首页 > 最新文献

Chemical and Process Engineering-Inzynieria Chemiczna I Procesowa最新文献

英文 中文
Studies of a mixing process induced by a rotating magnetic field with the application of magnetic particles 应用磁性粒子研究旋转磁场诱导的混合过程
4区 工程技术 Q4 ENGINEERING, CHEMICAL Pub Date : 2023-11-06 DOI: 10.24425/cpe.2021.138922
We demonstrate in this study that a rotating magnetic field (RMF) and spinning magnetic particles using this kind of magnetic field give rise to a motion mechanism capable of triggering mixing effect in liquids. In this experimental work two mixing mechanisms were used, magnetohydrodynamics due to the Lorentz force and mixing due to magnetic particles under the action of RMF, acted upon by the Kelvin force. To evidence these mechanisms, we report mixing time measured during the neutralization process (weak acid-strong base) under the action of RMF with and without magnetic particles. The efficiency of the mixing process was enhanced by a maximum of 6.5% and 12.8% owing to the application of RMF and the synergistic effect of magnetic field and magnetic particles, respectively
{"title":"Studies of a mixing process induced by a rotating magnetic field with the application of magnetic particles","authors":"","doi":"10.24425/cpe.2021.138922","DOIUrl":"https://doi.org/10.24425/cpe.2021.138922","url":null,"abstract":"We demonstrate in this study that a rotating magnetic field (RMF) and spinning magnetic particles using this kind of magnetic field give rise to a motion mechanism capable of triggering mixing effect in liquids. In this experimental work two mixing mechanisms were used, magnetohydrodynamics due to the Lorentz force and mixing due to magnetic particles under the action of RMF, acted upon by the Kelvin force. To evidence these mechanisms, we report mixing time measured during the neutralization process (weak acid-strong base) under the action of RMF with and without magnetic particles. The efficiency of the mixing process was enhanced by a maximum of 6.5% and 12.8% owing to the application of RMF and the synergistic effect of magnetic field and magnetic particles, respectively","PeriodicalId":55267,"journal":{"name":"Chemical and Process Engineering-Inzynieria Chemiczna I Procesowa","volume":"23 2","pages":"0"},"PeriodicalIF":0.0,"publicationDate":"2023-11-06","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"135635070","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 3
In memoriam Professor Krzysztof Warmuziński 为了纪念Krzysztof教授Warmuziński
4区 工程技术 Q4 ENGINEERING, CHEMICAL Pub Date : 2023-11-06 DOI: 10.24425/cpe.2019.126117
{"title":"In memoriam Professor Krzysztof Warmuziński","authors":"","doi":"10.24425/cpe.2019.126117","DOIUrl":"https://doi.org/10.24425/cpe.2019.126117","url":null,"abstract":"","PeriodicalId":55267,"journal":{"name":"Chemical and Process Engineering-Inzynieria Chemiczna I Procesowa","volume":"263 3","pages":"0"},"PeriodicalIF":0.0,"publicationDate":"2023-11-06","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"135678727","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Optimal feed temperature for hydrogen peroxide decomposition process occurring in a bioreactor with fixed-bed of commercial catalase: a case study on thermal deactivation of the enzyme 过氧化氢酶固定床生物反应器中过氧化氢分解过程的最佳进料温度——以过氧化氢酶热失活为例
IF 0.6 4区 工程技术 Q4 ENGINEERING, CHEMICAL Pub Date : 2023-11-06 DOI: 10.24425/CPE.2018.124974
I. Grubecki
On the basis of hydrogen peroxide decomposition process occurring in the bioreactor with fixed-bed of commercial catalase the optimal feed temperature was determined. This feed temperature was obtained by maximizing the time-average substrate conversion under constant feed flow rate and temperature constraints. In calculations, convection-diffusion-reaction immobilized enzyme fixed-bed bioreactor described by a coupled mass and energy balances as well as general kinetic equation for rate of enzyme deactivation was taken into consideration. This model is based on kinetic, hydrodynamic and mass-transfer parameters estimated in earlier work. The simulation showed that in the biotransformation with thermal deactivation of catalase optimal feed temperature is only affected by kinetic parameters for enzyme deactivation and decreases with increasing value of activation energy for deactivation. When catalase undergoes parallel deactivation the optimal feed temperature is strongly dependent on hydrogen peroxide feed concentration, feed flow rate and diffusional resistances expressed by biocatalyst effectiveness factor. It has been shown that the more significant diffusional resistances and the higher hydrogen peroxide conversions, the higher the optimal feed temperature is expected.
