Pyrene-based fluorescent chemosensor for rapid detection of water and its applications

IF 4.2 3区 生物学 Q1 BIOCHEMICAL RESEARCH METHODS Methods Pub Date : 2023-11-01 DOI:10.1016/j.ymeth.2023.10.006
Pragyan P. Dash , P. Mohanty , S. Behera , R. Behura , Bibhuti B. Palai , Bhaskar Nath , Suban K. Sahoo , Bigyan R. Jali
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Abstract

This manuscript introduces a pyrene-based Schiff base L by reacting pyrenecarboxaldehyde with 2-aminothiazole in equimolar ratio. The ligand L was characterized by various spectral data and single crystal. The water sensing ability of L was examined in different organic solvents. The weakly emissive L in DMSO showed a fluorescence enhancement upon the addition of water. The water-induced fluorescence enhancement of L was occurred due to the combined effect of aggregation-induced emission (AIE) phenomenon and suppression of photo-induced electron transfer (PET) process. Using L, the water in DMSO can be detected down to 0.50 wt% with a quantification limit of 1.52 wt%. The analytical novelty of the developed sensor L was validated by detecting moisture in a variety of raw food products.

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用于水快速检测的芘基荧光化学传感器及其应用。
本文介绍了由芘甲醛和2-氨基噻唑以等摩尔比反应制备的芘基席夫碱L。配体L通过各种光谱数据和单晶进行了表征。考察了L在不同有机溶剂中的水敏性能。DMSO中的弱发射性L在加入水后显示出荧光增强。L的水诱导荧光增强是由于聚集诱导发射(AIE)现象和光诱导电子转移(PET)过程的抑制的共同作用而发生的。使用L,DMSO中的水可以检测到0.50 wt%,定量限为1.52 重量%。通过检测各种生食品中的水分,验证了所开发的传感器L的分析新颖性。
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来源期刊
Methods
Methods 生物-生化研究方法
CiteScore
9.80
自引率
2.10%
发文量
222
审稿时长
11.3 weeks
期刊介绍: Methods focuses on rapidly developing techniques in the experimental biological and medical sciences. Each topical issue, organized by a guest editor who is an expert in the area covered, consists solely of invited quality articles by specialist authors, many of them reviews. Issues are devoted to specific technical approaches with emphasis on clear detailed descriptions of protocols that allow them to be reproduced easily. The background information provided enables researchers to understand the principles underlying the methods; other helpful sections include comparisons of alternative methods giving the advantages and disadvantages of particular methods, guidance on avoiding potential pitfalls, and suggestions for troubleshooting.
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