Renewable non-edible oils derived long chain (C24.1) bio-based zwitterionic surfactant with ultralow interfacial tension between crude oil and formation brine

Abstract

A new ultra-long chain monounsaturated 4-(N-nervonicamidopropyl-N,N-dimethylammonium) butane sulfonate (NDAS) zwitterionic surfactant with ultralow interfacial tensions was developed through the modification of nervonic acid derived from renewable non-edible seed oils by a simple and effective method. Its structure was characterized by ESI-HRMS, ¹H NMR, and ¹³C NMR. NDAS surfactant exhibited a strong interfacial activity (∼10⁻⁴ mN/m) between the crude oil and the formation brine at a very low surfactant dosage (0.05 g/L) and at high salinity conditions, which is equivalent to 2% (w/w) of dosage of the most traditional surfactants used in the enhanced oil recovery field. Meanwhile, at a very low concentration (0.05 g/L), NDAS demonstrated strong NaCl compatibility up to 100 g/L, Ca²⁺ ions compatibility up to 200 mg/L, and temperature stability up to 90 °C. The surface tension, emulsification, and biodegradability parameters were also evaluated. This work consolidates our hypothesis that increasing the hydrophobic chain length of a surfactant certainly contributes to the high interfacial activity and good compatibility of salts and temperatures. Hence, it will facilitate the design of a sustainable alternative to petroleum-based chemicals to develop bio-based surfactants and extend the domain of bio-based surfactants to new applications such as in enhanced oil recovery (EOR).