根据过氧化氢酶固定床生物反应器中过氧化氢分解过程,确定了最佳进料温度。该进料温度是通过在恒定进料流量和温度约束下最大化时间平均底物转化率而获得的。在计算中,考虑了对流-扩散-反应固定化酶固定床生物反应器的质量和能量耦合平衡以及酶失活速率的一般动力学方程。该模型基于早期工作中估计的动力学、流体力学和传质参数。模拟结果表明,在过氧化氢酶热失活生物转化过程中,最佳饲料温度只受酶失活动力学参数的影响,并随着失活活化能的增大而降低。过氧化氢酶平行失活时,最佳进料温度与过氧化氢进料浓度、进料流量和生物催化剂效能因子表达的扩散阻力密切相关。结果表明,扩散阻力越大,过氧化氢转化率越高,期望的最佳进料温度越高。
{"title":"Optimal feed temperature for hydrogen peroxide decomposition process occurring in a bioreactor with fixed-bed of commercial catalase: a case study on thermal deactivation of the enzyme","authors":"I. Grubecki","doi":"10.24425/CPE.2018.124974","DOIUrl":"https://doi.org/10.24425/CPE.2018.124974","url":null,"abstract":"On the basis of hydrogen peroxide decomposition process occurring in the bioreactor with fixed-bed of commercial catalase the optimal feed temperature was determined. This feed temperature was obtained by maximizing the time-average substrate conversion under constant feed flow rate and temperature constraints. In calculations, convection-diffusion-reaction immobilized enzyme fixed-bed bioreactor described by a coupled mass and energy balances as well as general kinetic equation for rate of enzyme deactivation was taken into consideration. This model is based on kinetic, hydrodynamic and mass-transfer parameters estimated in earlier work. The simulation showed that in the biotransformation with thermal deactivation of catalase optimal feed temperature is only affected by kinetic parameters for enzyme deactivation and decreases with increasing value of activation energy for deactivation. When catalase undergoes parallel deactivation the optimal feed temperature is strongly dependent on hydrogen peroxide feed concentration, feed flow rate and diffusional resistances expressed by biocatalyst effectiveness factor. It has been shown that the more significant diffusional resistances and the higher hydrogen peroxide conversions, the higher the optimal feed temperature is expected.","PeriodicalId":55267,"journal":{"name":"Chemical and Process Engineering-Inzynieria Chemiczna I Procesowa","volume":"39 1","pages":""},"PeriodicalIF":0.6,"publicationDate":"2023-11-06","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"68947290","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 1
Analysis of wake structures in bubbly flows using Particle Image Velocimetry (PIV) 粒子图像测速法(PIV)分析气泡流尾迹结构
IF 0.6 4区 工程技术 Q4 ENGINEERING, CHEMICAL Pub Date : 2023-11-06 DOI: 10.24425/CPE.2018.124996
Björn Lewandowski, M. Fertig, G. Krekel, M. Ulbricht
{"title":"Analysis of wake structures in bubbly flows using Particle Image Velocimetry (PIV)","authors":"Björn Lewandowski, M. Fertig, G. Krekel, M. Ulbricht","doi":"10.24425/CPE.2018.124996","DOIUrl":"https://doi.org/10.24425/CPE.2018.124996","url":null,"abstract":"","PeriodicalId":55267,"journal":{"name":"Chemical and Process Engineering-Inzynieria Chemiczna I Procesowa","volume":"1 1","pages":""},"PeriodicalIF":0.6,"publicationDate":"2023-11-06","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"68947339","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 4
Application of turbiscan lab to study the effect of emulsifier content on the stability of plant origin dispersion 应用浊化验室研究乳化剂含量对植物源分散体稳定性的影响
IF 0.6 4区 工程技术 Q4 ENGINEERING, CHEMICAL Pub Date : 2023-11-06 DOI: 10.24425/CPE.2019.130214
A. Zalewska, J. Kowalik, I. Grubecki
The effect of emulsifier volume on emulsion system stability of plant origin being the basis of diet supplements for animals in winter season was analyzed. For this purpose, measurements of the backscattered light intensity as the function of the measuring cell height were conducted with a Turbiscan LAB optical analyzer. System stability was analyzed on the basis of Turbiscan Stability Index values. A Helos laser analyzer and a Nikon Eclipse E400 POL optical microscope were used to investigate drop size distribution and analyze microscopic pictures. It was shown that emulsion with 10% (w/w) of the emulsifier was the most stable one.
