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Occupational Exposure of Footwear Roughing Dust during Footwear Manufacturing Process 鞋类生产过程中鞋类毛坯粉尘的职业性暴露
Q4 Engineering Pub Date : 2023-09-30 DOI: 10.24264/lfj.23.3.4
Md. Mehedi HASAN, Hossain ISLAM, Md. Mukter ALAM, Mongsathowai MARMA, Md. Rayhan SARKER
Footwear roughing dust (FRD) is generated from roughing operations involved in footwear manufacturing. The dust is created by the friction of emery paper against the grain surface of finished leather. FRD coming from finished leather is likely to contain chromium, which is widely used for leather processing. Generally, chromium is found in two forms in the leather industry, namely Cr (III) and Cr (VI), of which the latter has an evident and adverse effect on human health. This study aims to identify the major effects of FRD on workers’ health and to find out the correlation with the factors influencing those adverse health effects. In this study, a survey among 30 roughing operators from eight footwear factories in Bangladesh was conducted. The major health effects of FRD are eye irritation, skin itching, chest pain, coughing, and fatigue. This study constructed three hypotheses to investigate whether human health is affected by FRD with working experience, the age of workers, and the use of personal protective equipment (PPE). The results showed that working experience and use of PPE have distinct influences on the health effects caused by FRD, whereas workers’ age has no impact on their health effects. Finally, some recommendations are formulated to prevent or mitigate workers’ adverse health effects in order to ensure a better working environment in the footwear industry.
鞋类粗加工粉尘(FRD)是鞋类制造中涉及的粗加工操作产生的。灰尘是由砂纸与成品皮革的颗粒表面摩擦产生的。来自成品皮革的FRD可能含有铬,而铬被广泛用于皮革加工。在皮革工业中,铬通常以两种形式存在,即铬(III)和铬(VI),其中铬(VI)对人体健康有明显的不利影响。本研究旨在确定FRD对工人健康的主要影响,并找出影响这些不利健康影响的因素之间的相关性。在本研究中,对孟加拉国8家鞋厂的30名粗加工操作员进行了调查。FRD对健康的主要影响是眼睛刺激、皮肤瘙痒、胸痛、咳嗽和疲劳。本研究构建了三个假设,探讨FRD是否与工作经验、工人年龄和个人防护装备(PPE)的使用有关。结果表明,工作经验和PPE使用对FRD的健康影响显著,而工人年龄对FRD的健康影响不显著。最后,制定了一些建议,以防止或减轻工人对健康的不利影响,以确保鞋业有一个更好的工作环境。
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引用次数: 0
Production of Elastic Leathers from Horse Raw Material Using Activated Aqueous Solutions of Agent 用活化剂水溶液生产马原料弹力革
Q4 Engineering Pub Date : 2023-09-30 DOI: 10.24264/lfj.23.3.2
Anatolii DANYLKOVYCH, Oksana ROMANIUK, Tetiana NADOPTA
A step-by-step technology of formation of leather material made of horse raw materials using electrochemically activated aqueous solutions of chemical agents has been developed. Effective implementation of the leather raw material soaking process has been established due to the use of the optimal ratio of catholyte and anolyte. At the same time, environmentally hazardous agents are excluded from the process and its duration is reduced by two times compared to the current technology. The use of working solutions at the stages of liming and tanning with the use of catholyte and anolyte respectively, ensures the exclusion of environmentally hazardous chemical agents and the reduction of the processes duration. The developed technology of production of leather materials, unlike the existing ones, is characterized by simultaneous treatment of all anatomical areas of the hide.
