{"title":"Selective Oxidation of Alkenes by Dioxygen Using Modified Gold Nanoclusters","authors":"H. Salari, M. Gholami","doi":"10.22036/PCR.2020.220761.1735","DOIUrl":null,"url":null,"abstract":"Selective oxidation of cyclohexene and styrene was investigated using molecular oxygen under mild conditions. Au/TiO2 and Au/Al2O3 surfaces were impregnated with three different ionic liquids. Supported ionic liquids (ILs) gold nanocatalysts are particularly versatile catalysts for oxidation reaction with exceptionally high efficiency and significant selectivity. Improved activity is attributed to the stabilization of reaction intermediates via different interaction such as hydrogen bonding and polarity/dipolarizability between ILs and intermediates. Surface coating of obtained nanoparticles with ionic liquids is found to increase the interaction energy. The estimated rate constant decreases in the following order: [EAP] > [bmim]PF6 > [emim]EtSO4. EAP/Au/Al2O3 exhibited maximum conversion compare to other IL-impregnated catalysts. Supported ionic liquids gold nanocatalysts are active catalysts for oxidation reaction with high efficiency and selectivity.","PeriodicalId":20084,"journal":{"name":"Physical Chemistry Research","volume":"8 1","pages":"557-568"},"PeriodicalIF":1.4000,"publicationDate":"2020-09-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"Physical Chemistry Research","FirstCategoryId":"1085","ListUrlMain":"https://doi.org/10.22036/PCR.2020.220761.1735","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q3","JCRName":"CHEMISTRY, MULTIDISCIPLINARY","Score":null,"Total":0}
引用次数: 0
Abstract
Selective oxidation of cyclohexene and styrene was investigated using molecular oxygen under mild conditions. Au/TiO2 and Au/Al2O3 surfaces were impregnated with three different ionic liquids. Supported ionic liquids (ILs) gold nanocatalysts are particularly versatile catalysts for oxidation reaction with exceptionally high efficiency and significant selectivity. Improved activity is attributed to the stabilization of reaction intermediates via different interaction such as hydrogen bonding and polarity/dipolarizability between ILs and intermediates. Surface coating of obtained nanoparticles with ionic liquids is found to increase the interaction energy. The estimated rate constant decreases in the following order: [EAP] > [bmim]PF6 > [emim]EtSO4. EAP/Au/Al2O3 exhibited maximum conversion compare to other IL-impregnated catalysts. Supported ionic liquids gold nanocatalysts are active catalysts for oxidation reaction with high efficiency and selectivity.
期刊介绍：
The motivation for this new journal is the tremendous increasing of useful articles in the field of Physical Chemistry and the related subjects in recent years, and the need of communication between Physical Chemists, Physicists and Biophysicists. We attempt to establish this fruitful communication and quick publication. High quality original papers in English dealing with experimental, theoretical and applied research related to physics and chemistry are welcomed. This journal accepts your report for publication as a regular article, review, and Letter. Review articles discussing specific areas of physical chemistry of current chemical or physical importance are also published. Subjects of Interest: Thermodynamics, Statistical Mechanics, Statistical Thermodynamics, Molecular Spectroscopy, Quantum Chemistry, Computational Chemistry, Physical Chemistry of Life Sciences, Surface Chemistry, Catalysis, Physical Chemistry of Electrochemistry, Kinetics, Nanochemistry and Nanophysics, Liquid Crystals, Ionic Liquid, Photochemistry, Experimental article of Physical chemistry. Mathematical Chemistry.
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