EFFECT OF A BARRIER ON ENERGY EIGENVALUE OF THE NONRELATIVISTIC (SCHRÖDINGER EQUATION) AND SOME EXPECTATION VALUES OF COMBINED POTENTIALS

IF 0.2 Q4 CHEMISTRY, MULTIDISCIPLINARY Periodico Tche Quimica Pub Date : 2020-12-20 DOI:10.52571/ptq.v17.n36.2020.661_periodico36_pgs_646_661.pdf
C. Onate, M. Onyeaju, A. Abolarinwa, J. O. Okoro
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Abstract

Schrödinger equation was proposed in theoretical physics to provide information and the behavior of a system of particles. The Schrödinger equation was recently solved for a combination of different potentials using different traditional methodologies. The studies do not consider the effect of a barrier between the potentials. In reality, the barrier between the potentials has an effect on the energy eigenvalues. In the present work, a Kratzer-Mie-type potential, a combination of Kratzer and Mie-type-constant potentials, was proposed as the interacting potential. The solutions of the radial Schrödinger equation was obtained in the presence of the combined potentials by considering a barrier between the potentials. The energy equation and the corresponding wave functions were explicitly calculated. The calculations were performed by using the methodology of supersymmetric quantum mechanics. This method involves the proposition of superpotential function as a solution to its Riccati differential equation. Numerical results were generated for some diatomic molecules using the energy equation and the diatomic model parameters. Some expectation values for the combined potential were calculated using Hellmann Feynman Theorem, and the effect of the barrier on the expectation values were numerically studied. It was observed that when a particle moves from the lower end to a higher end of a barrier, it absorbs energy from the system for some time. This same behavior was also noted when the particle penetrates through a barrier. Thus, its vibration will only depend on the initial energy, which is absorbed. It was equally seen that as the width of the barrier becomes larger than the height, the energy of the system decreases drastically.
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势垒对非相对论性能量本征值(schrÖdinger方程)和组合势期望值的影响
Schrödinger方程是在理论物理学中提出的,用于提供粒子系统的信息和行为。最近用不同的传统方法求解了不同电位组合的Schrödinger方程。这些研究没有考虑到电位之间屏障的影响。实际上,势垒对能量特征值有影响。在本工作中,提出了一个克拉泽-米奇型电势作为相互作用电势,它是克拉泽电势和米奇型恒定电势的组合。通过考虑势垒之间的作用,得到了复合势存在时径向Schrödinger方程的解。明确地计算了能量方程和相应的波函数。计算是用超对称量子力学的方法进行的。该方法涉及到超势函数的命题作为其里卡蒂微分方程的解。利用能量方程和双原子模型参数对一些双原子分子进行了数值计算。利用Hellmann - Feynman定理计算了组合势的期望值,并数值研究了势垒对期望值的影响。我们观察到,当一个粒子从势垒的低端移动到高端时,它会在一段时间内从系统中吸收能量。当粒子穿过屏障时,同样的行为也被注意到。因此,它的振动只取决于被吸收的初始能量。同样可以看出,当势垒的宽度大于势垒的高度时,系统的能量急剧下降。
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Periodico Tche Quimica
Periodico Tche Quimica CHEMISTRY, MULTIDISCIPLINARY-
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期刊介绍: The Journal publishes original research papers, review articles, short communications (scientific publications), book reviews, forum articles, announcements or letters as well as interviews. Researchers from all countries are invited to publish on its pages.
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