In-situ TiC-reinforced Ni-based composite coatings fabricated by ultrasonic-assisted electrospark powder deposition

IF 2.2 4区 材料科学 Q2 MATERIALS SCIENCE, CERAMICS Journal of Asian Ceramic Societies Pub Date : 2022-11-11 DOI:10.1080/21870764.2022.2142368
Hang Zhao, Chang Gao, Cheng Guo, Bin Xu, Xiao-yu Wu, Jianguo Lei
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引用次数: 1

Abstract

ABSTRACT In this study, a (Ti + graphite)-Ni composite powder serving as a coating material was deposited on H13 steel to fabricate an in-situ TiC-reinforced Ni-based composite coating by a new type of ESD process, which was named ultrasonic-assisted electrospark powder deposition (UEPD). The composite coating has an average thickness of approximately 45.5 μm and metallurgically bonds with the substrate. The ultrasonic vibration exerted on the UEPD electrode can effectively improve the forming quality of the composite coating, which produces better compactness and thickness uniformity as well as few defects. The microstructure mainly consisted of submicron dendrites due to the rapid solidification of the molten pool. TiC particles as reinforcements were successfully synthesized in the coating via an in-situ reaction due to their low Gibbs free energy and high melting point. The formation of refined grains and in-situ reinforcements prompts the average hardness of the coating to reach 1400.5 HV0.05, which is approximately 2.5 times that of the substrate. The tribological properties of the composite coating are greatly improved in comparison with those of the substrate. The wear rate and friction coefficient of the composite coating decrease by two orders of magnitude and 46.2%, respectively.
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超声辅助电火花粉末沉积原位制备tic增强镍基复合涂层
摘要本研究采用一种新型的ESD工艺,即超声辅助电火花粉末沉积(UEPD),在H13钢上沉积(Ti+石墨)-Ni复合粉末作为涂层材料,制备了原位TiC增强镍基复合涂层。复合涂层的平均厚度约为45.5μm,并与基体冶金结合。超声振动作用在UEPD电极上可以有效地提高复合涂层的成型质量,使复合涂层具有更好的致密性和厚度均匀性,同时缺陷少。由于熔池的快速凝固,微观结构主要由亚微米枝晶组成。TiC颗粒由于其低吉布斯自由能和高熔点,通过原位反应在涂层中成功地合成了增强体。细化晶粒和原位增强的形成促使涂层的平均硬度达到1400.5HV0.05,约为基体的2.5倍。与基体相比,复合涂层的摩擦学性能有了很大的提高。复合涂层的磨损率和摩擦系数分别降低了两个数量级和46.2%。
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来源期刊
Journal of Asian Ceramic Societies
Journal of Asian Ceramic Societies Materials Science-Ceramics and Composites
CiteScore
5.00
自引率
4.30%
发文量
78
审稿时长
10 weeks
期刊介绍: The Journal of Asian Ceramic Societies is an open access journal publishing papers documenting original research and reviews covering all aspects of science and technology of Ceramics, Glasses, Composites, and related materials. These papers include experimental and theoretical aspects emphasizing basic science, processing, microstructure, characteristics, and functionality of ceramic materials. The journal publishes high quality full papers, letters for rapid publication, and in-depth review articles. All papers are subjected to a fair peer-review process.
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