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IF 2.1 4区 环境科学与生态学 Q3 ENGINEERING, CHEMICAL Pub Date : 2024-11-21 DOI: 10.1002/ep.14425
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引用次数: 0
Issue Information - Cover and Table of Contents 发行信息 - 封面和目录
IF 2.1 4区 环境科学与生态学 Q3 ENGINEERING, CHEMICAL Pub Date : 2024-11-21 DOI: 10.1002/ep.14182
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引用次数: 0
Comparison of environmental and health acceptability of squatting and sitting toilets: A review 比较蹲厕和坐厕在环境和健康方面的可接受性:综述
IF 2.1 4区 环境科学与生态学 Q3 ENGINEERING, CHEMICAL Pub Date : 2024-10-22 DOI: 10.1002/ep.14507
Hanyieh Salehfar, Asma Torkalipour, Seyydeh-Amene Karimi, Hossein Fayyazi, Mostafa Mahdavianpour

In general, two types of sitting and squatting toilets are used by people in the world, each of which has its own advantages and disadvantages from an environmental and health point of view. So far, no study has been done to compare these two types of toilets, precisely. Therefore, the precise comparison of these two types of toilets based on a simple literature review was the main purpose of this study. For this purpose, the amount of water consumption, toilet paper consumption, related diseases, ease of cleaning, odor problem, and the flexibility to equip with treatment and reuse systems in both types of toilets was compared. Squatting toilets is a better option in terms of water consumption, toilet paper consumption, ease of cleaning, and diseases related to body posture. In the case of infectious diseases, the sitting toilet has better conditions and in terms of flexibility to install the treatment and reuse systems, the conditions of both were almost similar. The odor problem in the sitting toilet is less than the squatting toilet. Since the advantages and disadvantages of both types of toilets are also complementary, the best option is to install both toilets together.

一般来说,世界上人们使用的厕所有坐式和蹲式两种,从环保和健康的角度来看,这两种厕所各有利弊。迄今为止,还没有研究对这两种厕所进行精确比较。因此,根据简单的文献综述对这两种厕所进行精确比较是本研究的主要目的。为此,我们比较了这两种类型厕所的耗水量、厕纸消耗量、相关疾病、清洁难易程度、异味问题以及配备处理和再利用系统的灵活性。从耗水量、厕纸消耗量、清洁难易程度以及与身体姿势有关的疾病等方面来看,蹲厕都是更好的选择。在传染病方面,坐式厕所的条件更好,而在安装处理和再利用系统的灵活性方面,两种厕所的条件几乎相似。坐式厕所的臭味问题比蹲式厕所小。由于两种厕所的优缺点也是互补的,最好的选择是同时安装两种厕所。
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引用次数: 0
Incorporation of trace metals in Hanford waste boehmite mineral phases and dissolution rate impacts 汉福德废物波美度石矿物相中痕量金属的掺入及其溶解速率的影响
IF 2.1 4区 环境科学与生态学 Q3 ENGINEERING, CHEMICAL Pub Date : 2024-10-20 DOI: 10.1002/ep.14505
Amy M. Westesen, Gregg J. Lumetta, Reid A. Peterson

Data from radioactive Hanford tank waste samples was analyzed to assess whether trace metals present were incorporated into the bulk boehmite matrix or were simply intermingled with the bulk material and subsequent impacts to the boehmite dissolution rate. Results suggest that chromium is primarily blended into the bulk boehmite, with a small fraction present on the surface of the solids. However, increasing the level of chromium incorporation 30-fold decreased the dissolution rate of boehmite by only 8%, suggesting incorporation of chromium into these samples had a minimal impact on the dissolution rate. Iron was also found to be incorporated in the boehmite solids. Silicon appears to be simply intermingled and not blended into the boehmite crystals.

对放射性汉福德储罐废料样本的数据进行了分析,以评估存在的痕量金属是融入了块状波美度石基体中,还是仅仅与块状材料混合在一起,以及随后对波美度石溶解速率的影响。结果表明,铬主要与块状波墨石混合,只有一小部分存在于固体表面。然而,将铬的掺入量提高 30 倍后,波美度石的溶解率仅降低了 8%,这表明铬掺入这些样品对溶解率的影响微乎其微。此外,还发现沸石固体中含有铁。硅似乎只是混合在一起,并没有掺入到沸石晶体中。
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引用次数: 0
Production and recycling of blast furnace slag: A life cycle assessment approach in India 高炉矿渣的生产和回收利用:印度的生命周期评估方法
IF 2.1 4区 环境科学与生态学 Q3 ENGINEERING, CHEMICAL Pub Date : 2024-10-20 DOI: 10.1002/ep.14503
Rohit B. Meshram, Kanai L. Sahoo, Ganapati D. Yadav, Kumudini V. Marathe

