Recent advances on structural, thermal, vibrational, optical, phase transitions, and catalysis properties of alkylenediammonium halogenometallate materials (Metal: Bi, Sb, Halogen: Cl, Br, I)

IF 4.1 3区 化学 Q1 CHEMISTRY, INORGANIC & NUCLEAR Reviews in Inorganic Chemistry Pub Date : 2022-07-07 DOI:10.1515/revic-2022-0012
A. Ouasri
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引用次数: 1

Abstract

Abstract This paper aims to review recent advances on synthesis, crystal structures, thermal, spectroscopic, phase transitions, optical, dielectric, and catalysis properties of hydrate and anhydrous alkylenediammonium halogenometallates materials (Metal: Bi, Sb, Halogen: Cl, Br, I). These hybrid materials present rich structural diversities based on octahedra forming infinite zero dimensional, 1-dimensional chains, 2-dimensional layers, discrete bioctahedra, and discrete tetramer units. The effect, contribution and importance of hydrogen bonding N–H … X (X: Cl, Br, I) are reviewed in terms of solid state relationship. Particularly, a comparative study is made on hydrate and anyhdrous aliphatic chlorobismuthates with alkylenediammonium +NH3(CH2) n NH3+ based on structural data and V/Z variation with (CH2) n chains (n = 2–8, 12), and variation of BiCl63− Raman frequencies modes versus (CH2) n chains (n = 3–8). Hydrate salts with (n = 3, 12) consist of isolated BiCl63− anions and two water molecules, against others ones with isolated anionic chains [BiCl52−] n or Bi2Cl104− dimers, formed by distorted octahedra BiCl63− sharing corners, vices or edges. The reviewed optical and electronic band gaps suggested interesting compounds with band gaps (1.85–2.4 eV), as suitable materials in optoelectronic properties, photoactive layer in solution-processed photovoltaics, and bio-imaging or photovoltaic applications. It was concluded that iodobismuthate salts have generally the lowest bands gap, compared to that of bromo and chlorobismuthate slats. Catalysis proprieties are reviewed n fast (RhB) degradation under dark conditions for (C4N2H7)4Bi2Cl10, (C5H9N2)BiI4, and {(H-BPA)4·[(BiI6)I13]·2I3} n , and in organic salts synthesis under solvent-free conditions. Herein NH3(CH2) n NH3BiCl5 (n = 5–7) salts were used as highly efficient catalysts, which is a novel tendency in chlorobismuthate researchs in the green chemistry field.
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卤代金属酸亚烯二铵材料(金属:Bi, Sb,卤素:Cl, Br, I)的结构、热、振动、光学、相变和催化性能研究进展
摘要本文综述了水合物和无水亚烷基卤代二铵材料(金属:Bi,Sb,卤素:Cl,Br,I)的合成、晶体结构、热、光谱、相变、光学、介电和催化性能的最新进展。这些杂化材料基于八面体呈现出丰富的结构多样性,八面体形成无限的零维、一维链、二维层、离散的生物八面体和离散的四聚体单元。从固态关系的角度综述了氢键N–H…X(X:Cl,Br,I)的作用、贡献和重要性。特别是,基于结构数据和(CH2)n链的V/Z变化(n=2–8,12),以及BiCl63−拉曼频率模式与(CH2。具有(n=3,12)的水合物盐由分离的BiCl63−阴离子和两个水分子组成,而其他分子则具有分离的阴离子链[BiCl52−]n或Bi2Cl104−二聚体,由扭曲的八面体BiCl63–共享角、副或边缘形成。综述的光学和电子带隙表明,具有带隙(1.85–2.4 eV)的有趣化合物是光电子性能、溶液处理光伏中的光活性层以及生物成像或光伏应用中的合适材料。得出的结论是,与溴和氯铋酸盐相比,碘铋酸盐通常具有最低的带隙。综述了(C4N2H7)4Bi2Cl10、(C5H9N2)BiI4和{(H-BPA)4·[(BiI6)I13]·2I3}n在黑暗条件下的快速(RhB)降解以及在无溶剂条件下的有机盐合成中的催化特性。本文使用NH3(CH2)n-NH3BiCl5(n=5–7)盐作为高效催化剂,这是绿色化学领域氯铋酸盐研究的一个新趋势。
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来源期刊
Reviews in Inorganic Chemistry
Reviews in Inorganic Chemistry 化学-分析化学
CiteScore
7.30
自引率
4.90%
发文量
20
审稿时长
1 months
期刊介绍: Reviews in Inorganic Chemistry (REVIC) is a quarterly, peer-reviewed journal that focuses on developments in inorganic chemistry. Technical reviews offer detailed synthesis protocols, reviews of methodology and descriptions of apparatus. Topics are treated from a synthetic, theoretical, or analytical perspective. The editors and the publisher are committed to high quality standards and rapid handling of the review and publication process. The journal publishes all aspects of solid-state, molecular and surface chemistry. Topics may be treated from a synthetic, theoretical, or analytical perspective. The editors and the publisher are commited to high quality standards and rapid handling of the review and publication process. Topics: -Main group chemistry- Transition metal chemistry- Coordination chemistry- Organometallic chemistry- Catalysis- Bioinorganic chemistry- Supramolecular chemistry- Ionic liquids
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