Biomass ash as a new potential rеsource of phosphorous for industry

S. Vassilev, C. Vassileva
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Abstract

The content and modes of occurrence of phosphorous (P) in eight biomass ashes (BAs) were studied. It was found that BAs are enriched in P as its concentration varies in the range 0.3–4.4% (mean 1.7%). The highest contents of P (>2 %) are characteristic of ashes produced from agricultural residues, namely plum pits, sunflower shells and corn cobs. It was identified that the modes of P occurrence in BAs are related mostly to apatite and whitlockite. Hence, BAs having renewable and C-neutral origin could be alternative and very perspective resource for the potential recovery of P and its utilization in industry in contrast to finite and non-renewable phosphate rocks.
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生物质灰作为一种潜在的新型工业磷资源源
研究了8种生物质灰中磷的含量和存在方式。研究发现,BAs富含P,其浓度在0.3-4.4%(平均1.7%)之间变化。P含量最高(>2%)的是农业残留物产生的灰烬,即李子坑、向日葵壳和玉米芯。结果表明,磷在BAs中的赋存方式主要与磷灰石和白榴石有关。因此,与有限和不可再生的磷矿石相比,具有可再生和碳中性来源的BAs可能是潜在的磷回收及其在工业中利用的替代和非常有前景的资源。
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