{"title":"Application of turbiscan lab to study the effect of emulsifier content on the stability of plant origin dispersion","authors":"A. Zalewska, J. Kowalik, I. Grubecki","doi":"10.24425/CPE.2019.130214","DOIUrl":"https://doi.org/10.24425/CPE.2019.130214","url":null,"abstract":"The effect of emulsifier volume on emulsion system stability of plant origin being the basis of diet supplements for animals in winter season was analyzed. For this purpose, measurements of the backscattered light intensity as the function of the measuring cell height were conducted with a Turbiscan LAB optical analyzer. System stability was analyzed on the basis of Turbiscan Stability Index values. A Helos laser analyzer and a Nikon Eclipse E400 POL optical microscope were used to investigate drop size distribution and analyze microscopic pictures. It was shown that emulsion with 10% (w/w) of the emulsifier was the most stable one.","PeriodicalId":55267,"journal":{"name":"Chemical and Process Engineering-Inzynieria Chemiczna I Procesowa","volume":"40 1","pages":""},"PeriodicalIF":0.6,"publicationDate":"2023-11-06","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"68947409","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 8
Editor’s notes. In memoriam of Professor Jerzy Bałdyga 编者笔记。为了纪念Jerzy教授Bałdyga
IF 0.6 4区 工程技术 Q4 ENGINEERING, CHEMICAL Pub Date : 2023-11-06 DOI: 10.24425/CPE.2019.130217
E. Molga
{"title":"Editor’s notes. In memoriam of Professor Jerzy Bałdyga","authors":"E. Molga","doi":"10.24425/CPE.2019.130217","DOIUrl":"https://doi.org/10.24425/CPE.2019.130217","url":null,"abstract":"","PeriodicalId":55267,"journal":{"name":"Chemical and Process Engineering-Inzynieria Chemiczna I Procesowa","volume":"1 1","pages":""},"PeriodicalIF":0.6,"publicationDate":"2023-11-06","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"68947471","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Differential quadrature method for some diffusion-reaction problems 一类扩散反应问题的微分求积法
IF 0.6 4区 工程技术 Q4 ENGINEERING, CHEMICAL Pub Date : 2023-11-06 DOI: 10.24425/CPE.2019.130219
M. Szukiewicz
In the paper, differential quadrature method (DQM) is used to find numerical solutions of reactiondiffusion equations with different boundary conditions. The DQM-method changes the reactiondiffusion equation (ordinary differential equation) into a system of algebraic equations. The obtained system is solved using built-in procedures of Maple®(Computer Algebra System-type program). Calculations were performed with Maple®program. The test problems include reaction-diffusion equation applied in heterogeneous catalysis. The method can be employed even in relatively hard tasks (e.g. ill-conditioned, free boundary problems).
