Influence of hydrophilic polymers based on polyvinyl alcohol and starch on physiсo-mechanical properties of thermal insulation materials

IF 0.3 Q4 CHEMISTRY, MULTIDISCIPLINARY Chemical Bulletin of Kazakh National University Pub Date : 2020-03-25 DOI:10.15328/cb1094
P. Urkimbaeva, B. Bakytzhanuly, Yesen Dilmukhambetov, A. Mamutova, Z. Kenessova
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Abstract

Thermal insulating materials based on diatomite with burnable and reinforcing additives modified with synthetic and natural polymers have been developed. A mixture of polyvinyl alcohol and starch was used as modifying polymers. The parameters of linear shrinkage, density, tensile strengths in compression and bending, as well as the coefficient of thermal conductivity of the material were determined depending on the concentration and ratio of polymers. It was established that polymer additives had a positive effect on almost all specified characteristics of thermal insulating materials. For example, when adding polymers up to 1 mass.%, the linear shrinkage coefficients decrease from 14.5 to 4.5%, the ultimate compression strengths increase from 0.22 to 2.51 MPa, the ultimate bending strengths increase from 0.2 to 1.26 MPa, the coefficients of thermal conductivity decrease from 0.068 to 0.049 W/m∙K. The densities of materials are in the range of 0.592-0.491 g/cm3. The results of the work showed that the obtained heat-insulating materials can be used as plasticizers in the field of thermal energy.
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聚乙烯醇和淀粉基亲水性聚合物对保温材料物理力学性能的影响
研制了以硅藻土为基材,添加可燃助剂和增强助剂,并用合成聚合物和天然聚合物对硅藻土进行改性的保温材料。聚乙烯醇和淀粉的混合物被用作改性聚合物。根据聚合物的浓度和配比,确定了材料的线收缩率、密度、压缩和弯曲抗拉强度以及导热系数等参数。研究表明,聚合物添加剂对保温材料的几乎所有特定性能都有积极的影响。例如,当加入聚合物的质量达到1时。%时,线收缩系数从14.5减小到4.5%,极限抗压强度从0.22增大到2.51 MPa,极限抗弯强度从0.2增大到1.26 MPa,导热系数从0.068减小到0.049 W/m∙K。材料的密度在0.592-0.491 g/cm3之间。研究结果表明,所制得的隔热材料可作为热能领域的增塑剂。
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