Dynamic Aliphatic Polyester Elastomers Crosslinked with Aliphatic Dianhydrides

Abstract

Chemically crosslinked elastomers are a class of polymeric materials with properties that render them useful as adhesives, sealants, and in other engineering applications. Poly(γ-methyl-ε-caprolactone) (PγMCL) is a hydrolytically degradable and compostable aliphatic polyester that can be biosourced and exhibits competitive mechanical properties to traditional elastomers when chemically crosslinked. A typical limitation of chemically crosslinked elastomers is that they cannot be reprocessed; however, the incorporation of dynamic covalent bonds can allow for bonds to reversibly break and reform under an external stimulus, usually heat. In this work, we study the dynamic behavior and mechanical properties of PγMCL elastomers synthesized from aliphatic dianhydride crosslinkers. The crosslinked elastomers in this work were synthesized using the commercially available crosslinkers, 1,2,4,5-cyclohexanetetracarboxylic dianhydride, and 1,2,3,4-cyclobutanetetracarboxylic dianhydride and three-arm hydroxy-telechelic PγMCL star polymers. Stress relaxation experiments on the crosslinked networks showed an Arrhenius dependence of viscosity with temperature with an activation energy of 118 ± 8 kJ/mol, which agrees well with the activation energy of transesterification exchange chemistry obtained from small molecule model studies. Dynamic mechanical thermal analysis and rheological experiments confirmed the dynamic nature of the networks and provided insight into the mechanism of exchange (i.e., associative or dissociative). Tensile testing showed that these materials can exhibit high strains at break and low Young’s moduli, characteristic of soft and strong elastomers. By controlling the exchange chemistry and understanding the effect of macromolecular structure on mechanical properties, we prepared the high-performance elastomers that can be potentially reprocessed at moderately elevated temperatures.