本文采用微分正交法求解具有不同边界条件的反应扩散方程的数值解。dqm方法将反应扩散方程(常微分方程)转化为代数方程组。使用Maple®(计算机代数系统类型程序)的内置程序求解得到的系统。使用Maple®程序进行计算。测试问题包括多相催化中应用的反应扩散方程。该方法甚至可以用于相对困难的任务(例如,病态、自由边界问题)。
{"title":"Differential quadrature method for some diffusion-reaction problems","authors":"M. Szukiewicz","doi":"10.24425/CPE.2019.130219","DOIUrl":"https://doi.org/10.24425/CPE.2019.130219","url":null,"abstract":"In the paper, differential quadrature method (DQM) is used to find numerical solutions of reactiondiffusion equations with different boundary conditions. The DQM-method changes the reactiondiffusion equation (ordinary differential equation) into a system of algebraic equations. The obtained system is solved using built-in procedures of Maple®(Computer Algebra System-type program). Calculations were performed with Maple®program. The test problems include reaction-diffusion equation applied in heterogeneous catalysis. The method can be employed even in relatively hard tasks (e.g. ill-conditioned, free boundary problems).","PeriodicalId":55267,"journal":{"name":"Chemical and Process Engineering-Inzynieria Chemiczna I Procesowa","volume":"1 1","pages":""},"PeriodicalIF":0.6,"publicationDate":"2023-11-06","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"68947529","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 1
Tyre-derived activated carbon – textural propertiesand modelling of adsorption equilibrium ofn-hexane 轮胎衍生活性炭——结构特性和正己烷吸附平衡模型
IF 0.6 4区 工程技术 Q4 ENGINEERING, CHEMICAL Pub Date : 2023-11-06 DOI: 10.24425/CPE.2019.130221
Tomasz Kotkowski, R. Cherbański, E. Molga
There is general agreement that primary pyrolysis products of end-of-life tyres should be valorised to improve the economics of pyrolysis. In this work, tyre pyrolysis char (TPC) is produced in a pyrolysis pilot plant designed and built at our home university. The produced TPC was upgraded to tyre-derived activated carbon (TDAC) by activation with CO 2 , and then characterised using stereological analysis (SA) and nitrogen adsorption at 77 K. SA showed that the grains of TPC and TDAC were quasi-spherical and slightly elongated with a 25% increase in the mean particle cross-section surface area for TDAC. The textural properties of TDAC demonstrated the BET and micropore surface areas of 259 and 70 m 2 /g, respectively. Micropore volume and micropore surface area were 5.8 and 6.7 times higher for TDAC than TPC at (cid:24) 2 nm, respectively. The n -hexane adsorption was investigated using experiments and modelling. Eight adsorption isotherms along with three error functions were tested to model the adsorption equilibrium. The optimum sets of isotherm parameters were chosen by comparing sum of the normalized errors. The analysis indicated that the Freundlich isotherm gave the best agreement with the equilibrium experiments. In relation to different activated carbons, the adsorption capacity of TDAC for n -hexane is about 16.2 times higher than that of the worst reference material and 4.3 times lower than that of the best reference material. In addition, stereological analysis showed that activation with CO 2 did not change the grain’s shape factors. However, a 25% increase in the mean particle cross-section surface area for TDAC was observed. The results show that the most common particle equivalent diameter, d 2 , is in a range between 10 and 15 (cid:22) m for both compared materials. In addition, a thorough analysis shows a very small difference between the frequencies of the most common particle equivalent diameter in this range (29.6% for TPC against 28.1% for TDAC). No significant difference has been found between the TPC and TDAC samples in terms of shape factors. The shape factors calculated from the d max = d 2 and p = d 2 ratios indicate that the grains of both samples are quasi-spherical and slightly elongated (Wejrzanowski Kurzydlowski, 2003; Wejrzanowski et al., 2008). However, it is worth noting that there is a 25% increase in the mean particle cross-section surface area for the activated sample (TDAC).
