Forensic Analysis of Artworks: More Than a (Complex) Analytical Issue

M. Andrade
{"title":"Forensic Analysis of Artworks: More Than a (Complex) Analytical Issue","authors":"M. Andrade","doi":"10.30744/brjac.2179-3425.point-of-view-mvoandrade","DOIUrl":null,"url":null,"abstract":"In 2008, Nicolas Eastaugh, founder and chief researcher at Art Discovery, a renowned London company for the analysis and research of artwork, discovered the presence of the white titanium (titanium dioxide) pigment in a painting attributed to the Dutch naturalized expressionist artist Heinrich Capendonk. The work had reached a record value of EUR 2.4 million at an auction in 2006. However, in 1915, the year in which the work was supposed to have been created, white titanium was not even available for use as a pigment, which would happen about 20 to 30 years later. The analytical result achieved by Eastaught revealed one of the biggest schemes of artwork forgeries ever discovered. The forger, Wolfgang Beltracchi, made a fortune, (under)estimated at EUR 30 million, built over 25 years acting in the art market. There are several cases of counterfeiting schemes involving artwork, large fortunes, renowned galleries, museums, collectors, specialists, and masterpieces. Cases like the one revealed by Eastaugh's analyses or the millionaire counterfeit scheme involving the century-old North American Knoedler Gallery are illustrative examples of how the art market is vulnerable to this kind of crime. The International Monetary Fund (IMF) and the United Nations Office on Drugs and Crime (UNODC) estimated the total annual trade in art and antiques in 2018 at around USD 70 billion, of which about USD 6 billion may have been due to illegal transactions related to theft, counterfeiting, smuggling, and organized crime. Still according to those institutions, half of that amount involved financial crimes and money laundering. In Brazil, within the scope of the Lava Jato Operation, the Federal Police seized 842 pieces of art and historical and cultural heritage, including paintings from different historical periods, sculptures, and other pieces, which add up to an estimated value of over BRL 33 million. All the pieces were related to investigations involving money laundering in cases of active and passive corruption. As other forms of money laundering resulting from various crimes have been curtailed by world authorities through specific legislation, the art market world has become increasingly attractive to crime. This scenario, combined with the great financial relevance of the legitimate art market, caused a very considerable increase in the demand for works by renowned authors and, as a direct consequence, a proportional increase in the number of forgeries and adulterations. As a result, the quality of counterfeits has also experienced a great improvement, requiring a proportional gain in technology and expertise in forensic analysis and authentication fields. Similarly, the high speculation in prices of artworks also increased the interest in new and advanced analytical techniques for determining authenticity, authorship, origin, and materials used by the authors. The refinement of counterfeiting and adulteration techniques has demanded a multidisciplinary and technological approach to the authentication process, and, at this point, we are faced with a considerable degree of complexity in the already difficult process of authenticating works of art. The authorship or authenticity determination of a painting is unavoidably based on a triangle formed by three disciplines: art history, preservation sciences, and materials sciences. The voices of our benches and equipment are unlikely to be able, on their own, to unequivocally conclude the authenticity of a work of art. Likewise, the most trained eyes of a professional connoisseur are no longer able to face the most astute counterfeiters. The best results of authenticity studies will always be achieved when these three distinct disciplines come together