{"title":"Heterotridentate organodiphosphines in Pt(η3–P1X1P2)(Y) derivatives-structural aspects","authors":"M. Melnik, P. Mikuš","doi":"10.1515/revic-2021-0011","DOIUrl":null,"url":null,"abstract":"Abstract This review covers over 30 examples of monomeric Pt(II) complexes of the types: Pt(η3–P1O1P2)(Y) (Y = PL, CL, OL), Pt(η3–P1N1P2)(Y) (Y = H, NL, CL, Cl, PL) and Pt(η3–P1P2N1)(Y) (Y = Cl). The heterotridentate donor ligands create 11 types of a couple chelate rings with common central atom O1 (η3–P1O1P2), N1 (η3–P1N1P2) and P2 (η3–P1P2N1). The most frequent is P1C2N1C2P2. Some cooperative effects between chelate rings and Y donor ligands were found and discussed. A degree of distortions of square-planar geometry about Pt(II) were also calculated.","PeriodicalId":21162,"journal":{"name":"Reviews in Inorganic Chemistry","volume":"42 1","pages":"297 - 306"},"PeriodicalIF":4.1000,"publicationDate":"2021-07-22","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"3","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"Reviews in Inorganic Chemistry","FirstCategoryId":"92","ListUrlMain":"https://doi.org/10.1515/revic-2021-0011","RegionNum":3,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q1","JCRName":"CHEMISTRY, INORGANIC & NUCLEAR","Score":null,"Total":0}
引用次数: 3
Abstract
Abstract This review covers over 30 examples of monomeric Pt(II) complexes of the types: Pt(η3–P1O1P2)(Y) (Y = PL, CL, OL), Pt(η3–P1N1P2)(Y) (Y = H, NL, CL, Cl, PL) and Pt(η3–P1P2N1)(Y) (Y = Cl). The heterotridentate donor ligands create 11 types of a couple chelate rings with common central atom O1 (η3–P1O1P2), N1 (η3–P1N1P2) and P2 (η3–P1P2N1). The most frequent is P1C2N1C2P2. Some cooperative effects between chelate rings and Y donor ligands were found and discussed. A degree of distortions of square-planar geometry about Pt(II) were also calculated.
期刊介绍：
Reviews in Inorganic Chemistry (REVIC) is a quarterly, peer-reviewed journal that focuses on developments in inorganic chemistry. Technical reviews offer detailed synthesis protocols, reviews of methodology and descriptions of apparatus. Topics are treated from a synthetic, theoretical, or analytical perspective. The editors and the publisher are committed to high quality standards and rapid handling of the review and publication process. The journal publishes all aspects of solid-state, molecular and surface chemistry. Topics may be treated from a synthetic, theoretical, or analytical perspective. The editors and the publisher are commited to high quality standards and rapid handling of the review and publication process.
Topics:
-Main group chemistry-
Transition metal chemistry-
Coordination chemistry-
Organometallic chemistry-
Catalysis-
Bioinorganic chemistry-
Supramolecular chemistry-
Ionic liquids
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