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Issue Information - Cover and Table of Contents 发行资料-封面及目录
IF 2.3 4区 环境科学与生态学 Q3 ENGINEERING, CHEMICAL Pub Date : 2026-01-30 DOI: 10.1002/ep.70347
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引用次数: 0
Issue Information - Info for Authors 发行信息-作者信息
IF 2.3 4区 环境科学与生态学 Q3 ENGINEERING, CHEMICAL Pub Date : 2026-01-30 DOI: 10.1002/ep.70346
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引用次数: 0
Vanillin production from lignin depolymerization by acidic deep eutectic solvent and its possible mechanism 酸性深共晶溶剂解聚木质素制香兰素及其可能机理
4区 环境科学与生态学 Q3 ENGINEERING, CHEMICAL Pub Date : 2025-12-19 DOI: 10.1002/ep.70279
Xiaoyan Chen, Xiaohui Pan, Dandan Cui
Abstract As one of the most abundant renewable resources and complex aromatic polymers, lignin holds great promise for producing monophenolic compounds. However, its depolymerization into valuable monomers is hindered by intricate side reactions. In this study, alkaline lignin was converted into vanillin using nine choline chloride‐based deep eutectic solvents (DES) under an eco‐friendly and mild process. Among them, choline chloride /lactic acid (molar ratio 10:1) containing 30% water at 80°C for 120 min achieved the highest vanillin yield (1.92 wt %), outperforming oxalic‐, levulinic‐, and glycol‐based DES by 1.5 to 5‐fold. Single‐factor assays showed that acidity (lactic acid fraction), water content (20%–40%), and reaction time (≤120 min) were decisive. GPC revealed that the weight‐average molar mass dropped from 3000 to 420 g mol −1 and PDI narrowed to 1.25, confirming extensive yet selective cleavage of β‐O‐4 linkages. 2D‐HSQC indicated simultaneous demethoxylation and minor condensation of side chains. The depolymerized products exhibited strong antibacterial activity toward Staphylococcus aureus (79.6% inhibition) and Escherichia coli (65.5% inhibition). A mild acid–water synergistic oxidation pathway is proposed, in which protons generated from DES dissociation attack ether bonds and H 2 O activates oxygen transfer, enabling greener lignin without noble metals or high pressure.
木质素作为最丰富的可再生资源和复杂的芳香族聚合物之一,在生产单酚类化合物方面具有很大的前景。然而,复杂的副反应阻碍了其解聚成有价值的单体。在本研究中,碱性木质素采用九氯化胆碱基深共晶溶剂(DES),在环保温和的工艺条件下转化为香兰素。其中,氯化胆碱/乳酸(摩尔比为10:1)在含30%水的条件下,在80°C下反应120分钟,香兰素的产率最高(1.92 wt %),比草酸、乙酰丙酸和乙二醇基DES的产率高出1.5 - 5倍。单因素试验表明,酸度(乳酸部分)、含水量(20%-40%)和反应时间(≤120 min)是决定性因素。GPC显示,重量-平均摩尔质量从3000 g mol - 1下降到420 g mol - 1, PDI缩小到1.25,证实了β - O - 4键的广泛而选择性的裂解。2D‐HSQC显示同时发生脱甲氧基化和侧链的轻微缩合。解聚产物对金黄色葡萄球菌(79.6%)和大肠杆菌(65.5%)具有较强的抑菌活性。提出了一种温和的酸-水协同氧化途径,其中DES解离产生的质子攻击醚键,h2o激活氧转移,使木质素更加绿色,无需贵金属或高压。
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引用次数: 0
The industrialization paradox under energy-transition policies: Do ICT, economic growth and natural resource rents promote renewable energy adoption? 能源转型政策下的工业化悖论:信息通信技术、经济增长和自然资源租金是否促进可再生能源的采用?
IF 2.3 4区 环境科学与生态学 Q3 ENGINEERING, CHEMICAL Pub Date : 2025-12-12 DOI: 10.1002/ep.70226
Guangpeng Chen, Babatunde Sunday Eweade, Dilber Uzun Ozsahin