研究了一种利用化学试剂的电化学活化水溶液逐步形成马原料皮革材料的工艺。采用最佳阴极液和阳极液配比,建立了皮革原料浸泡工艺的有效实施。同时,环境有害物质被排除在该过程之外,其持续时间比目前的技术缩短了两倍。在石灰化和鞣制阶段使用工作溶液,分别使用阴极液和阳极液,确保排除对环境有害的化学剂并减少过程持续时间。与现有的生产皮革材料的先进技术不同,其特点是同时处理皮革的所有解剖区域。
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引用次数: 0
Influence of Atmospheric Conditions on the Polymer Composite Based on NBR Rubber and Functionalized Protein Waste 大气条件对丁腈橡胶与功能化蛋白废弃物聚合物复合材料的影响
Q4 Engineering Pub Date : 2023-09-30 DOI: 10.24264/lfj.23.3.3
Mihaela NIŢUICĂ (VÎLSAN), Maria SÖNMEZ, Mihai GEORGESCU, Maria Daniela STELESCU, Dana GURĂU, Bogdan Florin RUSU, Andrei DUMITRU, Constantin-Vlad BĂRBULESCU
Technology has progressed a lot in the last 20 years, today it is possible to obtain new polymer composites that show performance properties. The ever-increasing demand for new high-performance materials has determined the appearance of new polymer structures based on elastomers and various wastes (protein, cellulosic, elastomeric, etc.) from various fields (shoes, leather goods, etc.). This paper describes the obtaining and characterization of polymer composites based on NBR rubber (butadiene-co-acrylonitrile) and protein waste from the footwear and leather goods industry, cryogenically ground to micrometric dimensions and modified with PDMS (polydimethyl siloxane). PDMS has the role of a plasticizer, but at the same time it improves the dispersion of protein waste mixed in the polymer matrix. The polymer composites were obtained by the mixing technique and tested from a physical-mechanical point of view according to the standards in force. The characterization in normal condition and accelerated aging at 70°C for 168 h (it was carried out hot, using the hot air circulation oven method) was carried out after the samples were subjected to conditioning for 24 h at ambient temperature. Also, the polymer composite samples were subjected for 365 days to atmospheric conditions (sun, rain, wind, hail, light, etc.) to see their influence on the properties of the obtained polymer composites.
在过去的20年里,技术取得了很大的进步,今天有可能获得具有性能的新型聚合物复合材料。对新型高性能材料不断增长的需求决定了基于弹性体和各种废物(蛋白质、纤维素、弹性体等)的新型聚合物结构的出现,这些废物来自各个领域(鞋、皮革制品等)。本文介绍了以丁腈橡胶(丁二烯-共丙烯腈)和鞋类和皮革制品工业的蛋白质废料为基础,低温研磨至微米尺寸,用聚二甲基硅氧烷(PDMS)改性的聚合物复合材料的制备和表征。PDMS具有增塑剂的作用,但同时它改善了混合在聚合物基质中的蛋白质废物的分散。采用混合法制备了聚合物复合材料,并按现行标准从物理力学角度进行了测试。样品在室温条件下调理24 h后,进行常温和70℃加速时效168 h的表征(热态,采用热风循环烘箱法)。此外,将聚合物复合材料样品置于365天的大气条件下(太阳、雨、风、冰雹、光等),以观察它们对所获得的聚合物复合材料性能的影响。
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引用次数: 0
Personal Design, the New Fashion Trend with Applications of Innovative Technologies 个人设计,新时尚潮流与创新技术的应用
Q4 Engineering Pub Date : 2023-09-30 DOI: 10.24264/lfj.23.3.5
Traian FOIAȘI, Mirela PANTAZI-BĂJENARU, Dana GURĂU
The development of 3D technology has brought opportunities and challenges to the shoe industry, as people’s living standards have improved due to economic development, and people have increasing requirements for shoe design. They have become more critical, active and informed. They pursue customized products/services and like to be involved in the design process. Additive manufacturing technologies enable this customization of products and new business models should embrace these trends to differentiate themselves and gain competitive advantage. The application of 3D technology is widespread in various fields, including footwear production. From a physical model, it is possible to create a digital model using 3D scanning technology for redesign purposes. The use of 3D printing technology can enable faster modeling of footwear products, enrich the shape of footwear and meet the aesthetic needs of footwear designers. Therefore, the article studies and analyzes the top technologies in fashion, 3D shoe printing technology.
