V. Arivalagan, M. Meera, Devaraj Stephen, M. Soundarrajan, . SGGunasekaran
{"title":"Phthalide cardo chain extended imine skeletal linked maleimido end capped nanotitania reinforced novel polybenzoxazine (nTiO2/PBZ) hybrid nanocomposites","authors":"V. Arivalagan, M. Meera, Devaraj Stephen, M. Soundarrajan, . SGGunasekaran","doi":"10.1177/09540083231162516","DOIUrl":null,"url":null,"abstract":"A new class of nanotitania reinforced polybenzoxazine (nTiO2/PBZ) hybrid nanocomposites was synthesized using newly designed phthalide cardo chain extended imine skeletal linked maleimido end capped polybenzoxazine (PHM-PBZ) and nTiO2 through in-situ sol-gel method. The formation of hybrid nanocomposites was confirmed by NMR and FT-IR spectra. The structurally stable nTiO2 present in the nTiO2/PBZ hybrids accounted their exceptional thermal stability and good char yield. The restricted motion of flexible polymeric chain resulted from the inclusion of nTiO2 in the PBZ system increased the glass transition temperature (T g ) to a higher percentage than that of neat PBZ system. With the successive enhancement in the incorporation of nTiO2, the synthesized nanocomposites exhibited better thermal stability, higher flame retardancy and lesser water absorption behaviour than the of neat PBZ. The sequential increments in the loading level of nTiO2 onto the PBZ matrices caused the lower value of dielectric constant than that of neat PBZ. The homogeneity and successful dispersion of the nTiO2 fillers in the PBZ matrix were ascertained from the strong fluorescent emissions observed in the wavelength range of 300–550 nm through optical studies. Scanning electron microscope and transmission electron microscopic micrographs evidenced the successful incorporation of nTiO2 as can be seen from the different morphology at the nanoscale level in the PBZ matrix. This kind of structurally designed nTiO2/PBZ nanocomposites may find multifaceted applications in the form of adhesives, encapsulants, matrices and sealants and in the fields of automobile and microelectronics applications for better performance and longevity.","PeriodicalId":12932,"journal":{"name":"High Performance Polymers","volume":"35 1","pages":"697 - 716"},"PeriodicalIF":1.8000,"publicationDate":"2023-03-14","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"High Performance Polymers","FirstCategoryId":"92","ListUrlMain":"https://doi.org/10.1177/09540083231162516","RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q3","JCRName":"POLYMER SCIENCE","Score":null,"Total":0}
引用次数: 0
Abstract
A new class of nanotitania reinforced polybenzoxazine (nTiO2/PBZ) hybrid nanocomposites was synthesized using newly designed phthalide cardo chain extended imine skeletal linked maleimido end capped polybenzoxazine (PHM-PBZ) and nTiO2 through in-situ sol-gel method. The formation of hybrid nanocomposites was confirmed by NMR and FT-IR spectra. The structurally stable nTiO2 present in the nTiO2/PBZ hybrids accounted their exceptional thermal stability and good char yield. The restricted motion of flexible polymeric chain resulted from the inclusion of nTiO2 in the PBZ system increased the glass transition temperature (T g ) to a higher percentage than that of neat PBZ system. With the successive enhancement in the incorporation of nTiO2, the synthesized nanocomposites exhibited better thermal stability, higher flame retardancy and lesser water absorption behaviour than the of neat PBZ. The sequential increments in the loading level of nTiO2 onto the PBZ matrices caused the lower value of dielectric constant than that of neat PBZ. The homogeneity and successful dispersion of the nTiO2 fillers in the PBZ matrix were ascertained from the strong fluorescent emissions observed in the wavelength range of 300–550 nm through optical studies. Scanning electron microscope and transmission electron microscopic micrographs evidenced the successful incorporation of nTiO2 as can be seen from the different morphology at the nanoscale level in the PBZ matrix. This kind of structurally designed nTiO2/PBZ nanocomposites may find multifaceted applications in the form of adhesives, encapsulants, matrices and sealants and in the fields of automobile and microelectronics applications for better performance and longevity.
期刊介绍:
Health Services Management Research (HSMR) is an authoritative international peer-reviewed journal which publishes theoretically and empirically rigorous research on questions of enduring interest to health-care organizations and systems throughout the world. Examining the real issues confronting health services management, it provides an independent view and cutting edge evidence-based research to guide policy-making and management decision-making. HSMR aims to be a forum serving an international community of academics and researchers on the one hand and healthcare managers, executives, policymakers and clinicians and all health professionals on the other. HSMR wants to make a substantial contribution to both research and managerial practice, with particular emphasis placed on publishing studies which offer actionable findings and on promoting knowledge mobilisation toward theoretical advances. All papers are expected to be of interest and relevance to an international audience. HSMR aims at enhance communication between academics and practitioners concerned with developing, implementing, and analysing health management issues, reforms and innovations primarily in European health systems and in all countries with developed health systems. Papers can report research undertaken in a single country, but they need to locate and explain their findings in an international context, and in international literature.