D. A. Pomogailo, O. I. Gromov, V. I. Pergushov, I. D. Sorokin, M. Ya. Melnikov
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引用次数: 0
Abstract
The nature of radical cations stabilized in irradiated frozen 1,3-butadiene diepoxide/CF3CCl3 solutions was determined via low-temperature UV/Vis spectroscopy, electron paramagnetic resonance spectroscopy, and quantum chemistry. It was found that the cyclic radical cations yielded as radiolysis products undergo C–C bond cleavage in both oxirane cycles under the action of light with further elimination of molecular formaldehyde resulting in distonic •CH2OC+CH2 radical cations.
期刊介绍：
Moscow University Chemistry Bulletin is a journal that publishes review articles, original research articles, and short communications on various areas of basic and applied research in chemistry, including medical chemistry and pharmacology.
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