Newly industrialized countries face a growth–transition paradox: economic expansion and resource rents finance development but can lock in fossil dependence. Using annual NIC data for 1990–2024, we test whether growth and natural resource rents promote renewable energy, and how industrialization, financial development, and ICT shape this link. Second-generation diagnostics confirm slope heterogeneity, cross-sectional dependence, and cointegration among REN, GDP, NRR, IND, FDE, and ICT. We then estimate Method of Moments Quantile Regression (MMQR, τ = 0.10–0.90) and cross-check with FMOLS/DOLS/FE-OLS and Dumitrescu–Hurlin causality. MMQR shows GDP is positive and significant across all quantiles—strongest at the tails; NRR is consistently negative, with larger magnitudes at upper quantiles; IND is mostly negative beyond lower quantiles (one positive estimate at τ = 0.20); FDE and ICT have mixed, generally insignificant effects. Benchmarks corroborate GDP(+) and FDE(+) with IND(−) on average. Causality indicates GDP → REN, NRR → REN, FDE → REN, bidirectional REN↔IND, and no ICT–REN causality. Overall, growth reliably supports renewables, resource-rent dependence hinders them, industrial pressure tilts against REN without correction, and enabling institutions are uneven—effects that vary across the adoption distribution.

新兴工业化国家面临着增长转型的悖论:经济扩张和资源租金为发展提供资金,但可能会锁定对化石燃料的依赖。利用1990-2024年的年度NIC数据,我们检验了经济增长和自然资源租金是否促进了可再生能源,以及工业化、金融发展和信息通信技术如何塑造了这种联系。第二代诊断证实了REN、GDP、NRR、IND、FDE和ICT之间的斜率异质性、横截面依赖性和协整性。然后,我们估计矩分位数回归方法(MMQR, τ = 0.10-0.90),并与FMOLS/DOLS/FE-OLS和dumitrescuo - hurlin因果关系进行交叉检验。MMQR显示,GDP在所有分位数中都是正的且显著的——在尾部最强;NRR始终为负,在高分位数处的幅度更大;IND在较低分位数之外大多为负(τ = 0.20时有一个正估计);FDE和ICT的影响是混合的,通常不显著。基准平均证实了GDP(+)和FDE(+)与IND(-)。因果关系表示GDP→REN、NRR→REN、FDE→REN、双向REN↔IND,无ICT-REN因果关系。总体而言,增长可靠地支持可再生能源,资源租金依赖阻碍了可再生能源,工业压力在没有纠正的情况下倾向于可再生能源,而扶持制度是不均衡的——在不同的采用分布中存在差异。
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引用次数: 0
Sustainable productivity enhancement of conical solar distillers using Peanut Shell bio-waste: Energy and economic analyses 利用花生壳生物废料可持续提高锥形太阳能蒸馏器的生产效率:能源和经济分析
IF 2.3 4区 环境科学与生态学 Q3 ENGINEERING, CHEMICAL Pub Date : 2025-12-10 DOI: 10.1002/ep.70253
A. Muthu Manokar, Mohammed El Hadi Attia, Alagar Karthick, Madhu Petchimuthu

This experimental study aimed to improve the output of the Conical Distiller (CD) using low-cost natural bio-materials. Three CDs (simple CD (SCD), a CD with Natural Peanut Shells (CD-NPS) and a CD with Black-Painted Peanut Shells (CD-BPS)) were fabricated for comparative analysis under identical climatic conditions. Experimental results revealed that the daily yields, energy, and exergy efficiencies for SCD, CD-NPS, and CD-BPS are 4.69 kg, 6.49%, 45.30%, and 7.43%, 31.23%, 52.06%, and 1.15%, 1.78%, 2.38%, respectively. The results showed that the daily yields of CD-NPS and CD-BPS increased by 38.4% and 58.4%, respectively, and the daily energy efficiency of CD-NPS and CD-BPS increased by 45.06% and 66.69%, respectively, compared with the SCD. The daily exergy efficiency of CD-NPS and CD-BPS increased by 54.20% and 106.64%, respectively, compared with the SCD. The economic analysis confirmed that integrating BPS is an effective and cost-effective way to improve the CD yield.

本实验旨在利用低成本的天然生物材料提高锥形蒸馏器(CD)的产量。在相同的气候条件下,制作了3张CD(简单CD (SCD)、天然花生壳CD (CD- nps)和涂黑花生壳CD (CD- bps)进行对比分析。实验结果表明,SCD、CD-NPS和CD-BPS的日产量、能量和㶲效率分别为4.69 kg、6.49%、45.30%和7.43%、31.23%、52.06%和1.15%、1.78%、2.38%。结果表明,与SCD相比,CD-NPS和CD-BPS的日产量分别提高了38.4%和58.4%,CD-NPS和CD-BPS的日能效分别提高了45.06%和66.69%。CD-NPS和CD-BPS的日火用效率分别比SCD提高了54.20%和106.64%。经济分析证实,整合BPS是提高CD产量的有效且经济的方法。
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引用次数: 0
Unraveling the pseudo-decoupling phenomenon: Typology identification and pathway deciphering of the decoupling trap between livestock carbon emissions and economic growth in China 伪脱钩现象的揭示:中国畜牧业碳排放与经济增长脱钩陷阱的类型学识别与路径解读
IF 2.3 4区 环境科学与生态学 Q3 ENGINEERING, CHEMICAL Pub Date : 2025-12-08 DOI: 10.1002/ep.70258
Ming Li, Haifeng Xiao