人们普遍认为,应该对报废轮胎的初级热解产品进行定价,以提高热解的经济性。本文以轮胎热解焦(TPC)为研究对象,在国内大学自行设计建造的热解中试装置中进行生产。制备的TPC经co2活化后升级为轮胎衍生活性炭(TDAC),并在77 K条件下进行了立体分析(SA)和氮吸附表征。SA结果表明,TPC和TDAC的晶粒呈准球形,略有拉长,TDAC的平均颗粒横截面表面积增加了25%。TDAC的结构性能表明,其BET和微孔表面积分别为259和70 m2 /g。在(cid:24) 2 nm处,TDAC的微孔体积和微孔表面积分别是TPC的5.8倍和6.7倍。通过实验和模型研究了正己烷的吸附。用8条吸附等温线和3个误差函数来模拟吸附平衡。通过比较归一化误差和,选择最佳的等温线参数集。分析表明,Freundlich等温线与平衡实验最吻合。相对于不同的活性炭,TDAC对正己烷的吸附量比最差标准物质高16.2倍,比最佳标准物质低4.3倍。此外,体视学分析表明,co2活化对晶粒的形状因子没有影响。然而,观察到TDAC的平均颗粒截面表面积增加了25%。结果表明,两种比较材料最常见的颗粒等效直径d2在10 ~ 15 (cid:22) m之间。此外,一个彻底的分析表明,在这个范围内,最常见的颗粒当量直径的频率之间的差异非常小(TPC为29.6%,而TDAC为28.1%)。在形状因子方面,TPC和TDAC样品之间没有发现显著差异。由d max = d2和p = d2比值计算出的形状因子表明,两种样品的晶粒均为准球形且略微拉长(Wejrzanowski Kurzydlowski, 2003;Wejrzanowski et al., 2008)。然而,值得注意的是,活化样品(TDAC)的平均颗粒横截面表面积增加了25%。
{"title":"Tyre-derived activated carbon – textural propertiesand modelling of adsorption equilibrium ofn-hexane","authors":"Tomasz Kotkowski, R. Cherbański, E. Molga","doi":"10.24425/CPE.2019.130221","DOIUrl":"https://doi.org/10.24425/CPE.2019.130221","url":null,"abstract":"There is general agreement that primary pyrolysis products of end-of-life tyres should be valorised to improve the economics of pyrolysis. In this work, tyre pyrolysis char (TPC) is produced in a pyrolysis pilot plant designed and built at our home university. The produced TPC was upgraded to tyre-derived activated carbon (TDAC) by activation with CO 2 , and then characterised using stereological analysis (SA) and nitrogen adsorption at 77 K. SA showed that the grains of TPC and TDAC were quasi-spherical and slightly elongated with a 25% increase in the mean particle cross-section surface area for TDAC. The textural properties of TDAC demonstrated the BET and micropore surface areas of 259 and 70 m 2 /g, respectively. Micropore volume and micropore surface area were 5.8 and 6.7 times higher for TDAC than TPC at (cid:24) 2 nm, respectively. The n -hexane adsorption was investigated using experiments and modelling. Eight adsorption isotherms along with three error functions were tested to model the adsorption equilibrium. The optimum sets of isotherm parameters were chosen by comparing sum of the normalized errors. The analysis indicated that the Freundlich isotherm gave the best agreement with the equilibrium experiments. In relation to different activated carbons, the adsorption capacity of TDAC for n -hexane is about 16.2 times higher than that of the worst reference material and 4.3 times lower than that of the best reference material. In addition, stereological analysis showed that activation with CO 2 did not change the grain’s shape factors. However, a 25% increase in the mean particle cross-section surface area for TDAC was observed. The results show that the most common particle equivalent diameter, d 2 , is in a range between 10 and 15 (cid:22) m for both compared materials. In addition, a thorough analysis shows a very small difference between the frequencies of the most common particle equivalent diameter in this range (29.6% for TPC against 28.1% for TDAC). No significant difference has been found between the TPC and TDAC samples in terms of shape factors. The shape factors calculated from the d max = d 2 and p = d 2 ratios indicate that the grains of both samples are quasi-spherical and slightly elongated (Wejrzanowski Kurzydlowski, 2003; Wejrzanowski et al., 2008). However, it is worth noting that there is a 25% increase in the mean particle cross-section surface area for the activated sample (TDAC).","PeriodicalId":55267,"journal":{"name":"Chemical and Process Engineering-Inzynieria Chemiczna I Procesowa","volume":"41 1","pages":""},"PeriodicalIF":0.6,"publicationDate":"2023-11-06","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"68947542","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 4
Optimizing the conditions of PGSu synthesiswith simplex method 用单纯形法优化合成PGSu的条件
IF 0.6 4区 工程技术 Q4 ENGINEERING, CHEMICAL Pub Date : 2023-11-06 DOI: 10.24425/CPE.2020.132535
Michał Wrzecionek, J. Howis, Paweł Ruśkowski, Agnieszka Gadomska‐Gajadhur
Poly(glycerol succinate) – PGSu – is one of glycerol polyesters which has focused nowadays the interest of scientists developing new biomaterials. Probably the polyester could be used as a drug carrier or as a cell scaffold in tissue engineering. Due to its potential use in medicine, it is extremely important to develop a synthesis and then optimize it to obtain a material with desired properties. In this work one flask two-step polycondensation of glycerol and succinic anhydride to PGSu is presented. Synthesis was optimized with the simplex method and also described using a second-degree equation with two variables (temperature and time) to better find the optimum conditions. PGSu was characterized by FTIR spectroscopy, NMR spectroscopy, degree of esterification was determined, and also molecular weight was calculated for each experiment using Carothers equation. A new synthesis route was developed and optimized. Temperature and time influence on molecular weight and esterification degree of obtained polyester are presented. Based on experiments conducted in this work, it was possible to obtain poly(glycerol succinate) with molecular weight of 6.7 kDa.
