Remediation of cesium-contaminated fine soil using electrokinetic method

IF 0.8 4区 工程技术 Q4 ENGINEERING, CHEMICAL Membrane Water Treatment Pub Date : 2020-05-01 DOI:10.12989/MWT.2020.11.3.189
Ilgook Kim, June-Hyun Kim, Sung-Man Kim, C. Park, Hee-Man Yang, I. Yoon
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Abstract

In this study, electrokinetic remediation equipment was used to remove cesium (Cs) from clay soil and waste solution was treated with sorption process. The influence of electrokinetic process on the removal of Cs was evaluated under the condition of applied electric voltage of 15.0-20.0 V. In addition to monitoring the Cs removal, electrical current and temperature of the electrolyte during experiment were investigated. The removal efficiency of Cs from soil by electrokinetic method was more than 90%. After electrokinetic remediation, Cs was selectively separated from soil waste solution using sorbents. Various adsorption agents such as potassium nickel hexacyanoferrate (KNiHCF), Prussian blue, sodium tetraphenylborate (NaTPB), and zeolite were compared and KNiHCF showed the highest Cs removal efficiency. The Cs adsorption on KNiHCF reached equilibrium in 30 min. The maximum adsorption capacity was 120.4 mg/g at 0.1 g/L of adsorbent dosage. These results demonstrated that our proposed process combined electrokinetic remediation of soil and waste solution treatment with metal ferrocyanide can be a promising technique to decontaminate Cs-contaminated fine soil.
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用电动法修复铯污染的细土
本研究采用电动修复设备去除粘土中的铯,并对废液进行吸附处理。在外加电压15.0-20.0V的条件下,评估了电动过程对Cs去除的影响。除了监测Cs的去除外,还研究了实验过程中电解质的电流和温度。电动法对土壤中Cs的去除率达90%以上。在电动修复后,利用吸附剂从土壤废液中选择性分离Cs。比较了六氰基高铁酸镍钾(KNiHCF)、普鲁士蓝、四苯基硼酸钠(NaTPB)和沸石等吸附剂对Cs的去除效果,发现KNiHCFCs的去除效率最高。Cs在KNiHCF上的吸附在30min内达到平衡。在0.1g/L的吸附剂用量下,最大吸附量为120.4mg/g。这些结果表明,我们提出的土壤电动修复和金属亚铁氰化物废液处理相结合的工艺是一种很有前途的净化Cs污染细土壤的技术。
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来源期刊
Membrane Water Treatment
Membrane Water Treatment ENGINEERING, CHEMICAL-WATER RESOURCES
CiteScore
1.90
自引率
30.00%
发文量
0
审稿时长
>12 weeks
期刊介绍: The Membrane and Water Treatment(MWT), An International Journal, aims at opening an access to the valuable source of technical information and providing an excellent publication channel for the global community of researchers in Membrane and Water Treatment related area. Specific emphasis of the journal may include but not limited to; the engineering and scientific aspects of understanding the basic mechanisms and applying membranes for water and waste water treatment, such as transport phenomena, surface characteristics, fouling, scaling, desalination, membrane bioreactors, water reuse, and system optimization.
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