3D技术的发展给制鞋行业带来了机遇和挑战,因为经济的发展提高了人们的生活水平,人们对鞋子设计的要求也越来越高。他们变得更挑剔、更活跃、更见多识广。他们追求定制的产品/服务,喜欢参与设计过程。增材制造技术能够实现产品的定制化,新的商业模式应该拥抱这些趋势,以实现差异化并获得竞争优势。3D技术的应用在包括鞋类生产在内的各个领域都很广泛。从一个物理模型,可以创建一个数字模型,使用3D扫描技术重新设计的目的。利用3D打印技术,可以更快地对鞋类产品进行建模,丰富鞋类的造型,满足鞋类设计师的审美需求。因此,本文对时尚领域的前沿技术——3D鞋打印技术进行了研究和分析。
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引用次数: 0
Keratin Hydrolysate from Wool By-products as an Additive for Dyeing Bovine Leathers 羊毛副产品角蛋白水解物在牛皮革染色中的应用
Q4 Engineering Pub Date : 2023-09-30 DOI: 10.24264/lfj.23.3.1
Mariana Daniela BERECHET, Carmen GAIDĂU, Demetra SIMION, Claudiu ȘENDREA
In this research, the aim was to obtain keratin hydrolysate from wool waste from sheep breeders and use it in technologies for dyeing bovine hides. The keratin hydrolysate (KerNa), obtained by alkaline hydrolysis with sodium hydroxide, was physico-chemically analyzed, determining the protein substance in the amount of 80.65%, highlighting the bands specific to peptides and compounds with sulfur by FTIR spectroscopy and particle size by DLS technique, obtaining majority populations at 161 nm and 615 nm. Bovine hides were treated with keratin hydrolysate, in different stages of the dyeing process, and an increase in the dyeing resistance to wet and dry rubbing and the dyeing resistance to water drops was obtained, as well as the improvement of the specific color parameters. Leathers dyed with the use of the KerNa additive showed an increase in the friction resistance of the dyeing (grade 5/5) and brighter colors according to ISO Brightness. Treatments based on protein-rich keratin hydrolysate, applied in various stages of the dyeing process, interact with the leather’s collagen or tanning agents, giving the finished leathers improved properties of shade, shine and softness. The good results obtained in the applications of keratin hydrolysate in the leather industry show that the keratin extract can be the basis for obtaining new biomaterials with various applications. The utilization of wool waste from animal husbandry leads to a decrease in the amount of waste and the prevention of environmental pollution.
本研究的目的是从绵羊饲养者的羊毛废料中获得角蛋白水解物,并将其用于牛皮染色技术。对氢氧化钠碱性水解得到的角蛋白水解产物(KerNa)进行理化分析,确定了80.65%的蛋白质物质,FTIR光谱突出了多肽和含硫化合物的特异波段,DLS技术突出了粒径,在161 nm和615 nm处获得了大多数群体。用水解角蛋白处理牛皮,在不同的染色阶段,获得了抗干湿摩擦染色和抗水滴染色的效果,并改善了特定的颜色参数。使用KerNa添加剂染色的皮革显示出染色的耐摩擦性增加(5/5级)和根据ISO亮度更亮的颜色。基于富含蛋白质的角蛋白水解物的处理,应用于染色过程的各个阶段,与皮革的胶原蛋白或鞣制剂相互作用,使成品皮革的阴影,光泽和柔软性得到改善。角蛋白水解物在皮革工业中的应用取得了良好的效果,表明角蛋白提取物可作为获得具有多种用途的新型生物材料的基础。利用畜牧业产生的羊毛废料,可以减少废物的数量,防止环境污染。
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引用次数: 0
Environmental Sustainability: A Challenge for Leather Industry 环境可持续性:皮革工业面临的挑战
Q4 Engineering Pub Date : 2023-09-30 DOI: 10.24264/lfj.23.3.6
Kanij FATEMA, Md. Rayhan SARKER, Kawsar AKHTAR, Aklima BEGUM, Shafiqul ISLAM
Adopting pollution prevention strategies (PPS) can ensure environmental sustainability (ES) in the leather industry and can help the industry achieve several sustainable development goals (SDGs). In order to ensure the ES of the leather industry, there is a need for research to identify a comprehensive list of PPS. This research aims at identifying the most effective PPS for the leather industry, which are categorized into 4R (reduce, reuse, recycle, and recover) dimensions. This is a case study where four leather processing companies from Bangladesh were purposively selected. Through an extensive literature review and experts’ opinions, 21 PPS are identified for the leather industry’s ES. Also, this study shows several benefits of PPS through which various SDGs can be achieved in the leather industry. This study will certainly guide the leather industry managers to ensure the ES of the leather industry and, consequently, assist in achieving several SDGs.
