{"title":"A diffuse reflectance portable near infrared spectroscopy system for the determination of biuret content in urea fertilizer","authors":"Jing Liu, Sha Yu, Shupeng Hu, Ziyang Ling, Jiguang Gao, Binmei Liu, Lixiang Yu, Yang Yang, Ye Yang, Qi Wang, Xiaoyu Ni, Liping Zhao, Yuejin Wu","doi":"10.1177/09670335221136546","DOIUrl":null,"url":null,"abstract":"Simple, rapid, and reliable determination of the biuret content in urea fertilizer is very important for the development of fertilizer industry. A near infrared diffuse reflectance measurement system with a portable spectrometer was developed, in which the reference and dark background spectrum could also be recorded automatically in addition to the absorbance data. The key performances of the proposed NIR system have been tested on urea fertilizer. Numerical experiments showed that the coefficient of determination (R2) of the external validation set was 0.97, with a root mean square error (RMSE) of 0.04%. The ratios of the performance deviation (RPD) value in the calibration and validation sets were 12 and 3.5, respectively. It can be concluded that this NIR system for the determination of biuret content in urea fertilizer may potentially be used as an alternative method to traditional wet chemical methods due to its simplicity, sensitivity, and portability.","PeriodicalId":1,"journal":{"name":"Accounts of Chemical Research","volume":null,"pages":null},"PeriodicalIF":16.4000,"publicationDate":"2022-11-28","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"Accounts of Chemical Research","FirstCategoryId":"92","ListUrlMain":"https://doi.org/10.1177/09670335221136546","RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q1","JCRName":"CHEMISTRY, MULTIDISCIPLINARY","Score":null,"Total":0}
引用次数: 0
Abstract
Simple, rapid, and reliable determination of the biuret content in urea fertilizer is very important for the development of fertilizer industry. A near infrared diffuse reflectance measurement system with a portable spectrometer was developed, in which the reference and dark background spectrum could also be recorded automatically in addition to the absorbance data. The key performances of the proposed NIR system have been tested on urea fertilizer. Numerical experiments showed that the coefficient of determination (R2) of the external validation set was 0.97, with a root mean square error (RMSE) of 0.04%. The ratios of the performance deviation (RPD) value in the calibration and validation sets were 12 and 3.5, respectively. It can be concluded that this NIR system for the determination of biuret content in urea fertilizer may potentially be used as an alternative method to traditional wet chemical methods due to its simplicity, sensitivity, and portability.
期刊介绍：
Accounts of Chemical Research presents short, concise and critical articles offering easy-to-read overviews of basic research and applications in all areas of chemistry and biochemistry. These short reviews focus on research from the author’s own laboratory and are designed to teach the reader about a research project. In addition, Accounts of Chemical Research publishes commentaries that give an informed opinion on a current research problem. Special Issues online are devoted to a single topic of unusual activity and significance.
Accounts of Chemical Research replaces the traditional article abstract with an article "Conspectus." These entries synopsize the research affording the reader a closer look at the content and significance of an article. Through this provision of a more detailed description of the article contents, the Conspectus enhances the article's discoverability by search engines and the exposure for the research.
京公网安备 11010802042870号
京ICP备2023020795号-1
分享
求助内容：
应助结果提醒方式：
扫码关注我们
