Robert Țincu, A. Slabu, C. Stavarache, M. Duldner, Emeric Barth, F. Teodorescu
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引用次数: 1
Abstract
Metal-containing ionic liquids with general formula [Rmim]+MX3- (R=n-butyl or n-lauryl; M=Zn, Cd; X=Cl, Br) were synthesised and then characterized by nuclear magnetic resonance spectroscopy and infrared spectroscopy. The catalytic activity was tested in glycolysis of poly(ethylene terephthalate) (PET) with ethylene glycol (EG) with the main product being bis-2-hydroxyethyl terephthalate (BHET). The following parameters were varied: the catalyst type, the catalyst loading and the molar ratio between PET and EG. For every reaction conversion and selectivity were calculated. All these reactions arose with high selectivity in the desired product, the conversion of PET being quasi-total.
期刊介绍：
Materiale Plastice, abbreviated as Mater. Plast., publishes original scientific papers or guest reviews on topics of great interest.
The Journal does not publish memos, technical reports or non-original papers (that are a compiling of literature data) or papers that have been already published in other national or foreign Journal.
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