Grain growth inhibited during grain size-sensitive creep in polycrystalline ice: an energy dissipation-rate perspective

IF 1.2 4区 地球科学 Q4 MATERIALS SCIENCE, MULTIDISCIPLINARY Physics and Chemistry of Minerals Pub Date : 2022-07-02 DOI:10.1007/s00269-022-01202-9
Tess E. Caswell, Reid F. Cooper
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Abstract

Experiments in which two identical polycrystalline ice Ih specimens are simultaneously subjected to the same time–temperature history while one of the specimens is actively deformed via grain size-sensitive (GSS) creep demonstrate distinctly different microstructural evolution: for particular ranges of starting grain size and differential stress, grains do not grow in the deforming specimen. Ice Ih specimens having initial, uniform grain sizes in the range d = 6–63 μm were tested in pairs that were subjected to identical time–temperature conditions (durations t = 4–12 days; T = 240 K) but of which only one was subjected to differential stress (σ1 = 0.25–1.85 MPa; σ3 = 0). Comparing specimens within a pair, for those with coarser initial grain size, the deformed specimens exhibit suppressed or no grain growth. Our results are interpreted from the perspective of nonequilibrium thermodynamics, specifically comparing the energy dissipation rates associated with both grain growth and plastic flow: if the rate of energy dissipation associated with flow exceeds that of grain growth, the grains will not grow. An examination of the limited database on GSS flow and grain growth in silicates conforms to our analysis. The results are applied to the question of the mechanical evolution of terrestrial glaciers and to the ice-rich shells of the outer satellites.

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多晶冰晶粒尺寸敏感蠕变过程中晶粒生长受到抑制:能量耗散率的视角
实验中,两个相同的多晶冰Ih试样同时受到相同的时间-温度历史,而其中一个试样通过晶粒尺寸敏感(GSS)蠕变进行主动变形,结果显示出明显不同的微观组织演变:在特定的起始晶粒尺寸和差应力范围内,变形试样中的晶粒不生长。初始晶粒尺寸在d = 6-63 μm范围内均匀的冰Ih试样在相同的时间-温度条件下成对进行测试(持续时间t = 4-12天;T = 240 K),但其中只有一个受到差应力(σ1 = 0.25 ~ 1.85 MPa;σ3 = 0)。在一对试样中,对于初始晶粒尺寸较粗的试样,变形试样的晶粒生长受到抑制或不生长。我们的结果是从非平衡热力学的角度来解释的,具体比较了与晶粒生长和塑性流动相关的能量耗散率:如果与流动相关的能量耗散率超过晶粒生长的能量耗散率,则晶粒不会长大。对硅酸盐中GSS流动和晶粒生长的有限数据库的检查符合我们的分析。这些结果应用于陆地冰川的力学演化问题和外层卫星的富冰壳问题。
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来源期刊
Physics and Chemistry of Minerals
Physics and Chemistry of Minerals 地学-材料科学:综合
CiteScore
2.90
自引率
14.30%
发文量
43
审稿时长
3 months
期刊介绍: Physics and Chemistry of Minerals is an international journal devoted to publishing articles and short communications of physical or chemical studies on minerals or solids related to minerals. The aim of the journal is to support competent interdisciplinary work in mineralogy and physics or chemistry. Particular emphasis is placed on applications of modern techniques or new theories and models to interpret atomic structures and physical or chemical properties of minerals. Some subjects of interest are: -Relationships between atomic structure and crystalline state (structures of various states, crystal energies, crystal growth, thermodynamic studies, phase transformations, solid solution, exsolution phenomena, etc.) -General solid state spectroscopy (ultraviolet, visible, infrared, Raman, ESCA, luminescence, X-ray, electron paramagnetic resonance, nuclear magnetic resonance, gamma ray resonance, etc.) -Experimental and theoretical analysis of chemical bonding in minerals (application of crystal field, molecular orbital, band theories, etc.) -Physical properties (magnetic, mechanical, electric, optical, thermodynamic, etc.) -Relations between thermal expansion, compressibility, elastic constants, and fundamental properties of atomic structure, particularly as applied to geophysical problems -Electron microscopy in support of physical and chemical studies -Computational methods in the study of the structure and properties of minerals -Mineral surfaces (experimental methods, structure and properties)
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