Exploratory study of potential usefulness of cost-effective composites thin films for energy device

IF 3.6 Q2 MATERIALS SCIENCE, MULTIDISCIPLINARY Materials for Renewable and Sustainable Energy Pub Date : 2023-09-02 DOI:10.1007/s40243-023-00238-3
Maryama Hammi
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Abstract

In this study, we synthesized neat and loaded lead phosphate glass (PbO–P2O5) with the inclusion of Cr, Co, Ni, and Zn using an inexpensive sol–gel technique. These composites were then deposited on silica glass substrates. Our objective was to investigate the influence of these fillers on the properties of the glass. The concentrations of the fillers were varied from 0 to 16 wt%, and the resulting thin films were characterized by measuring the absorption coefficient and estimating the optical band gap at room temperature. Additionally, we measured the electrical resistivity of the semiconducting thin films as a function of filler concentrations and temperature. To assess the overall performance of the films, we calculated the figure of merit using the Iles and Soclof approach, considering the DC resistance versus free carrier concentration and absorption coefficient. Interestingly, our results revealed a significant improvement in the figure of merit at specific filler concentrations. The obtained results are comprehensive and provide detailed insights. They indicate that the thin films produced in this study have the potential to be useful in energy devices, particularly in applications involving P–N junctions and similar structures.

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低成本复合材料薄膜在能源器件中的潜在用途的探索性研究
在这项研究中,我们采用一种廉价的溶胶-凝胶技术合成了纯净的和添加了铬、钴、镍和锌的磷酸铅玻璃(PbO-P2O5)。然后将这些复合材料沉积在硅玻璃基底上。我们的目的是研究这些填料对玻璃特性的影响。填料的浓度在 0 到 16 wt% 之间变化,通过测量吸收系数和估算室温下的光带隙来表征所得到的薄膜。此外,我们还测量了半导体薄膜的电阻率与填料浓度和温度的函数关系。为了评估薄膜的整体性能,我们采用 Iles 和 Soclof 方法,考虑了直流电阻与自由载流子浓度和吸收系数的关系,计算出了优点系数。有趣的是,我们的研究结果表明,在特定的填料浓度下,薄膜的优越性能显著提高。获得的结果是全面的,并提供了详细的见解。这些结果表明,本研究中制备的薄膜具有在能源设备中发挥作用的潜力,尤其是在涉及 P-N 结和类似结构的应用中。
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来源期刊
Materials for Renewable and Sustainable Energy
Materials for Renewable and Sustainable Energy MATERIALS SCIENCE, MULTIDISCIPLINARY-
CiteScore
7.90
自引率
2.20%
发文量
8
审稿时长
13 weeks
期刊介绍: Energy is the single most valuable resource for human activity and the basis for all human progress. Materials play a key role in enabling technologies that can offer promising solutions to achieve renewable and sustainable energy pathways for the future. Materials for Renewable and Sustainable Energy has been established to be the world''s foremost interdisciplinary forum for publication of research on all aspects of the study of materials for the deployment of renewable and sustainable energy technologies. The journal covers experimental and theoretical aspects of materials and prototype devices for sustainable energy conversion, storage, and saving, together with materials needed for renewable fuel production. It publishes reviews, original research articles, rapid communications, and perspectives. All manuscripts are peer-reviewed for scientific quality. Topics include: 1. MATERIALS for renewable energy storage and conversion: Batteries, Supercapacitors, Fuel cells, Hydrogen storage, and Photovoltaics and solar cells. 2. MATERIALS for renewable and sustainable fuel production: Hydrogen production and fuel generation from renewables (catalysis), Solar-driven reactions to hydrogen and fuels from renewables (photocatalysis), Biofuels, and Carbon dioxide sequestration and conversion. 3. MATERIALS for energy saving: Thermoelectrics, Novel illumination sources for efficient lighting, and Energy saving in buildings. 4. MATERIALS modeling and theoretical aspects. 5. Advanced characterization techniques of MATERIALS Materials for Renewable and Sustainable Energy is committed to upholding the integrity of the scientific record. As a member of the Committee on Publication Ethics (COPE) the journal will follow the COPE guidelines on how to deal with potential acts of misconduct. Authors should refrain from misrepresenting research results which could damage the trust in the journal and ultimately the entire scientific endeavor. Maintaining integrity of the research and its presentation can be achieved by following the rules of good scientific practice as detailed here: https://www.springer.com/us/editorial-policies
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