and complement each other in the search for comprehensive, technical, and artistic knowledge about the work. In addition to the historical study of the piece, the physical–chemical characterization of materials and components or elementary and multispectral imaging become powerful tools for fraud detection and even characterization and individualization of the authentic piece. The simplest techniques, generally used for initial documentation, to the more complex, analytical resources are used to extract the greatest amount of information from the different parts that make up a painting. In its diverse and complex layers, from the support to the final coating, paintings are composed of multilayers of heterogeneous mixtures of varied organic and inorganic compounds. A thorough investigation of this scenario always requires the use of advanced and combined techniques to better understand each case, depending on their nature. The analysis of the painting surface by a stereo-microscope will reveal genuine—or artificially produced—craquelure or brushwork patterns compatible with the artistic style proposed by the author of the work. Likewise, the UV fluorescence properties of the painting may differentiate between old and new additions of paint to the piece. However, it is in the deepest layers of an artwork that the most sophisticated analytical techniques contribute most incisively. X-ray radiography and infrared reflectography, coupled with ultra-sensitive charge-coupled devices (CCD), began to detect underdrawings that were invisible to the previously available methods. Several works have demonstrated the usefulness of tools such as synchrotron radiation, microimaging by X-ray fluorescence (XRF), and Raman or Fourier-transform infrared (FTIR) spectroscopies, combined with the versatility of portable spectrometric identification techniques, where pigment particles less than 1 micrometer in diameter can be analyzed. Even the power of pyrolysis-gas chromatography-mass spectrometry (Py-GC-MS) to identify novel synthetic organic polymers, which greatly assists in the analyses of pigments, coatings, binders, and other painting components, can, in many cases, reveal anachronisms present in the counterfeits. Other techniques such as laser ablation-inductively coupled plasma-mass spectrometry (LA-ICP-MS), isotope-ratio mass spectrometry (IRMS), and accelerator mass spectrometry (AMS) allow for the determination of isotopic ratios of heavy and light elements, which are decisive to determining the geographical origin of some pigments and the age of a painting canvas or its wooden frame. Such techniques used in association with multivariate analysis tools, artificial intelligence, and machine learning help achieve increasingly conclusive results, requiring less time and effort from the entire team of researchers. Each of the analytical techniques, evaluated for their versatility, resolution power, type of information generated, portability, and employment, have the potential for greater use in combined and multimodal work. This approach makes the description of the artwork much more precise and richer in details since it individualizes not only its components, support, and coating materials, but also the context in which they were used. The wisdom in better bringing together the analytical resources available and performing the analyses required by each case determines the success of a forensic examination of a forgery or the authenticity of a work of art. It is not hard to see that it is unlikely that a single company or laboratory, whether public, private, academic, or not, will own all the technological resources to exhaust such an analysis. Furthermore, it is not uncommon for crimes involving works of art to be transnational. All this leads us to the last step of our range of complexity: laboratories, museums, forensic, and research institutes involved in examining the authenticity of artworks should operate on secure and integrated networks, generating data that is