{"title":"Activity modification of a new type of carbamide-based non-polluting solid powdery medium used in the sulphonitrocarburising process","authors":"M. Cojocaru, M. Branzei, M. Ion, L. Drugặ","doi":"10.1504/ijsurfse.2020.10034488","DOIUrl":null,"url":null,"abstract":"Carbamide (technical grade urea) is frequently used as a highly efficient active component in the mediums used for ferritic or austenitic nitrocarburising processes, and across a wide range of temperature values, ranging from values below 590°C required for achieving the ferritic nitrocarburising process, to values above 800°C required for the austenitic nitrocarburising process. The carbamide activity generates a particularly intense layer of growth kinetics. This paper studies the ability of carbamide to supply nitrogen and carbon, in the temperature range 550-950°C. It was concluded that this process varies by temperature, and for a composition of the solid powdery medium (35% carbamide, 50% carbon, 10% sulphur and 5% ammonium chloride) at 820°C the carbon potential level is higher compared to the nitrogen one.","PeriodicalId":14460,"journal":{"name":"International Journal of Surface Science and Engineering","volume":" ","pages":""},"PeriodicalIF":1.0000,"publicationDate":"2020-12-23","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"International Journal of Surface Science and Engineering","FirstCategoryId":"5","ListUrlMain":"https://doi.org/10.1504/ijsurfse.2020.10034488","RegionNum":4,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q4","JCRName":"ENGINEERING, MECHANICAL","Score":null,"Total":0}
引用次数: 0
Abstract
Carbamide (technical grade urea) is frequently used as a highly efficient active component in the mediums used for ferritic or austenitic nitrocarburising processes, and across a wide range of temperature values, ranging from values below 590°C required for achieving the ferritic nitrocarburising process, to values above 800°C required for the austenitic nitrocarburising process. The carbamide activity generates a particularly intense layer of growth kinetics. This paper studies the ability of carbamide to supply nitrogen and carbon, in the temperature range 550-950°C. It was concluded that this process varies by temperature, and for a composition of the solid powdery medium (35% carbamide, 50% carbon, 10% sulphur and 5% ammonium chloride) at 820°C the carbon potential level is higher compared to the nitrogen one.
期刊介绍:
IJSurfSE publishes refereed quality papers in the broad field of surface science and engineering including tribology, but with a special emphasis on the research and development in friction, wear, coatings and surface modification processes such as surface treatment, cladding, machining, polishing and grinding, across multiple scales from nanoscopic to macroscopic dimensions. High-integrity and high-performance surfaces of components have become a central research area in the professional community whose aim is to develop highly reliable ultra-precision devices.