Activation of persulfate by iron-loaded soybean straw biochar for efficient degradation of dye contaminants: Synthesis, performance, and mechanism

Abstract

Biochar loaded with metal ions has been widely used to activate persulfate to degrade organic pollutants. However, the preparation conditions of catalysts are always controversial. In this study, the co-heating conditions of soybean straw with high carbon and low nitrogen and nano-iron oxide were systematically discussed by response surface method, and an efficient catalyst (Fe@BC) was obtained. Fe@BC can effectively activate sodium persulfate (PS) and degrade three synthetic azo dyes (Methyl orange (MO), Amino black 10B (AB10B), and Orange II) and rhodamine B (RhB). Under the optimum conditions, the removal rate of total organic carbon of these four dyes reached 41.1%–89.8% and the final degradation rate could reach 100%. The physicochemical properties of Fe@BC were studied by SEM, BET, XRD, XPS and TGA. The results revealed that the specific surface area of Fe@BC was 195.6m²/g. Further, reducing iron oxide by C generated C_0.09Fe_1.91 and zero-valent iron. Free radical scavenging experiments and electron paramagnetic resonance (EPR) measurements showed that the main reactive oxide species (ROS) in the Fe@BC/PS system were hydroxyl radicals (•OH) and singlet oxygen (¹O₂). Finally, Several Fe@BC modification systems were explored, the optimum pH of Fe@BC/PS system was analyzed, and the effects of Fe@BC and PS dosage on degradation performance were also studied. This study provides a scientific basis for the production of efficient catalysts and biochar energy, and an effective treatment scheme for printing and dyeing wastewater.