Agricultural soil health monitoring using photonic crystal fiber based on combined principles of surface plasmon resonance and interferometry for lead ion detection

IF 16.4 1区 化学 Q1 CHEMISTRY, MULTIDISCIPLINARY Accounts of Chemical Research Pub Date : 2023-07-01 DOI:10.1117/1.JNP.17.036013
Sudipta Kumari Panigrahy, Preeti Das, S. K. Tripathy
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Abstract

Abstract. To monitor the health of agricultural soil, lead (Pb2  +  ) ion measurement is essential. The various sensors for lead ion detection reported in the literature earlier are either expensive or have complicated designs. This inspired us to propose a fiber optic sensor that is simple in design, less expensive, and more efficient. A photonic crystal fiber (PCF)-unclad single mode fiber (SMF)-PCF hybrid configuration makes up the suggested sensor, and the sensing mechanism is based on a synergistic application of surface plasmon resonance and interferometry. It is shown that the suggested structure is easy to use for Pb2  +   ion detection, in addition to other advantages in limit of detection (LOD) and sensitivity. The proposed structure is optimized to attain a LOD of 8.32  mg  /  kg, which is much less than the permissible limit of Pb2  +   ions permitted in healthy agricultural soil, i.e., 100 to 400  mg  /  kg. Additionally, a polymer that is attached atop the gold layer and to which only Pb2  +   ions can adhere ensures the sensor’s specificity. To the best of our knowledge, our proposed optical fiber-based sensor design and approach adopted to detect lead ions in agricultural soil are the first of their kind.
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基于表面等离子体共振和干涉测量相结合原理的光子晶体光纤用于铅离子检测的农业土壤健康监测
摘要为了监测农业土壤的健康状况,铅(Pb2  +  ) 离子测量是必不可少的。早期文献中报道的用于铅离子检测的各种传感器要么昂贵,要么设计复杂。这启发了我们提出一种设计简单、价格低廉、效率更高的光纤传感器。光子晶体光纤(PCF)-无包层单模光纤(SMF)-光子晶体光纤的混合配置构成了所建议的传感器,其传感机制基于表面等离子体共振和干涉测量的协同应用。结果表明,所提出的结构易于用于Pb2  +   离子检测,以及在检测限(LOD)和灵敏度方面的其他优点。对所提出的结构进行了优化,以获得8.32的LOD  毫克  /  kg,远低于Pb2的允许限值  +   健康农业土壤中允许的离子,即100至400  毫克  /  此外,一种附着在金层顶部的聚合物,其上只有Pb2  +   离子可以粘附确保传感器的特异性。据我们所知,我们提出的基于光纤的传感器设计和用于检测农业土壤中铅离子的方法是同类传感器中的第一种。
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来源期刊
Accounts of Chemical Research
Accounts of Chemical Research 化学-化学综合
CiteScore
31.40
自引率
1.10%
发文量
312
审稿时长
2 months
期刊介绍: Accounts of Chemical Research presents short, concise and critical articles offering easy-to-read overviews of basic research and applications in all areas of chemistry and biochemistry. These short reviews focus on research from the author’s own laboratory and are designed to teach the reader about a research project. In addition, Accounts of Chemical Research publishes commentaries that give an informed opinion on a current research problem. Special Issues online are devoted to a single topic of unusual activity and significance. Accounts of Chemical Research replaces the traditional article abstract with an article "Conspectus." These entries synopsize the research affording the reader a closer look at the content and significance of an article. Through this provision of a more detailed description of the article contents, the Conspectus enhances the article's discoverability by search engines and the exposure for the research.
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