Intensification of the Process of Coal Ignition by Adding Biomass under Flame Combustion Conditions

IF 0.8 4区 工程技术 Q4 CHEMISTRY, MULTIDISCIPLINARY Solid Fuel Chemistry Pub Date : 2023-10-16 DOI:10.3103/S0361521923050087
A. V. Zhuikov, D. O. Glushkov, A. I. Tsepenok, A. O. Pleshko
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Abstract

The characteristics of thermal decomposition and combustion processes on the heating of fine particles (100–200 μm) of Chernogorsky coal, larch wood, and mixtures based on them, including the concentrations of the main components of flue gases (CO, CO2, NOx, and H2S + SO2), were determined using modern techniques, analytical instrumentation, and experimental equipment. The biomass contents of the fuel mixtures based on coal were 10, 20, and 30 wt %. The temperatures at which the ignition of the coke residue occurred and the combustion process was completed were established using the thermogravimetric analysis of individual solid fuels and their mixtures. Larch sawdust was more reactive than Chernogorsky coal due to the lowest temperature at which the carbon residue was ignited; therefore, the addition of even 10% biomass to coal had a positive effect on the reactivity of the mixture. Under conditions of fuel heating in a flow of air at temperatures of 500–800°C, the ignition delay times were determined using a hardware–software complex for high-speed video recording of fast processes. Based on the results of the experimental studies, it was found that the ignition delay times of the test fuels in a flow of heated air varied in a range from 0.02 to 0.22 s, and the addition of 10–30 wt % biomass to coal shortened the ignition delay times of fuel mixtures by up to 50%. The analysis of flue gases upon the combustion of solid fuels made it possible to establish the concentrations of the main anthropogenic emissions; the use of biomass as an additive to coal reduced the emissions of carbon dioxide, nitrogen oxides, and sulfur compounds (H2S + SO2) by 2.2–13.5, 6.2–28.9, and 18.2–33.3%, respectively.

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火焰燃烧条件下添加生物质强化煤的点火过程
使用现代技术、分析仪器和实验设备确定了切诺戈尔斯基煤、落叶松及其混合物的细颗粒(100–200μm)加热热分解和燃烧过程的特征,包括烟气的主要成分(CO、CO2、NOx和H2S+SO2)的浓度。基于煤的燃料混合物的生物质含量为10、20和30wt%。使用单个固体燃料及其混合物的热重分析来确定焦炭残渣发生点火和完成燃烧过程的温度。落叶松木屑比Chernogorsky煤更具活性,这是因为残炭点燃的温度最低;因此,即使在煤中加入10%的生物质,也会对混合物的反应性产生积极影响。在温度为500–800°C的气流中加热燃料的条件下,使用用于快速过程的高速视频记录的硬件-软件复合体来确定点火延迟时间。根据实验研究结果,发现试验燃料在加热空气流中的点火延迟时间在0.02至0.22 s之间变化,向煤中添加10–30 wt%的生物质可将燃料混合物的点火延迟缩短50%。通过对固体燃料燃烧产生的烟气进行分析,可以确定主要人为排放物的浓度;使用生物质作为煤的添加剂,二氧化碳、氮氧化物和硫化合物(H2S+SO2)的排放量分别减少了2.2–13.5、6.2–28.9和18.2–33.3%。
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来源期刊
Solid Fuel Chemistry
Solid Fuel Chemistry CHEMISTRY, MULTIDISCIPLINARY-ENERGY & FUELS
CiteScore
1.10
自引率
28.60%
发文量
52
审稿时长
6-12 weeks
期刊介绍: The journal publishes theoretical and applied articles on the chemistry and physics of solid fuels and carbonaceous materials. It addresses the composition, structure, and properties of solid fuels. The aim of the published articles is to demonstrate how novel discoveries, developments, and theories may be used in improved analysis and design of new types of fuels, chemicals, and by-products. The journal is particularly concerned with technological aspects of various chemical conversion processes and includes papers related to geochemistry, petrology and systematization of fossil fuels, their beneficiation and preparation for processing, the processes themselves, and the ultimate recovery of the liquid or gaseous end products.
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