{"title":"Reference Correlation for the Viscosity of Cyclopentane from the Triple Point to 460 K and up to 380 MPa","authors":"K. Α. Tasidou, M. Huber, Marc J. Assael","doi":"10.1063/1.5128321","DOIUrl":null,"url":null,"abstract":"This paper presents a new wide-ranging correlation for the viscosity of cyclopentane based on critically evaluated experimental data. The correlation is designed to be used with a recently developed equation of state, and it is valid from the triple point to 360 K in the liquid range up to 380 MPa and 460 K in the low-pressure vapor range. The average absolute percent deviation of the fit for all primary data is 0.8% with a bias of −0.3%. The estimated expanded uncertainty of the whole fit is 2.7% (at the 95% confidence level), while the uncertainty near atmospheric pressure from 298 K to 460 K increases to 4%. The correlation behaves in a physically reasonable manner when extrapolated to 500 MPa; however, care should be taken when using the correlations outside of the validated range.This paper presents a new wide-ranging correlation for the viscosity of cyclopentane based on critically evaluated experimental data. The correlation is designed to be used with a recently developed equation of state, and it is valid from the triple point to 360 K in the liquid range up to 380 MPa and 460 K in the low-pressure vapor range. The average absolute percent deviation of the fit for all primary data is 0.8% with a bias of −0.3%. The estimated expanded uncertainty of the whole fit is 2.7% (at the 95% confidence level), while the uncertainty near atmospheric pressure from 298 K to 460 K increases to 4%. The correlation behaves in a physically reasonable manner when extrapolated to 500 MPa; however, care should be taken when using the correlations outside of the validated range.","PeriodicalId":16783,"journal":{"name":"Journal of Physical and Chemical Reference Data","volume":"48 1","pages":"043101"},"PeriodicalIF":4.4000,"publicationDate":"2019-11-14","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://sci-hub-pdf.com/10.1063/1.5128321","citationCount":"3","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"Journal of Physical and Chemical Reference Data","FirstCategoryId":"5","ListUrlMain":"https://doi.org/10.1063/1.5128321","RegionNum":2,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q2","JCRName":"CHEMISTRY, MULTIDISCIPLINARY","Score":null,"Total":0}
引用次数: 3
Abstract
This paper presents a new wide-ranging correlation for the viscosity of cyclopentane based on critically evaluated experimental data. The correlation is designed to be used with a recently developed equation of state, and it is valid from the triple point to 360 K in the liquid range up to 380 MPa and 460 K in the low-pressure vapor range. The average absolute percent deviation of the fit for all primary data is 0.8% with a bias of −0.3%. The estimated expanded uncertainty of the whole fit is 2.7% (at the 95% confidence level), while the uncertainty near atmospheric pressure from 298 K to 460 K increases to 4%. The correlation behaves in a physically reasonable manner when extrapolated to 500 MPa; however, care should be taken when using the correlations outside of the validated range.This paper presents a new wide-ranging correlation for the viscosity of cyclopentane based on critically evaluated experimental data. The correlation is designed to be used with a recently developed equation of state, and it is valid from the triple point to 360 K in the liquid range up to 380 MPa and 460 K in the low-pressure vapor range. The average absolute percent deviation of the fit for all primary data is 0.8% with a bias of −0.3%. The estimated expanded uncertainty of the whole fit is 2.7% (at the 95% confidence level), while the uncertainty near atmospheric pressure from 298 K to 460 K increases to 4%. The correlation behaves in a physically reasonable manner when extrapolated to 500 MPa; however, care should be taken when using the correlations outside of the validated range.
期刊介绍:
The Journal of Physical and Chemical Reference Data (JPCRD) is published by AIP Publishing for the U.S. Department of Commerce National Institute of Standards and Technology (NIST). The journal provides critically evaluated physical and chemical property data, fully documented as to the original sources and the criteria used for evaluation, preferably with uncertainty analysis. Critical reviews may also be included if they document a reference database, review the data situation in a field, review reference-quality measurement techniques, or review data evaluation methods.