Achieving carbon decoupling within the livestock sector is a crucial step toward promoting green and low-carbon transitions, which is essential for meeting dual-carbon targets. Existing research has thoroughly examined the decoupling status and spatiotemporal evolution of carbon emissions from livestock farming, but has paid insufficient attention to the stability of decoupling and its underlying causes. This study innovatively introduces the concepts and identification methodologies of decoupling traps and real-pseudo decoupling. By utilizing the Tapio decoupling model, we evaluate the carbon decoupling status and real decoupling achievements across Chinese provinces. A binary logit model is employed to identify key determinants for overcoming decoupling traps. Our findings reveal that (1) China's livestock sector carbon emissions have shown a fluctuating downward trend, with total emissions decreasing from 466 million tons to 377 million tons—a reduction of 19.12%. (2) From the 2006 to 2010 period to the 2021 to 2023 period, the relationship between livestock carbon emissions and economic growth in China was predominantly characterized by strong decoupling and weak decoupling. Although overall decoupling performance is relatively favorable, significant spatial heterogeneity and temporal volatility are observed. (3) Substantial disparities exist among provinces regarding real-pseudo decoupling. Real decoupling is primarily concentrated in economically advanced municipalities and major livestock production regions, while other areas remain in a state of pseudo-decoupling, thereby falling into decoupling traps. (4) Industrial structure, technological progress, urbanization level, government support, and infrastructure development are identified as critical pathways to facilitate the transition from pseudo-decoupling to real decoupling.

实现畜牧业的碳脱钩是促进绿色和低碳转型的关键一步,这对实现双碳目标至关重要。现有研究对畜牧业碳排放的解耦状态和时空演化进行了较为深入的考察,但对解耦的稳定性及其深层次原因关注不够。创新性地引入了解耦陷阱和实-伪解耦的概念和识别方法。利用Tapio解耦模型,对中国各省的碳解耦现状和实际解耦成果进行了评价。二元logit模型用于识别克服解耦陷阱的关键决定因素。结果表明:(1)中国畜牧业碳排放呈波动下降趋势,总排放量从4.66亿吨下降到3.77亿吨,减少了19.12%;(2) 2006 - 2010年和2021 - 2023年期间,中国畜牧业碳排放与经济增长的关系主要表现为强脱钩和弱脱钩。尽管整体去耦性能相对较好,但存在显著的空间异质性和时间波动性。(3)各省之间的实-伪脱钩存在较大差异。真正脱钩主要集中在经济发达的直辖市和畜牧主产区,其他地区则处于伪脱钩状态,陷入脱钩陷阱。(4)产业结构、技术进步、城镇化水平、政府支持和基础设施建设是促进伪脱钩向真正脱钩转变的关键路径。
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引用次数: 0
Review of carbon dioxide sequestration by basalt mineral carbonation 玄武岩矿物碳酸化封存二氧化碳的研究进展
IF 2.3 4区 环境科学与生态学 Q3 ENGINEERING, CHEMICAL Pub Date : 2025-12-08 DOI: 10.1002/ep.70266
Jiatie Cai, Di Wu, Xing Xu, Ruotong Wang, Huiyang Ma, Yi Pan

Excessive carbon dioxide emissions have become one of the main factors contributing to global warming, and developing effective carbon dioxide sequestration technologies has become an urgent need to address climate change. Basalt mineralization sequestration technology has shown great potential for the long-term stable sequestration of CO2. This article reviews the current research status of CO2 mineral sequestration in basalt, with a focus on analyzing the main factors affecting sequestration rates, including mineral composition, temperature, pH, porosity, and permeability. Additionally, it summarizes the methods for evaluating the sequestration potential of basalt. Studies have shown that the mineral composition of basalt can form stable carbonate minerals when reacting with CO2, effectively sequestering CO2 with a high sequestration rate. In addition, temperature and pH conditions have a significant impact on the mineralization sequestration rate, and optimal reaction conditions can significantly improve reaction efficiency. Compared to traditional CO2 sequestration methods, basalt mineral sequestration offers more long-term, safe, and stable sequestration effects. Finally, this article summarizes future research directions for CO2 sequestration in basalt, providing a theoretical foundation and technical support to promote technological advancements and applications in this field.