采用污染预防策略(PPS)可以确保皮革行业的环境可持续性(ES),并可以帮助该行业实现几个可持续发展目标(sdg)。为了确保皮革行业的ES,有必要研究确定一个全面的PPS清单。本研究旨在为皮革行业确定最有效的PPS,分为4R(减少,再利用,再循环和回收)维度。这是一个案例研究,其中四家皮革加工公司从孟加拉国被有意选择。通过广泛的文献回顾和专家的意见,21 PPS被确定为皮革行业的ES。此外,这项研究显示了PPS的几个好处,通过它可以在皮革行业实现各种可持续发展目标。这项研究肯定会指导皮革行业管理者确保皮革行业的ES,从而协助实现几个可持续发展目标。
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引用次数: 0
Effect of Custom-Made Orthotic Insoles on Lower Limb Biomechanics in Children with Flexible Flat Feet 定制矫形鞋垫对柔性平足儿童下肢生物力学的影响
Q4 Engineering Pub Date : 2023-06-30 DOI: 10.24264/lfj.23.2.2
Yunqi TANG, Shizhe CHENG, Lingqiu ZOU, Liying ZHOU, Peiyao LIANG, Hui REN, Xiaoli LIU
This study aimed to investigate the effect of custom-made orthotic insoles on the lower limb biomechanics in children with flexible flat feet. A sample of 27 children (19 boys and eight girls) aged 7 to 13 years old with flexible flat feet participated in the study. Each custom-made orthotic insole was individually designed based on the foot of each subject, using ethylene-vinyl acetate (EVA) material with medium density. The study was conducted using a gait analysis laboratory, and participants were required to walk randomly at a self-selected speed with one of three insole conditions (custom-made orthotic insole, flat insole, and barefoot). The data was processed using Visual 3D software and analyzed by SPSS software. The results showed that using custom-made orthotic insoles resulted in a significant reduction in the maximum ankle inversion angle and ankle inversion moment while increasing the knee adduction moment during the stance phase when compared to wearing either flat insoles or being barefoot (p<0.05). This study found that custom-made orthotic insoles significantly altered the biomechanical characteristics of the lower limbs of children with flexible flat feet, reducing the movement of the ankle joint in the frontal plane, thereby enhancing ankle joint stability, but may increase knee joint load.
本研究旨在探讨定制矫形鞋垫对柔性平足儿童下肢生物力学的影响。27名年龄在7到13岁之间、患有柔性扁平足的儿童(19名男孩和8名女孩)参与了这项研究。每个定制的矫正鞋垫都是根据每个受试者的脚单独设计的,使用中密度的乙烯-醋酸乙烯酯(EVA)材料。该研究在步态分析实验室进行,参与者被要求以自己选择的速度随机行走,并在三种鞋垫条件中选择一种(定制矫正鞋垫、平鞋垫和赤脚)。数据采用Visual 3D软件处理,SPSS软件分析。结果显示,与穿平鞋垫或赤脚相比,使用定制矫正鞋垫显著降低了站立阶段的最大踝关节倒置角度和踝关节倒置力矩,同时增加了膝关节内收力矩(p<0.05)。本研究发现,定制的矫形鞋垫明显改变了柔性扁平足儿童下肢的生物力学特征,减少了踝关节在额平面的运动,从而增强了踝关节的稳定性,但可能会增加膝关节负荷。
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引用次数: 0
Expert Examination of Leather in International Trade: Ukrainian Experience 国际贸易中皮革的专家检验:乌克兰的经验
Q4 Engineering Pub Date : 2023-06-30 DOI: 10.24264/lfj.23.2.3
Taras KARAVAYEV, Olena MOKROUSOVA, Kateryna YAZVINSKA, Maryna ZHALDAK, Valentyna TKACHUK
In the article the state of the market, volumes of export and import of leather are analyzed. The procedure of leather identification expert examination for customs purposes in international trade is showed. Identification expert examination of leather was carried out and its results were issued for customs purposes. The code of leather according to the Harmonized Commodity Description and Coding System (HS) and the Ukrainian Classification of Goods for Foreign Economic Activity (UСGFEA) is defined based on the results of identification expert examination.
