The Influence of Protein and Elastomer Waste Mixture on the NBR-Based Elastomer Compound

Abstract

The paper presents the influence of a mixture of elastomeric and protein waste from the footwear industry on the properties of elastomeric compounds based on NBR (butadiene-co-acrylonitrile) rubber, as well as their obtaining and characterization. The mixture of leather and rubber waste was cryogenically ground, in three grinding cycles, and the selected size was 0.35 mm, and the rotation speed of 14,000 rpm. After grinding, the leather and rubber waste mixture was functionalized with potassium oleate at a temperature of 60°C. The polymer compounds based on butadiene-co-acrylonitrile rubber (NBR) and the mixture of protein and elastomeric waste (in the ratio of 15, 20, 40, 50%) from the footwear industry were processed by mixing on an internal Brabender mixer, tested from a rheological, physical and mechanical point of view (hardness, elasticity and tensile strength) after conditioning for 24 h at room temperature according to the standards in force, but also by FT-IR spectroscopy performed with a double beam IR molecular absorption spectrometer, in the range 4000-400 cm-1, using the FT-IR Thermo Nicolet iS 50, equipped with ATR with diamond crystal. Following characterisation, it can be said that they present optimal values that fall within the standards for the footwear industry.