FTIR-PCA analysis as an initial analysis to distinguish the origin of skin and leather

R. Yuliatmo, R. L. M. Wibowo, W. Pambudi, Sofwan Siddiq Abdullah, T. R. Hakim, Y. Erwanto
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引用次数: 3

Abstract

Leather products are parts of daily fashion in Indonesia, such as bags, shoes, jackets, and gloves. Adulteration of raw materials for leather products can occur if there are no labels on these products. Various methods such as PCR, GC-MS, HPLC, and FTIR have been carried out to distinguish the origin of leather products. The FTIR method is known as an easy and inexpensive method to use. The objective of this study was to evaluate the capability of FTIR spectroscopy and Principle Component Analysis (PCA) for lipid identifcation and initial analysis to distinguish the original materials on leather products. Lipid extracts obtained from the various skin were scanned using an FTIR spectrophotometer at 4000–450 cm -1 . It resulted in spectral differences in several wavenumbers (3000-2800 cm -1 and 1200-1000 cm -1 ). The same result is also found in lipid spectra from leather product extraction. The FTIR spectroscopy and PCA can differentiate pigskin and goatskin through specifc peaks in infrared spectra. This can be used as an initial analysis on determining the existence of skin adulteration in leather products. This study is prospective to be continued by chemometrics as quantitative analysis.
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FTIR-PCA分析作为区分皮肤和皮革来源的初步分析
皮革制品是印度尼西亚日常时尚的一部分,如包、鞋、夹克和手套。如果皮革产品上没有标签,则可能会发生皮革产品原材料的掺杂。人们已经采用了多种方法,如PCR、GC-MS、HPLC和FTIR来区分皮革制品的来源。众所周知,傅立叶变换红外光谱法是一种简单而廉价的使用方法。本研究的目的是评估FTIR光谱和主成分分析(PCA)在脂质鉴定和初步分析中区分皮革制品原材料的能力。使用FTIR分光光度计在4000–450 cm-1下扫描从各种皮肤中获得的脂质提取物。它导致了几个波数(3000-2800 cm-1和1200-1000 cm-1)的光谱差异。在皮革制品提取的脂质光谱中也发现了相同的结果。FTIR光谱和PCA可以通过红外光谱中的特定峰来区分猪皮和山羊皮。这可以作为确定皮革产品中是否存在皮肤掺假的初步分析。这项研究有望通过化学计量学作为定量分析继续下去。
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