Effect of thermally induced microstructural changes on the mechanical properties and ballistic performance of poly (p-phenylene terephthalamide) fibers
Rinku Pramanick, S. Verma, R. Kumari, S. De, S. Neogi, S. Neogi
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引用次数: 1
Abstract
Microstructural variations have a strong influence on the load transfer capacity of the high-performance polymeric fibers, which is also reflected in their ballistic property changes. The focus of the present study is to investigate thermally induced microstructural changes and their reflection on the mechanical properties and theoretical ballistic limit of poly (p-phenylene terephthalamide) fibers by a correlation. From the quantitative analysis of XRD, thermally induced changes in unit cell a-dimension show profound sensitivity in affecting the tenacity and modulus of the fibers. Based on the physicochemical changes in FTIR and FESEM analysis, significant surface deterioration and changes in the chemical network are observed. However, dimensional variations of the crystal structure along a-direction show a stronger influence than the chemical and morphological changes, reflecting sigmoidal responses with tenacity, modulus and theoretical V50 by correlations. As an effect of unit cell dimensional variation, changes in crystallinity are resulted and lead to the loss in theoretical ballistic limit of the fibers by following first-order kinetics. Lastly, angular separation and (200) orientation angle are determined to build a global correlation with modulus and theoretical ballistic limit for quickly decoding macro-changes in terms of micro-properties. The given correlations can help to identify crystallographic transformations upon other induction techniques and view their effect on mechanical and ballistic parameters. In addition, the given approach can be extended for different ballistic materials under any environmental conditions. Graphical Abstract
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Health Services Management Research (HSMR) is an authoritative international peer-reviewed journal which publishes theoretically and empirically rigorous research on questions of enduring interest to health-care organizations and systems throughout the world. Examining the real issues confronting health services management, it provides an independent view and cutting edge evidence-based research to guide policy-making and management decision-making. HSMR aims to be a forum serving an international community of academics and researchers on the one hand and healthcare managers, executives, policymakers and clinicians and all health professionals on the other. HSMR wants to make a substantial contribution to both research and managerial practice, with particular emphasis placed on publishing studies which offer actionable findings and on promoting knowledge mobilisation toward theoretical advances. All papers are expected to be of interest and relevance to an international audience. HSMR aims at enhance communication between academics and practitioners concerned with developing, implementing, and analysing health management issues, reforms and innovations primarily in European health systems and in all countries with developed health systems. Papers can report research undertaken in a single country, but they need to locate and explain their findings in an international context, and in international literature.
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