二氧化碳的过量排放已成为导致全球变暖的主要因素之一,开发有效的二氧化碳封存技术已成为应对气候变化的迫切需要。玄武岩矿化封存技术在长期稳定封存CO2方面显示出巨大的潜力。本文综述了玄武岩中CO2矿物封存的研究现状,重点分析了影响封存速率的主要因素,包括矿物组成、温度、pH、孔隙度和渗透率。总结了玄武岩封存潜力的评价方法。研究表明,玄武岩的矿物组成与CO2反应可形成稳定的碳酸盐矿物,有效封存CO2,封存率高。此外,温度和pH条件对矿化固存率有显著影响,优化反应条件可显著提高反应效率。与传统的CO2封存方法相比,玄武岩矿物封存具有更长期、更安全、更稳定的封存效果。最后,总结了玄武岩CO2固存的未来研究方向,为促进该领域的技术进步和应用提供理论基础和技术支撑。
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引用次数: 0
Innovative biomass transformation: Harnessing biological marine waste for high-performance ecofriendly food packaging—Critical review 创新生物质转化:利用海洋生物废弃物进行高性能环保食品包装——综述
IF 2.3 4区 环境科学与生态学 Q3 ENGINEERING, CHEMICAL Pub Date : 2025-12-05 DOI: 10.1002/ep.70136
Saran Sundararaj, M. Prem Kumar, S. Sanjay, N. Venkatesh

Growing environmental issues associated with conventional plastic packaging have spurred further research into sustainable biomass-derived alternatives, particularly underutilized Marine wastes. Highlights show the potential of Marine waste for renewable, high-performance eco-friendly food packaging materials. This is the first critical review on the use of marine isolate as feedstock in the production of biodegradable plastics. The review includes a detailed analysis of characterization in terms of physicochemical properties related to a high lignocellulosic nature and its importance as raw materials utilized among various biomass conversion technologies such as thermochemical, biochemical, and hybrid approaches. This review emphasizes the relevance of environmental Marine waste, its transition to biodegradable plastics, composite materials, and edible films boosted by catalytic pyrolysis together with enzymatic hydrolysis or microbial fermentation, causing improvement in their mechanical properties (strength), thermal stability, and ability as a barrier. In a different sense, the review further discusses the employment of nanotechnology together with green chemistry to fine-tune these conversion processes and functionalities in biopolymeric-based packaging materials. It critically reviews challenges related to process efficiency, economic viability, and regulatory compliance along with recent technological advancements in the field of biorefinery, as well as future directions for Research and Development. Thus, the review highlights that in addition to Marine waste valorisation, a broader circular bioeconomy approach could significantly support the reduction of environmental impacts through bio-based and sustainable packaging solutions.

与传统塑料包装有关的日益严重的环境问题促使进一步研究可持续的生物质替代品,特别是未充分利用的海洋废物。重点展示了海洋废物作为可再生、高性能环保食品包装材料的潜力。这是关于使用海洋分离物作为生产生物降解塑料的原料的第一篇重要综述。该综述包括详细分析了与高木质纤维素性质相关的物理化学特性及其作为各种生物质转化技术(如热化学、生化和混合方法)中使用的原材料的重要性。这篇综述强调了环境海洋废物的相关性,通过催化热解、酶水解或微生物发酵,促进其向生物降解塑料、复合材料和可食用薄膜的转变,从而改善了它们的机械性能(强度)、热稳定性和作为屏障的能力。在不同的意义上,本文进一步讨论了纳米技术与绿色化学的应用,以微调这些转化过程和生物聚合物基包装材料的功能。它批判性地回顾了与工艺效率、经济可行性和法规遵从性相关的挑战,以及生物炼制领域的最新技术进步,以及未来的研究和发展方向。因此,该综述强调,除了海洋废物增值之外,更广泛的循环生物经济方法可以通过生物基和可持续包装解决方案显著支持减少对环境的影响。
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引用次数: 0
Policy bundling for petro-state transitions: Firm-level impacts of renewable energy support 石油国家转型的政策捆绑:可再生能源支持的企业层面影响
IF 2.3 4区 环境科学与生态学 Q3 ENGINEERING, CHEMICAL Pub Date : 2025-12-04 DOI: 10.1002/ep.70260
Chokri Zehri, Mohammed Alharithi