widely shared between partner institutions. Several institutes in the world already work in this way, such as INTERPOL, the INTERNATIONAL COUNCIL OF MUSEUMS (ICOM), the Federal Bureau of Investigation (FBI), UNODC, and the Integrated Platform for the European Research Infrastructure on Cultural Heritage (Iperion CH). This has proven to be one of the most effective ways to curb this type of crime, which, sneakily, erodes our history and cultural heritage.","PeriodicalId":9115,"journal":{"name":"Brazilian Journal of Analytical Chemistry","volume":" ","pages":""},"PeriodicalIF":1.1000,"publicationDate":"2022-01-21","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"1","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"Brazilian Journal of Analytical Chemistry","FirstCategoryId":"1085","ListUrlMain":"https://doi.org/10.30744/brjac.2179-3425.point-of-view-mvoandrade","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q4","JCRName":"CHEMISTRY, ANALYTICAL","Score":null,"Total":0}
引用次数: 1

Abstract

In 2008, Nicolas Eastaugh, founder and chief researcher at Art Discovery, a renowned London company for the analysis and research of artwork, discovered the presence of the white titanium (titanium dioxide) pigment in a painting attributed to the Dutch naturalized expressionist artist Heinrich Capendonk. The work had reached a record value of EUR 2.4 million at an auction in 2006. However, in 1915, the year in which the work was supposed to have been created, white titanium was not even available for use as a pigment, which would happen about 20 to 30 years later. The analytical result achieved by Eastaught revealed one of the biggest schemes of artwork forgeries ever discovered. The forger, Wolfgang Beltracchi, made a fortune, (under)estimated at EUR 30 million, built over 25 years acting in the art market. There are several cases of counterfeiting schemes involving artwork, large fortunes, renowned galleries, museums, collectors, specialists, and masterpieces. Cases like the one revealed by Eastaugh's analyses or the millionaire counterfeit scheme involving the century-old North American Knoedler Gallery are illustrative examples of how the art market is vulnerable to this kind of crime. The International Monetary Fund (IMF) and the United Nations Office on Drugs and Crime (UNODC) estimated the total annual trade in art and antiques in 2018 at around USD 70 billion, of which about USD 6 billion may have been due to illegal transactions related to theft, counterfeiting, smuggling, and organized crime. Still according to those institutions, half of that amount involved financial crimes and money laundering. In Brazil, within the scope of the Lava Jato Operation, the Federal Police seized 842 pieces of art and historical and cultural heritage, including paintings from different historical periods, sculptures, and other pieces, which add up to an estimated value of over BRL 33 million. All the pieces were related to investigations involving money laundering in cases of active and passive corruption. As other forms of money laundering resulting from various crimes have been curtailed by world authorities through specific legislation, the art market world has become increasingly attractive to crime. This scenario, combined with the great financial relevance of the legitimate art market, caused a very considerable increase in the demand for works by renowned authors and, as a direct consequence, a proportional increase in the number of forgeries and adulterations. As a result, the quality of counterfeits has also experienced a great improvement, requiring a proportional gain in technology and expertise in forensic analysis and authentication fields. Similarly, the high speculation in prices of artworks also increased the interest in new and advanced analytical techniques for determining authenticity, authorship, origin, and materials used by the authors. The refinement of counterfeiting and adulteration techniques has demanded a multidisciplinary and technological approach