本文对皮革的市场状况、进出口规模进行了分析。介绍了国际贸易中海关皮革鉴定专家鉴定的程序。本署对皮革进行鉴定专家检验,并发出鉴定结果供海关使用。根据协调商品名称及编码制度(HS)和乌克兰对外经济活动货物分类(UСGFEA),皮革的编码是根据鉴定专家审查的结果确定的。
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引用次数: 0
Supercritical Fluid Extracted Chestnut Tannin as Natural Biocide for Soaking Beamhouse Process of Leather Production 超临界流体萃取板栗单宁作为天然杀菌剂在皮革生产中的应用
Q4 Engineering Pub Date : 2023-06-30 DOI: 10.24264/lfj.23.2.1
Ersin ONEM
Microorganism activity during soaking beamhouse process of leather production is highly dangerous and should be kept under control. Some chemical components are used for this purpose to protect the hides/skins against microbial activities. Because of the banned and restricted substances due to the environmental and health risks in the recent times, natural active ingredients are considered for industrial production as sustainability. Moreover, supercritical fluid extraction as an environmentally friendly technology is applied to isolate biologically active extracts and supercritical extracted natural compounds are reported as potential antioxidant and antibacterial agent for several applications. In this study, supercritical fluid extracted chestnut tannin was used in soaking process of leather production and was determined as potential natural biocide with very good effect against microorganism activity in the process floats.
皮革生产过程中,微生物活动具有高度危险性,应加以控制。一些化学成分用于保护皮革免受微生物活动的侵害。由于近年来由于环境和健康风险而被禁止和限制的物质,天然活性成分被认为是工业生产的可持续性。此外,超临界流体萃取作为一种环境友好的技术被用于分离生物活性提取物,超临界萃取的天然化合物被报道为潜在的抗氧化剂和抗菌剂。本研究将超临界流体提取板栗单宁用于制革浸渍工艺,确定板栗单宁是一种潜在的天然杀菌剂,对工艺浮子中的微生物活性有很好的抑制作用。
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引用次数: 0
Applications of Enzymes as Ecologic Alternatives in the Leather Industry 酶作为生态替代品在皮革工业中的应用
Q4 Engineering Pub Date : 2023-06-30 DOI: 10.24264/lfj.23.2.4
Demetra SIMION, Carmen GAIDĂU, Gabriela PĂUN, Daniela BERECHET
The aim of this paper is to study the applications of enzymes, as ecological alternatives in the leather industry. The research proposes to create ecologic leathers/furs with additional functions (non-toxic, with high-quality of soft, well-degreased surfaces) through the use of original enzyme-based biotechnologies, as new additives for leather/fur processing intended for everyday use. Another application of the enzymes studied in this paper is the development of a novel technology based on enzymes and membrane technique, for purifying wastewaters from the leather industry. We selected and analytically characterized lipases, proteases, and also new enzymes: lysozyme, tryptophan deaminase for use in leather industry. The goal was to obtain leathers/furs for everyday use, with high-performance characteristics, by processing them with enzymes – as new additives that have not been used so far in the leather industry as an alternative to the use of potentially polluting chemical materials. Complex and original technologies of ecological bioprocessing of leather/furs were used. The innovation consists in developing new biotechnologies for leather/fur with enzymatic additives in order to achieve ecologic leathers or fur articles. These biotechnologies provided advanced performances for surface quality: intense and bright colors, soft, well-degreased, and resistant to abrasion and water.
本文的目的是研究酶作为生态替代品在皮革工业中的应用。该研究建议通过使用原始的酶基生物技术来创造具有附加功能(无毒,高质量柔软,表面脱脂良好)的生态皮革/毛皮,作为日常使用的皮革/毛皮加工的新添加剂。本文研究的酶的另一个应用是开发一种基于酶和膜技术的新技术,用于净化皮革工业废水。我们选择并分析表征了用于皮革工业的脂肪酶、蛋白酶以及新的酶:溶菌酶、色氨酸脱氨酶。目标是通过酶处理获得具有高性能特性的日常使用的皮革/毛皮-作为迄今尚未在皮革工业中使用的新添加剂,作为使用可能污染的化学材料的替代品。采用复杂的、独创的皮革/毛皮生态生物加工技术。创新在于开发新的皮革/毛皮生物技术,添加酶添加剂,以实现生态皮革或毛皮制品。这些生物技术为表面质量提供了先进的性能:强烈而明亮的颜色,柔软,脱脂良好,耐磨损和耐水。
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引用次数: 0
期刊
Leather and Footwear Journal
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