Periodic Donor-Acceptor (Co)polyarylenephthalides with Tunable Photoluminescent Parameters

IF 1 4区 化学 Q4 POLYMER SCIENCE Polymer Science, Series B Pub Date : 2023-07-03 DOI:10.1134/S1560090423700719
V. A. Kraikin, A. A. Fatykhov, N. G. Gileva, T. A. Yangirov, S. S. Ostakhov, R. R. Kayumova, A. V. Mamykin, S. N. Salazkin
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Abstract

The macromonomers of the dyad (OYO) and triad (OYOYO, OYTYO) structure (with О being diphenylene oxide, T being terphenylene, and Y being the phthalide cycle) as well as a series of (co)poly-arylenephthalides with general formula [(OY)p(TY)q]n differing in the ratio between the diphenyleneoxyphthalide p and terphenylenephthalide q groups (p : q = 0 : 1, 1 : 1, 2 : 1, 3 : 1, 1 : 0) have been synthesized. Photooptical and emission properties of the solutions and thin films of the synthesized (co)polymers and their aggregates formed upon the addition of a bad solvent have been investigated.

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具有可调谐光致发光参数的周期性给受体(Co)聚苯二甲酸盐
合成了二元(OYO)和三元(OYOYO, OYTYO)结构的大单体(О为氧化二苯,T为苯,Y为苯循环)和一系列(co)聚芳基苯酞,其通式[(OY)p(TY)q]n不同于二苯氧基苯酞p和苯酞q基团(p: q = 0,1, 1,2,1, 3,1, 1:0)。研究了合成的(co)聚合物的溶液和薄膜及其在添加不良溶剂后形成的聚集体的光学和发射性质。
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来源期刊
Polymer Science, Series B
Polymer Science, Series B 化学-高分子科学
CiteScore
1.80
自引率
8.30%
发文量
58
审稿时长
>0 weeks
期刊介绍: Polymer Science, Series B is a journal published in collaboration with the Russian Academy of Sciences. Series B experimental and theoretical papers and reviews dealing with the synthesis, kinetics, catalysis, and chemical transformations of macromolecules, supramolecular structures, and polymer matrix-based composites (6 issues a year). All journal series present original papers and reviews covering all fundamental aspects of macromolecular science. Contributions should be of marked novelty and interest for a broad readership. Articles may be written in English or Russian regardless of country and nationality of authors. All manuscripts are peer reviewed
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