanobiotechnology
IET nanobiotechnology 工程技术-纳米科技
CiteScore
6.20
自引率
4.30%
发文量
34
审稿时长
1 months
期刊介绍: Electrical and electronic engineers have a long and illustrious history of contributing new theories and technologies to the biomedical sciences. This includes the cable theory for understanding the transmission of electrical signals in nerve axons and muscle fibres; dielectric techniques that advanced the understanding of cell membrane structures and membrane ion channels; electron and atomic force microscopy for investigating cells at the molecular level. Other engineering disciplines, along with contributions from the biological, chemical, materials and physical sciences, continue to provide groundbreaking contributions to this subject at the molecular and submolecular level. Our subject now extends from single molecule measurements using scanning probe techniques, through to interactions between cells and microstructures, micro- and nano-fluidics, and aspects of lab-on-chip technologies. The primary aim of IET Nanobiotechnology is to provide a vital resource for academic and industrial researchers operating in this exciting cross-disciplinary activity. We can only achieve this by publishing cutting edge research papers and expert review articles from the international engineering and scientific community. To attract such contributions we will exercise a commitment to our authors by ensuring that their manuscripts receive rapid constructive peer opinions and feedback across interdisciplinary boundaries. IET Nanobiotechnology covers all aspects of research and emerging technologies including, but not limited to: Fundamental theories and concepts applied to biomedical-related devices and methods at the micro- and nano-scale (including methods that employ electrokinetic, electrohydrodynamic, and optical trapping techniques) Micromachining and microfabrication tools and techniques applied to the top-down approach to nanobiotechnology Nanomachining and nanofabrication tools and techniques directed towards biomedical and biotechnological applications (e.g. applications of atomic force microscopy, scanning probe microscopy and related tools) Colloid chemistry applied to nanobiotechnology (e.g. cosmetics, suntan lotions, bio-active nanoparticles) Biosynthesis (also known as green synthesis) of nanoparticles; to be considered for publication, research papers in this area must be directed principally towards biomedical research and especially if they encompass in vivo models or proofs of concept. We welcome papers that are application-orientated or offer new concepts of substantial biomedical importance Techniques for probing cell physiology, cell adhesion sites and cell-cell communication Molecular self-assembly, including concepts of supramolecular chemistry, molecular recognition, and DNA nanotechnology Societal issues such as health and the environment Special issues. Call for papers: Smart Nanobiosensors for Next-generation Biomedical Applications - https://digital-library.theiet.org/files/IET_NBT_CFP_SNNBA.pdf Selected extended papers from the International conference of the 19th Asian BioCeramic Symposium - https://digital-library.theiet.org/files/IET_NBT_CFP_ABS.pdf
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