to the authentication process, and, at this point, we are faced with a considerable degree of complexity in the already difficult process of authenticating works of art. The authorship or authenticity determination of a painting is unavoidably based on a triangle formed by three disciplines: art history, preservation sciences, and materials sciences. The voices of our benches and equipment are unlikely to be able, on their own, to unequivocally conclude the authenticity of a work of art. Likewise, the most trained eyes of a professional connoisseur are no longer able to face the most astute counterfeiters. The best results of authenticity studies will always be achieved when these three distinct disciplines come together and complement each other in the search for comprehensive, technical, and artistic knowledge about the work. In addition to the historical study of the piece, the physical–chemical characterization of materials and components or elementary and multispectral imaging become powerful tools for fraud detection and even characterization and individualization of the authentic piece. The simplest techniques, generally used for initial documentation, to the more complex, analytical resources are used to extract the greatest amount of information from the different parts that make up a painting. In its diverse and complex layers, from the support to the final coating, paintings are composed of multilayers of heterogeneous mixtures of varied organic and inorganic compounds. A thorough investigation of this scenario always requires the use of advanced and combined techniques to better understand each case, depending on their nature. The analysis of the painting surface by a stereo-microscope will reveal genuine—or artificially produced—craquelure or brushwork patterns compatible with the artistic style proposed by the author of the work. Likewise, the UV fluorescence properties of the painting may differentiate between old and new additions of paint to the piece. However, it is in the deepest layers of an artwork that the most sophisticated analytical techniques contribute most incisively. X-ray radiography and infrared reflectography, coupled with ultra-sensitive charge-coupled devices (CCD), began to detect underdrawings that were invisible to the previously available methods. Several works have demonstrated the usefulness of tools such as synchrotron radiation, microimaging by X-ray fluorescence (XRF), and Raman or Fourier-transform infrared (FTIR) spectroscopies, combined with the versatility of portable spectrometric identification techniques, where pigment particles less than 1 micrometer in diameter can be analyzed. Even the power of pyrolysis-gas chromatography-mass spectrometry (Py-GC-MS) to identify novel synthetic organic polymers, which greatly assists in the analyses of pigments, coatings, binders, and other painting components, can, in many cases, reveal anachronisms present in the counterfeits. Other techniques such as laser ablation-inductively coupled plasma-mass spectrometry (LA-ICP-MS), isotope-ratio mass spectrometry (IRMS), and accelerator mass spectrometry (AMS) allow for the determination of isotopic ratios of heavy and light elements, which are decisive to determining the geographical origin of some pigments and the age of a painting canvas or its wooden frame. Such techniques used in association with multivariate analysis tools, artificial intelligence, and machine learning help achieve increasingly conclusive results, requiring less time and effort from the entire team of researchers. Each of the analytical techniques, evaluated for their versatility, resolution power, type of information generated, portability, and employment, have the potential for greater use in combined and multimodal work. This approach makes the description of the artwork much more precise and richer in details since it individualizes not only its components, support, and coating materials, but also the context in which they were used. The wisdom in