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{"title":"A method to classify coal pore system by using cumulative amplitude ratio and its dynamic variation","authors":"Mingjun Zou, Ningbo Cai, Keying Wang, Zibin Ding, Linlin Yao","doi":"10.1002/ghg.2240","DOIUrl":null,"url":null,"abstract":"<p>As coal pore development is decisive for choosing the engineering site and predicting the CO<sub>2</sub> storage capacity, this paper provides a new method to define the double <i>T<sub>2</sub></i> cutoff values by using cumulative amplitude ratio measured by nuclear magnetic resonance measurements, classifies the coal pore systems, and analyzes the influences on cumulative amplitude ratio. The following cognitions are achieved. The minimum ratio always varies narrowly and ranges from 0.9 to 1.1, which is quite stable and approximately equals to 1. Ranges of maximum and average ratios are 1.2–3.5 and 1.1–1.8, respectively. <i>T</i><sub>2</sub><i><sub>c</sub></i><sub>1</sub> represents the dividing point of diffusion pore and permeation pore, and its average value is about 4.1 ms. <i>T</i><sub>2</sub><i><sub>c</sub></i><sub>2</sub> represents the dividing point of permeation pore and cleat, with an average value of about 81.9 ms. The volumetric proportions of diffusion pore range from 1.5% to 76.2%, with an average value of 34.6%; the volumetric proportions of permeation pore are from 14.9% to 98.5%, with an average of 46.8%; while the volumetric proportions of cleat are between 8.4% and 57.5%, with an average of 26.6%. According to the different influencing degrees on maximum and average ratios, three types of parameters can be divided. The first type is strong correlation parameters and includes permeability, volumetric percentage of cleat, and relative volumetric percentage of cleat. The second type is medium correlation parameters, such as volumetric percentage of diffusion pore. The third type is weak correlation parameters, including <i>T</i><sub>2</sub> cutoff values, porosity, and maximum vitrinite reflectance. © 2023 Society of Chemical Industry and John Wiley & Sons, Ltd.</p>","PeriodicalId":12796,"journal":{"name":"Greenhouse Gases: Science and Technology","volume":"13 5","pages":"721-731"},"PeriodicalIF":2.7000,"publicationDate":"2023-07-26","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"Greenhouse Gases: Science and Technology","FirstCategoryId":"93","ListUrlMain":"https://onlinelibrary.wiley.com/doi/10.1002/ghg.2240","RegionNum":4,"RegionCategory":"环境科学与生态学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q3","JCRName":"ENERGY & FUELS","Score":null,"Total":0}
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Abstract
As coal pore development is decisive for choosing the engineering site and predicting the CO2 storage capacity, this paper provides a new method to define the double T2 cutoff values by using cumulative amplitude ratio measured by nuclear magnetic resonance measurements, classifies the coal pore systems, and analyzes the influences on cumulative amplitude ratio. The following cognitions are achieved. The minimum ratio always varies narrowly and ranges from 0.9 to 1.1, which is quite stable and approximately equals to 1. Ranges of maximum and average ratios are 1.2–3.5 and 1.1–1.8, respectively. T 2 c 1 represents the dividing point of diffusion pore and permeation pore, and its average value is about 4.1 ms. T 2 c 2 represents the dividing point of permeation pore and cleat, with an average value of about 81.9 ms. The volumetric proportions of diffusion pore range from 1.5% to 76.2%, with an average value of 34.6%; the volumetric proportions of permeation pore are from 14.9% to 98.5%, with an average of 46.8%; while the volumetric proportions of cleat are between 8.4% and 57.5%, with an average of 26.6%. According to the different influencing degrees on maximum and average ratios, three types of parameters can be divided. The first type is strong correlation parameters and includes permeability, volumetric percentage of cleat, and relative volumetric percentage of cleat. The second type is medium correlation parameters, such as volumetric percentage of diffusion pore. The third type is weak correlation parameters, including T 2 cutoff values, porosity, and maximum vitrinite reflectance. © 2023 Society of Chemical Industry and John Wiley & Sons, Ltd.
一种利用累积振幅比及其动态变化对煤孔隙系统进行分类的方法
由于煤孔隙发育对工程选址和预测CO2储存量具有决定性作用,本文提出了利用核磁共振测量的累积振幅比确定双T2截止值的新方法,并对煤孔隙系统进行了分类,分析了对累积振幅比的影响。实现了以下认识。最小比值变化很小,在0.9 ~ 1.1之间,相当稳定,近似等于1。比值最大值为1.2-3.5,平均值为1.1-1.8。T2c1为扩散孔与渗透孔的分割点,其平均值约为4.1 ms。T2c2为渗透孔与透孔的分界点,平均值约为81.9 ms。扩散孔的体积占比为1.5% ~ 76.2%,平均值为34.6%;渗透孔体积占比为14.9% ~ 98.5%,平均为46.8%;而清净的体积比例在8.4% ~ 57.5%之间,平均为26.6%。根据对最大比和平均比的影响程度不同,可分为三类参数。第一类为强相关参数,包括渗透率、净土体积百分比和净土相对体积百分比。第二类是介质相关参数,如扩散孔体积百分比。第三类是弱相关参数,包括T2截止值、孔隙度和最大镜质组反射率。©2023化学工业协会和John Wiley &儿子,有限公司
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