{"title":"Optimizing the conditions of PGSu synthesiswith simplex method","authors":"Michał Wrzecionek, J. Howis, Paweł Ruśkowski, Agnieszka Gadomska‐Gajadhur","doi":"10.24425/CPE.2020.132535","DOIUrl":"https://doi.org/10.24425/CPE.2020.132535","url":null,"abstract":"Poly(glycerol succinate) – PGSu – is one of glycerol polyesters which has focused nowadays the interest of scientists developing new biomaterials. Probably the polyester could be used as a drug carrier or as a cell scaffold in tissue engineering. Due to its potential use in medicine, it is extremely important to develop a synthesis and then optimize it to obtain a material with desired properties. In this work one flask two-step polycondensation of glycerol and succinic anhydride to PGSu is presented. Synthesis was optimized with the simplex method and also described using a second-degree equation with two variables (temperature and time) to better find the optimum conditions. PGSu was characterized by FTIR spectroscopy, NMR spectroscopy, degree of esterification was determined, and also molecular weight was calculated for each experiment using Carothers equation. A new synthesis route was developed and optimized. Temperature and time influence on molecular weight and esterification degree of obtained polyester are presented. Based on experiments conducted in this work, it was possible to obtain poly(glycerol succinate) with molecular weight of 6.7 kDa.","PeriodicalId":55267,"journal":{"name":"Chemical and Process Engineering-Inzynieria Chemiczna I Procesowa","volume":"1 1","pages":""},"PeriodicalIF":0.6,"publicationDate":"2023-11-06","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"68947778","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 4
Determination of Hopf bifurcation sets of a chemicalreactors by two-parameter continuation method 用双参数延拓法确定化学反应器的Hopf分岔集
IF 0.6 4区 工程技术 Q4 ENGINEERING, CHEMICAL Pub Date : 2023-11-06 DOI: 10.24425/CPE.2020.132544
M. Berezowski
A two-parameter continuation method was developed and shown in the form of an example, allowing determination of Hopf bifurcation sets in a chemical reactor model. Exemplary calculations were made for the continuous stirred tank reactor model (CSTR). The set of HB points limiting the range of oscillation in the reactor was determined. The results were confirmed on the bifurcation diagram of steady states and on time charts. The method is universal and can be used for various models of chemical reactors.
