Vis-active photocatalytic composite thin films for advanced wastewater treatment

I. Tismanar, A. Duţă
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Abstract

Conventional wastewater treatment processes are preparing the water for discharge thus it still contains small amounts of pollutants. For re-use, advanced wastewater treatment is required and heterogeneous photocatalysis represent a viable path for removing organic pollutants at very low concentrations but still above the discharge limit. The mostly investigated photocatalyst is TiO2 that is a wide band gap semiconductor that can be activated only using UV radiation. However, for large-scale implementation of advanced wastewater treatment, there are required efficient and affordable processes, thus Vis- or solar-activated photocatalysts. Attempts on extending the photocatalytic response towards Vis are under intensive research including the development of composite structures with TiO2 matrix and various fillers that are discussed through this paper. The latest results involving carbon-based fillers are presented along with the extended use of the composites acting also as self-cleaning coatings.
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用于深度废水处理的可见光催化复合薄膜
传统的废水处理工艺是为排放水做准备,因此它仍然含有少量污染物。对于再利用,需要对废水进行深度处理,而多相光催化是去除极低浓度但仍高于排放限值的有机污染物的可行途径。研究最多的光催化剂是TiO2,它是一种宽带隙半导体,只能使用紫外线辐射激活。然而,为了大规模实施先进的废水处理,需要高效且价格合理的工艺,因此需要Vis或太阳能活化的光催化剂。将光催化响应扩展到Vis的尝试正在进行深入的研究,包括开发具有TiO2基质和各种填料的复合结构,本文对此进行了讨论。介绍了碳基填料的最新结果,以及复合材料作为自清洁涂层的广泛使用。
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