Optimization of fluoride removal using ultrasonically improved electrochemically generated adsorbent: A Taguchi approach

IF 0.5 4区 工程技术 Q4 ENGINEERING, CHEMICAL Chemical and Process Engineering-Inzynieria Chemiczna I Procesowa Pub Date : 2023-07-20 DOI:10.24425/cpe.2022.140814
Kunjan Junghare, Shyam M Kodape, A. Rathod, D. Lataye
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Abstract

Ultrasonically improved electrochemically generated adsorbent (UEGA) has been synthesized and used for adsorption of fluoride ions from fluoride laden waste water. UEGA was prepared in two major steps, firstly electrochemically generated adsorbent (EGA) was prepared using electrolytic method followed by ultrasonication treatment. Ultrasonication causes size reduction which leads to increase in surface area viz. active site which helps to enhance attachment of negatively charged fluoride ion on positively changed UEGA from waste water. UEGA was prepared at three different amplitude i.e. 50, 70 and 90% respectively. Taguchi optimization for defluoridation was carried out considering operating parameters such as initial concentration; contact time; adsorbent dose; and temperature. The results obtained demonstrated that adsorption showed different fluoride removal at varying frequency. This study proved that varying percentage amplitude of ultrasonication significantly affects defluoridation efficiency.
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优化超声改进电化学吸附剂的除氟效果:田口法
合成了超声改进的电化学生成吸附剂(UEGA),并将其用于含氟废水中氟离子的吸附。制备UEGA主要分为两个步骤,首先采用电解法制备了电化学生成吸附剂(EGA),然后进行超声处理。超声波作用使UEGA的尺寸减小,从而使其表面积(即活性位点)增加,这有助于增强带负电荷的氟离子在废水中正变化的UEGA上的附着。分别以50%、70%和90%三种不同振幅制备UEGA。考虑初始浓度等操作参数,进行了田口优化除氟;接触时间;吸附剂剂量;和温度。结果表明,在不同频率下,吸附对氟的去除效果不同。实验证明,不同百分比振幅的超声对除氟效果有显著影响。
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CiteScore
1.30
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0.00%
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0
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>12 weeks
期刊介绍: The content, aim and scope of the proposals should comply with the main subject of the journal, i.e. they should deal with mathematical modelling and/or experimental investigations on momentum, heat and mass transfer, unit processes and operations, integrated processes, biochemical engineering, statics and kinetics of chemical reactions. The experiments and modelling may cover different scales and processes ranging from the molecular phenomena up to production systems. The journal language is grammatically correct British English. Chemical and Process Engineering publishes: i) full text research articles, ii) invited reviews, iii) letters to the editor and iv) short communications, aiming at important new results and/or applications. Each of the publication form is peer-reviewed by at least two independent referees.
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