High-Temperature Interaction between Carbon Fibers and Cu–Ag Eutectic Alloy

IF 0.5 Q4 MATERIALS SCIENCE, MULTIDISCIPLINARY International Journal of Self-Propagating High-Temperature Synthesis Pub Date : 2023-01-09 DOI:10.3103/S1061386222040112
A. E. Sytschev, S. G. Vadchenko, M. L. Busurina, O. D. Boyarchenko, A. V. Karpov
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Abstract

High-temperature interaction of 30 wt % Cu–70 wt % Ag eutectic alloy with carbon fibers was studied. It was shown that Cu–Ag drops coated with carbon film are formed on the surface of carbon fibers. Carbon atoms dissolved in the molten Cu–Ag phase precipitated out on the drop surface at a lower temperature, thus resulting in growing few-layer graphene. Cu–Ag–carbon fibers composites sintered at 670°C was shown to represent a porous structure containing spherical Cu–Ag particles and carbon fibers. It was revealed that as C is added, the electrical resistivity of sintered samples decreases. Raman spectra of sintered composites containing 3.0 and 6.3 wt % C showed the formation of a multilayer graphene coating with a disordered structure.

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碳纤维与Cu-Ag共晶合金的高温相互作用
研究了30 wt % Cu-70 wt % Ag共晶合金与碳纤维的高温相互作用。结果表明,在碳纤维表面可形成包覆碳膜的Cu-Ag滴状物。溶解在熔融Cu-Ag相中的碳原子在较低温度下在液滴表面析出,从而生长出少层石墨烯。在670℃下烧结的Cu-Ag -碳纤维复合材料表现为含有球形Cu-Ag颗粒和碳纤维的多孔结构。结果表明,随着C的加入,烧结试样的电阻率降低。含有3.0 wt % C和6.3 wt % C的烧结复合材料的拉曼光谱显示,形成了无序结构的多层石墨烯涂层。
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来源期刊
CiteScore
1.00
自引率
33.30%
发文量
27
期刊介绍: International Journal of Self-Propagating High-Temperature Synthesis  is an international journal covering a wide range of topics concerned with self-propagating high-temperature synthesis (SHS), the process for the production of advanced materials based on solid-state combustion utilizing internally generated chemical energy. Subjects range from the fundamentals of SHS processes, chemistry and technology of SHS products and advanced materials to problems concerned with related fields, such as the kinetics and thermodynamics of high-temperature chemical reactions, combustion theory, macroscopic kinetics of nonisothermic processes, etc. The journal is intended to provide a wide-ranging exchange of research results and a better understanding of developmental and innovative trends in SHS science and applications.
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