This study analyzes how government support drives socio-economic benefits during renewable energy transitions in fossil-fuel-dependent economies, using Saudi Arabia's Vision 2030 as a strategic case. Employing dynamic fixed effects, system GMM, and Vector Autoregression models on panel data from 42 renewable energy firms (2012–2024), we find that bundled post-2016 support—financial aid, regulatory frameworks, and localization mandates—amplified outcomes. Financial support boosted renewable capacity and reduced fossil fuel imports; regulatory strength delivered sustained energy poverty reduction; and localization spurred job creation despite initial carbon costs, with regulatory and localization impacts proving slower but more durable than financial stimuli. Key policy implications highlight the necessity of coordinated policy bundling under a unified vision for petro-states, regulatory precision for equitable poverty reduction, complementary SME measures for inclusive growth under localization mandates, and sequencing that accounts for differing impact timelines, affirming the state's critical role.

本研究以沙特阿拉伯的2030愿景为战略案例,分析了政府支持如何在依赖化石燃料的经济体的可再生能源转型过程中推动社会经济效益。采用动态固定效应、系统GMM和向量自回归模型对来自42家可再生能源公司(2012-2024)的面板数据进行分析,我们发现,2016年后的支持、财政援助、监管框架和本地化授权捆绑在一起会放大结果。财政支持提高了可再生能源产能,减少了化石燃料进口;监管力度实现了持续的能源减贫;尽管最初的碳成本较高,但本地化刺激了就业机会的创造,与金融刺激相比,监管和本地化的影响被证明较慢,但更持久。关键的政策影响强调了在石油国家统一愿景下协调政策捆绑的必要性,公平减贫的监管准确性,本地化授权下的中小企业包容性增长的补充措施,以及考虑不同影响时间表的排序,肯定了国家的关键作用。
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引用次数: 0
Sustainable valorization of Madhuca longifolia flowers: A green approach to MgO nanoparticle synthesis and bioethanol production with LCA insights madhua longifolia花的可持续增值:MgO纳米颗粒合成和生物乙醇生产的绿色途径与LCA的见解
IF 2.3 4区 环境科学与生态学 Q3 ENGINEERING, CHEMICAL Pub Date : 2025-12-04 DOI: 10.1002/ep.70187
Pranali I. Kurhade, Shyam M. Kodape

Madhuca longifolia (Mahua) is a notable non-timber forest product (NTFP) in India, demonstrating remarkable phytochemistry and significant potential for the generation of bioethanol. This study examines the environmental impacts associated with MgO synthesis and biomass utilization via a dual-step process: (1) the green synthesis of MgO nanoparticles (nps) using Mahua flower extracts and (2) the production of bioethanol from the spent floral biomass. The cradle-to-gate life cycle assessment indicated a global warming potential of 11.90 kg CO2 equivalent for Step 1 of the green synthesis of MgO nps relative to conventional chemical methods, thus supporting its green attributes. Step 2 demonstrated the conversion of spent flowers with spent sugars (≈32%) into bioethanol, resulting in a yield of ≈50% compared to fresh flowers. The research highlights the principles of reduction, reuse, and recycling by converting waste into valuable bioethanol and potential soil amendments, thereby supporting a circular economy framework. This study illustrates the dual use of Mahua flowers as a renewable resource for the synthesis of nps and the production of bioethanol, while offering insights into the efficient utilization of biomass aligning with sustainability objectives.

麻花(madhua longifolia, Mahua)是印度著名的非木材林产品(NTFP),具有显著的植物化学特性和巨大的生物乙醇生产潜力。本研究通过两步工艺研究了与MgO合成和生物质利用相关的环境影响:(1)利用麻花提取物绿色合成MgO纳米颗粒(nps);(2)从废花生物质中生产生物乙醇。从摇篮到大门的生命周期评估表明,与传统化学方法相比,绿色合成MgO nps的第1步的全球变暖潜能值为11.90 kg CO2当量,从而支持其绿色属性。步骤2演示了用废糖(≈32%)将废花转化为生物乙醇,与鲜花相比,产率约为50%。该研究强调了通过将废物转化为有价值的生物乙醇和潜在的土壤改良剂来减少、再利用和再循环的原则,从而支持循环经济框架。本研究阐明了麻花作为一种可再生资源的双重用途,用于合成nps和生产生物乙醇,同时为符合可持续发展目标的生物质有效利用提供了见解。
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引用次数: 0
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Environmental Progress & Sustainable Energy
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