Lipid extraction and CO2 capture with switchable polarity solvent

IF 6.4 3区 环境科学与生态学 Q2 ENERGY & FUELS Carbon Resources Conversion Pub Date : 2023-06-05 DOI:10.1016/j.crcon.2023.05.005
Kejing Wu , Chuandong Tao , Shanjin Zeng , Yingying Liu , Bin Liang , Houfang Lu
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Abstract

In this study, lipid extraction and CO2 capture are combined using N, N-dimethylcyclohexylamine (DMCHA) as switchable polarity solvent. The effects of operation parameters are discussed according to the CO2 absorption/desorption and lipid/DMCHA recovery results. A triphasic models considering lipid, water, and gas phases are established to analyze the kinetic behaviors. The results show that DMCHA is reversible through CO2 absorption/desorption, and the enhanced dispersion of droplets and bubbles in water phase improves the lipid/DMCHA recovery and CO2 absorption/desorption. The triphasic kinetic models fit well with experimental data, and gas–liquid mass transfer is regarded as the rate-determining step. The lower interfacial areas result in the poorer gas–liquid mass transfer for the DMCHA recovery than lipid recovery process.

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脂质提取和二氧化碳捕获与切换极性溶剂
本研究采用N, N-二甲基环己胺(DMCHA)作为极性转换溶剂,将脂质提取和CO2捕获相结合。根据CO2的吸收/解吸和脂质/DMCHA的回收结果,讨论了操作参数的影响。建立了考虑脂相、水相和气相的三相模型来分析其动力学行为。结果表明,DMCHA通过CO2吸收/解吸是可逆的,水滴和气泡在水相中的分散增强,提高了脂质/DMCHA的回收率和CO2的吸收/解吸。三相动力学模型与实验数据吻合较好,并将气液传质作为速率决定步骤。较低的界面面积导致DMCHA回收过程的气液传质比脂质回收过程差。
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来源期刊
Carbon Resources Conversion
Carbon Resources Conversion Materials Science-Materials Science (miscellaneous)
CiteScore
9.90
自引率
11.70%
发文量
36
审稿时长
10 weeks
期刊介绍: Carbon Resources Conversion (CRC) publishes fundamental studies and industrial developments regarding relevant technologies aiming for the clean, efficient, value-added, and low-carbon utilization of carbon-containing resources as fuel for energy and as feedstock for materials or chemicals from, for example, fossil fuels, biomass, syngas, CO2, hydrocarbons, and organic wastes via physical, thermal, chemical, biological, and other technical methods. CRC also publishes scientific and engineering studies on resource characterization and pretreatment, carbon material innovation and production, clean technologies related to carbon resource conversion and utilization, and various process-supporting technologies, including on-line or off-line measurement and monitoring, modeling, simulations focused on safe and efficient process operation and control, and process and equipment optimization.
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Outside Front Cover Outside Back Cover Developments and challenges on enhancement of photocatalytic CO2 reduction through photocatalysis Outside Front Cover Outside Back Cover
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