Thermo-chemo-mechanical influences of impingement flow on the degradation of organic coatings in the underwater zone of offshore wind turbines

IF 2.3 4区 材料科学 Q2 Chemistry Journal of Coatings Technology and Research Pub Date : 2022-10-12 DOI:10.1007/s11998-022-00677-z
Amin Vedadi, Al Habib Ullah, Charles Fabijanic, Jordi Estevadeordal, Yechun Wang
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引用次数: 1

Abstract

Most offshore wind turbines use monopile structures anchored to seabed. In the underwater zone of these structures, water attacks the surface of the steel monopiles which is protected by organic coatings. The influence of applied stresses due to the water flow on the degradation of organic coatings is the focus of this study. For this purpose, an impingement flow chamber was employed to resemble the situation of monopile structures exposed to the shallow water currents in underwater zone. Electrochemical impedance spectroscopy was utilized to measure the changes of barrier properties of coatings exposed to the impingement flow of a 3.5 wt% NaCl solution with a variety of flow rates. Computational fluid dynamics (CFD) modeling as well as the particle image velocimetry measurements were employed to calculate and validate the magnitude of applied stresses on the surface of the coated samples. Thermal activation theory, thermal elasticity laws, and the Fick’s laws were utilized to investigate and analyze the influence of stresses on coating properties. The comparison among the obtained electrochemical parameters under different flow rates shows the direct influence of stresses on the degradation of the coatings. The utilized methods, in addition to the developed analytical procedure, can potentially predict the behavior of organic coatings applied on offshore wind turbines in underwater zone. It was concluded that the applied stresses do not influence the apparent diffusion coefficient of water in coatings, but a higher flow rate increases the volume fraction of water and coating capacitance significantly.

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冲击流对海上风力机水下区有机涂层降解的热-化学-力学影响
大多数海上风力涡轮机使用锚定在海底的单桩结构。在这些结构的水下区域,水侵蚀由有机涂层保护的钢单桩表面。本文重点研究了水流作用下的外加应力对有机涂层降解的影响。为此,采用冲击流室模拟单桩结构暴露在水下浅水流中的情况。采用电化学阻抗谱法测定了不同流速下3.5 wt% NaCl溶液冲击流对涂层阻挡性能的影响。采用计算流体力学(CFD)建模和粒子图像测速方法计算并验证了涂层样品表面的外加应力大小。利用热活化理论、热弹性定律和菲克定律研究和分析了应力对涂层性能的影响。不同流速下得到的电化学参数的比较表明,应力对涂层的降解有直接影响。所采用的方法,加上开发的分析程序,可以潜在地预测用于海上风力涡轮机的水下区域的有机涂层的行为。结果表明,施加应力对水在涂层中的表观扩散系数没有影响,但较高的流速可显著提高水的体积分数和涂层电容。
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来源期刊
Journal of Coatings Technology and Research
Journal of Coatings Technology and Research CHEMISTRY, APPLIED-MATERIALS SCIENCE, COATINGS & FILMS
CiteScore
4.40
自引率
8.70%
发文量
0
期刊介绍: Journal of Coatings Technology and Research (JCTR) is a forum for the exchange of research, experience, knowledge and ideas among those with a professional interest in the science, technology and manufacture of functional, protective and decorative coatings including paints, inks and related coatings and their raw materials, and similar topics.
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