better bringing together the analytical resources available and performing the analyses required by each case determines the success of a forensic examination of a forgery or the authenticity of a work of art. It is not hard to see that it is unlikely that a single company or laboratory, whether public, private, academic, or not, will own all the technological resources to exhaust such an analysis. Furthermore, it is not uncommon for crimes involving works of art to be transnational. All this leads us to the last step of our range of complexity: laboratories, museums, forensic, and research institutes involved in examining the authenticity of artworks should operate on secure and integrated networks, generating data that is widely shared between partner institutions. Several institutes in the world already work in this way, such as INTERPOL, the INTERNATIONAL COUNCIL OF MUSEUMS (ICOM), the Federal Bureau of Investigation (FBI), UNODC, and the Integrated Platform for the European Research Infrastructure on Cultural Heritage (Iperion CH). This has proven to be one of the most effective ways to curb this type of crime, which, sneakily, erodes our history and cultural heritage.
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艺术品的法医学分析:不仅仅是一个(复杂的)分析问题
2008年,伦敦著名艺术品分析和研究公司Art Discovery的创始人兼首席研究员尼古拉斯·伊斯特夫(Nicolas Eastaugh)在一幅被认为是荷兰归化表现主义艺术家海因里希·卡彭多克(Heinrich Capendonk)的画作中发现了白色钛(二氧化钛)颜料的存在。这幅作品在2006年的一次拍卖会上创下了240万欧元的纪录。然而,在1915年,也就是这幅作品创作的那一年,白钛甚至无法用作颜料,这是在大约20到30年后才出现的。伊斯特获得的分析结果揭示了迄今为止发现的最大的艺术品伪造计划之一。伪造者沃尔夫冈·贝尔特拉奇(Wolfgang Beltracchi)在艺术市场上从业25年,赚了一大笔钱,(低于)估计有3000万欧元。有几起伪造计划涉及艺术品、大笔财富、著名画廊、博物馆、收藏家、专家和杰作。伊斯特夫的分析揭示的案例,以及涉及百年历史的北美诺德勒画廊(Knoedler Gallery)的百万富翁伪造案,都是艺术市场如何容易受到这类犯罪影响的例证。国际货币基金组织(IMF)和联合国毒品和犯罪问题办公室(UNODC)估计,2018年艺术品和古董的年度贸易总额约为700亿美元,其中约60亿美元可能是与盗窃、伪造、走私和有组织犯罪有关的非法交易。但据这些机构称,其中一半涉及金融犯罪和洗钱。在巴西,在Lava Jato行动范围内,联邦警察缴获了842件艺术和历史文化遗产,包括不同历史时期的绘画、雕塑和其他作品,估计总价值超过3300万巴西雷亚尔。所有这些案件都与主动和被动腐败案件中涉及洗钱的调查有关。由于世界各国当局通过具体立法限制了各种犯罪活动产生的其他形式的洗钱活动,艺术市场对犯罪活动的吸引力越来越大。这种情况,再加上合法艺术品市场的巨大金融相关性,导致对知名作家作品的需求大幅增加,其直接后果是,伪造和掺假作品的数量相应增加。因此,仿冒品的质量也有了很大的提高,这就要求在法医分析和鉴定领域的技术和专业知识有相应的提高。同样,艺术品价格的高投机也增加了人们对新的和先进的分析技术的兴趣,这些技术用于确定真伪、作者身份、来源和作者使用的材料。伪造和掺假技术的改进要求对鉴定过程采用多学科和技术方法,在这一点上,我们在已经困难的鉴定艺术作品的过程中面临着相当程度的复杂性。确定一幅画的作者或真伪,不可避免地要基于艺术史、保存学、材料学三个学科构成的三角关系。我们的长凳和设备发出的声音不太可能凭它们自己明确地断定一件艺术品的真伪。同样,专业鉴赏家最训练有素的眼睛也无法面对最狡猾的造假者。当这三个不同的学科结合在一起,并在寻找有关作品的全面、技术和艺术知识方面相互补充时,真实性研究的最佳结果将永远得到实现。除了对作品的历史研究,材料和成分的物理化学表征或基本和多光谱成像成为欺诈检测甚至鉴定和个性化正品的有力工具。从最简单的技术(通常用于初始文档)到更复杂的分析资源(用于从构成一幅画的不同部分提取最大数量的信息)。在其多样而复杂的层中,从支撑层到最终涂层,绘画是由各种有机和无机化合物的多层异质混合物组成的。对这种情况的彻底调查总是需要使用先进的组合技术来更好地理解每个情况,这取决于它们的性质。通过立体显微镜对绘画表面进行分析,可以发现与作品作者所提出的艺术风格相匹配的真迹或人工制作的工艺或笔法图案。 同样,画作的紫外线荧光特性可以区分新旧添加的颜料。然而,正是在艺术品的最深层,最复杂的分析技术发挥了最深刻的作用。x射线照相术和红外反射照相术,加上超灵敏电荷耦合器件(CCD),开始探测到以前可用方法无法探测到的暗影。一些工作已经证明了同步辐射、x射线荧光(XRF)微成像、拉曼或傅里叶变换红外(FTIR)光谱等工具的实用性,结合便携式光谱识别技术的多功能性,可以分析直径小于1微米的颜料颗粒。即使是热解-气相色谱-质谱(Py-GC-MS)识别新型合成有机聚合物的能力,在颜料、涂料、粘合剂和其他油漆成分的分析中也大有帮助,在许多情况下,可以揭示假冒产品中存在的时代错误。其他技术,如激光烧蚀-电感耦合等离子体质谱法(LA-ICP-MS)、同位素比质谱法(IRMS)和加速器质谱法(AMS),可以测定重元素和轻元素的同位素比例,这对于确定某些颜料的地理来源和油画画布或其木制框架的年代具有决定性作用。这些技术与多变量分析工具、人工智能和机器学习相结合,有助于获得越来越确凿的结果,需要整个研究团队更少的时间和精力。每一种分析技术,根据其通用性、分辨率、生成的信息类型、可移植性和使用情况进行评估,都有可能在组合和多模式工作中得到更大的应用。这种方法使得艺术品的描述更加精确,细节更加丰富,因为它不仅个性化了其组件,支撑和涂层材料,而且还个性化了它们的使用环境。更好地汇集可用的分析资源并根据每个案件进行所需的分析,这一智慧决定了对赝品或艺术品的真伪进行法医检查的成功。不难看出,一家公司或实验室,无论是公共的、私人的、学术的还是非学术的,不太可能拥有所有的技术资源来进行这样的分析。此外,涉及艺术品的跨国犯罪并不罕见。所有这些都将我们带到了复杂范围的最后一步:实验室、博物馆、法医和研究机构参与检查艺术品的真实性,应该在安全和集成的网络上运行,生成数据,在合作机构之间广泛共享。国际刑警组织、国际博物馆理事会(ICOM)、美国联邦调查局(FBI)、联合国毒品和犯罪问题办公室(UNODC)以及欧洲文化遗产研究基础设施综合平台(Iperion CH)等世界上一些机构已经在以这种方式开展工作。事实证明,这是遏制这类犯罪的最有效方法之一,这种犯罪悄悄地侵蚀了我们的历史和文化遗产。
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来源期刊
CiteScore
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自引率
14.30%
发文量
46
期刊介绍: BrJAC is dedicated to the diffusion of significant and original knowledge in all branches of Analytical Chemistry, and is addressed to professionals involved in science, technology and innovation projects at universities, research centers and in industry.
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