SINTESIS SURFAKTAN TURUNAN AMIDA YANG DIPEROLEH DARI REKASI METIL RISINOLEAT DAN ETILENDIAMINA

Daniel Tarigan, Magdaleni Rahayu Agustina, Soerja Kosenarpadi
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引用次数: 1

Abstract

Interesterification of castor oil with methanol using base catalyst gave mixture of fatty acid methyl esther (FAME) castor oil. Methyl risinoleate as major composition of methyl esther castor oil was subjected to column chromatography using petroleum ether:diethyl ether (19:1, v/v) as eluent, to give yield 73%. Amidation of methyl risinoleate with ethylendiamine under refluks condition using benzene as solvent for  ± 12 hours and catalyst NaOCH3, gave 1,3–Dirisinoleil-Etilendiamida compound and 59% yield. The reactioned product 1,3–Dirisinoleil-Etilendiamida has been confirmed its structure using FT-IR spectroscopy, and Hidrofile Lipofile Balance (HLB) value was determined by titration method 12,56
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用碱催化剂对蓖麻油与甲醇进行酯化反应,得到脂肪酸甲基埃斯特(FAME)蓖麻油混合物。以蓖麻油为主要成分,以石油醚:二乙醚(v/v∶19)为洗脱液,对蓖麻油进行柱层析,得率为73%。以苯为溶剂,NaOCH3为催化剂,在回流条件下用乙胺与癸二胺酰胺化得到1,3 -二癸二烯油酸甲酯,收率为59%。用FT-IR光谱对反应产物1,3 -二烯二醇油-乙烯二胺的结构进行了确证,并用滴定法12,56测定了Hidrofile Lipofile Balance (HLB)值
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