Adsorption Kinetics of Chromium (VI) from Aqueous Solution Using an Anion Exchange Resin

IF 1.8 4区 化学 Q3 CHEMISTRY, ANALYTICAL Analytical Letters Pub Date : 2020-03-17 DOI:10.1080/00032719.2020.1731523
C. Marcu, C. Varodi, Ancuţa Balla
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引用次数: 10

Abstract

Abstract In the present study, batch experiments were performed to remove chromium (VI) from aqueous solutions using an anion exchange resin. In order to investigate the kinetic mechanism which controls the chromium (VI) adsorption, four kinetic models were used: pseudo-first order, pseudo-second order, the Elovich equation and the intraparticle diffusion model. In reaction with 1,5 diphenylcarbazide, chromium (VI) forms a complex, which was analyzed at 540 nm using a spectrophotometer after 7 min. The Cr (VI) adsorption process was well described by the pseudo-second order kinetic model for 0.1 to 0.3 g/L Cr (VI).
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阴离子交换树脂从水溶液中吸附铬(VI)的动力学
摘要在本研究中,使用阴离子交换树脂进行了从水溶液中去除铬(VI)的分批实验。为了研究控制铬(VI)吸附的动力学机制,使用了四个动力学模型:拟一阶、拟二阶、Elovich方程和颗粒内扩散模型。在与1,5二苯基咔唑的反应中,铬(VI)形成络合物,在540进行分析 nm,在7 min。Cr(VI)吸附过程通过0.1至0.3的伪二阶动力学模型得到了很好的描述 g/L Cr(VI)。
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来源期刊
Analytical Letters
Analytical Letters 化学-分析化学
CiteScore
4.10
自引率
5.00%
发文量
218
审稿时长
2.1 months
期刊介绍: Analytical Letters is an international medium for the rapid publication of original research papers, accelerated articles, or mini-reviews on important developments in all areas of analytical chemistry, including electrochemistry, mass spectrometry, separations, and spectroscopy. Papers are welcomed that consider fundamental developments, new or improved instrumentation and sensors, and applications of analytical chemistry in all areas that include biological and clinical science, engineering and instrumentation science, environmental chemistry and analysis, geochemistry, materials science, nanotechnology, and physics.
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