提出了一种双参数延拓方法,并以实例的形式给出了该方法对化学反应器模型的Hopf分岔集的确定。对连续搅拌槽式反应器模型(CSTR)进行了示例性计算。确定了限制反应器振荡范围的HB点集合。结果在稳态分岔图和时间图上得到了证实。该方法具有通用性,可用于各种型号的化学反应器。
{"title":"Determination of Hopf bifurcation sets of a chemicalreactors by two-parameter continuation method","authors":"M. Berezowski","doi":"10.24425/CPE.2020.132544","DOIUrl":"https://doi.org/10.24425/CPE.2020.132544","url":null,"abstract":"A two-parameter continuation method was developed and shown in the form of an example, allowing determination of Hopf bifurcation sets in a chemical reactor model. Exemplary calculations were made for the continuous stirred tank reactor model (CSTR). The set of HB points limiting the range of oscillation in the reactor was determined. The results were confirmed on the bifurcation diagram of steady states and on time charts. The method is universal and can be used for various models of chemical reactors.","PeriodicalId":55267,"journal":{"name":"Chemical and Process Engineering-Inzynieria Chemiczna I Procesowa","volume":"41 1","pages":""},"PeriodicalIF":0.6,"publicationDate":"2023-11-06","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"68947842","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
期刊
Chemical and Process Engineering-Inzynieria Chemiczna I Procesowa
全部 Acc. Chem. Res. ACS Applied Bio Materials ACS Appl. Electron. Mater. ACS Appl. Energy Mater. ACS Appl. Mater. Interfaces ACS Appl. Nano Mater. ACS Appl. Polym. Mater. ACS BIOMATER-SCI ENG ACS Catal. ACS Cent. Sci. ACS Chem. Biol. ACS Chemical Health & Safety ACS Chem. Neurosci. ACS Comb. Sci. ACS Earth Space Chem. ACS Energy Lett. ACS Infect. Dis. ACS Macro Lett. ACS Mater. Lett. ACS Med. Chem. Lett. ACS Nano ACS Omega ACS Photonics ACS Sens. ACS Sustainable Chem. Eng. ACS Synth. Biol. Anal. Chem. BIOCHEMISTRY-US Bioconjugate Chem. BIOMACROMOLECULES Chem. Res. Toxicol. Chem. Rev. Chem. Mater. CRYST GROWTH DES ENERG FUEL Environ. Sci. Technol. Environ. Sci. Technol. Lett. Eur. J. Inorg. Chem. IND ENG CHEM RES Inorg. Chem. J. Agric. Food. Chem. J. Chem. Eng. Data J. Chem. Educ. J. Chem. Inf. Model. J. Chem. Theory Comput. J. Med. Chem. J. Nat. Prod. J PROTEOME RES J. Am. Chem. Soc. LANGMUIR MACROMOLECULES Mol. Pharmaceutics Nano Lett. Org. Lett. ORG PROCESS RES DEV ORGANOMETALLICS J. Org. Chem. J. Phys. Chem. J. Phys. Chem. A J. Phys. Chem. B J. Phys. Chem. C J. Phys. Chem. Lett. Analyst Anal. Methods Biomater. Sci. Catal. Sci. Technol. Chem. Commun. Chem. Soc. Rev. CHEM EDUC RES PRACT CRYSTENGCOMM Dalton Trans. Energy Environ. Sci. ENVIRON SCI-NANO ENVIRON SCI-PROC IMP ENVIRON SCI-WAT RES Faraday Discuss. Food Funct. Green Chem. Inorg. Chem. Front. Integr. Biol. J. Anal. At. Spectrom. J. Mater. Chem. A J. Mater. Chem. B J. Mater. Chem. C Lab Chip Mater. Chem. Front. Mater. Horiz. MEDCHEMCOMM Metallomics Mol. Biosyst. Mol. Syst. Des. Eng. Nanoscale Nanoscale Horiz. Nat. Prod. Rep. New J. Chem. Org. Biomol. Chem. Org. Chem. Front. PHOTOCH PHOTOBIO SCI PCCP Polym. Chem.
×
引用
GB/T 7714-2015
复制
MLA
复制
APA
复制
导出至
BibTeX EndNote RefMan NoteFirst NoteExpress
×
0
微信
客服QQ
Book学术公众号 扫码关注我们
反馈
×
意见反馈
请填写您的意见或建议
请填写您的手机或邮箱
×
提示
您的信息不完整,为了账户安全,请先补充。
现在去补充
×
提示
您因"违规操作"
具体请查看互助需知
我知道了
×
提示
现在去查看 取消
×
提示
确定
Book学术官方微信
Book学术文献互助
Book学术文献互助群
群 号:481959085
Book学术
文献互助 智能选刊 最新文献 互助须知 联系我们:info@booksci.cn
Book学术提供免费学术资源搜索服务,方便国内外学者检索中英文文献。致力于提供最便捷和优质的服务体验。
Copyright © 2023 Book学术 All rights reserved.
ghs 京公网安备 11010802042870号 京ICP备2023020795号-1