Low voltage colour modulation in hydrothermally grown Ni-Co nanoneedles for electrochromic application

Abstract

A nanostructured film of NiCo₂O₄ has been prepared using a hydrothermal technique by simply using separate precursors to obtain nanoneedle-like architecture for electrochromic applications. A homogeneous film consisting of packed nanoneedles with moderate density, appearing translucent white in colour, has been obtained and characterized using XRD and Raman spectroscopy techniques for confirming the composition and structure. Electrochemical analysis of the film reveals that the film shows good electrochromic properties under the anodic scan of potential with strong stability. The mechanism of the electrode under the transformation from natural white to opaque dark brown colour has been understood with the help of an in situ optical absorption spectroscopy technique. The electrode is found electrochromically active with a bias of up to 2 V and shows 50% optical contrast which makes it a good candidate for application in a solid state electrochromic device.