This article investigated the cradle-to-gate environmental impact of granulated blast furnace slag (GBFS) produced in the steel industry and replacement of blast furnace (BF) slag (50%) in place of clinker in Portland slag cement using GaBi software (Indian extension database). In case of GBFS production, maximum burden on the environment is due to BF slag production and the amount of electricity consumed (161 MJ/ton) during the granulation process. The influence of electricity sources on GBFS production was studied via scenario analysis. For investigation, solar and thermal electricity mixes were considered in 50:50 and 75:25 ratios. For the 75:25 ratios, the abiotic depletion potential (fossil), acidification, eutrophication, global warming, and human toxicity potential show a decreasing trend of approximately 45%, 49%, 48%, 46%, and 41%, respectively. The scenario analysis of BF slag transportation (from 100 to 750 km) demonstrates a negative impact due to fuel. The results quantitatively confirm that the addition of GBFS can lower the overall impact for construction and steel industries.

本文使用 GaBi 软件(印度扩展数据库)调查了钢铁行业生产的粒化高炉矿渣(GBFS)以及在波特兰矿渣水泥中用高炉矿渣(50%)替代熟料对环境的影响。在 GBFS 的生产中,对环境造成最大负担的是高炉矿渣的生产和粒化过程中的耗电量(161 兆焦耳/吨)。通过情景分析研究了电力来源对 GBFS 生产的影响。在调查中,考虑了太阳能和热能电力的混合比例为 50:50 和 75:25。在 75:25 的比例下,非生物损耗潜能值(化石)、酸化、富营养化、全球变暖和人类毒性潜能值分别呈现出约 45%、49%、48%、46% 和 41% 的下降趋势。对碱性炉渣运输(从 100 公里到 750 公里)的情景分析表明,燃料会产生负面影响。结果从数量上证实,添加 GBFS 可以降低对建筑和钢铁行业的整体影响。
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引用次数: 0
Utilization of waste from paper industry as a heterogeneous base catalyst for the synthesis of biodiesel 利用造纸业废料作为合成生物柴油的异相基础催化剂
IF 2.1 4区 环境科学与生态学 Q3 ENGINEERING, CHEMICAL Pub Date : 2024-10-19 DOI: 10.1002/ep.14497
Sultana Parveen Ahmed, Sudhamoyee Kataky, Riku Dutta, Ashim Jyoti Thakur, Swapan Kumar Dolui

To meet the pressing demand for alternative biofuel in the contemporary world, the production cost of biodiesel has to be decreased. Hence, this work addresses the usage of CaCO3-rich industrial waste produced in a local paper industry in Assam, India for the synthesis of a heterogeneous catalyst for biodiesel synthesis. The collected lime sludge waste was subjected to calcination at 800°C for 3 h producing a CaO-rich catalyst which was then employed in the transesterification of cottonseed oil. The optimized reaction conditions obtained were 5 wt% catalyst concentration, oil to methanol molar ratio of 1:12 at 65°C temperature, and 3 h of reaction time. The catalyst's reusability was evaluated up to four cycles. Besides, the prepared catalyst has been characterized using Fourier transfer infrared spectroscopy (FTIR), powder X-ray Diffraction (p-XRD), Scanning Electron Microscope (SEM), Energy Dispersive X-ray analysis (EDX), and Brunauer–Emmett–Teller (BET) techniques and its basicity was measured using Hammett indicators. Moreover, the biodiesel obtained was characterized with 1H-nuclear magnetic resonance (NMR), 13C-NMR, Gas Chromatography- Mass Spectrometry (GC–MS), and FTIR techniques. A biodiesel yield of 98.03% was achieved and the quality of biodiesel formed during the transesterification of CSO also conforms to EN 14214 and ASTM D 6751 standards. Thus, our study highlights the sustainability and the potential for future industrial application of paper industrial waste in the production of biodiesel.

为了满足当今世界对替代生物燃料的迫切需求,必须降低生物柴油的生产成本。因此,本研究利用印度阿萨姆邦当地造纸业产生的富含 CaCO3 的工业废料,合成用于合成生物柴油的异相催化剂。收集的石灰污泥废料在 800°C 煅烧 3 小时后产生富含 CaO 的催化剂,然后用于棉籽油的酯交换反应。优化后的反应条件为:催化剂浓度为 5 wt%,油与甲醇的摩尔比为 1:12,温度为 65°C,反应时间为 3 小时。对催化剂的重复使用性进行了评估,最多可重复使用四次。此外,还使用傅立叶变换红外光谱(FTIR)、粉末 X 射线衍射(p-XRD)、扫描电子显微镜(SEM)、能量色散 X 射线分析(EDX)和布鲁瑙尔-艾美特-泰勒(BET)技术对制备的催化剂进行了表征,并使用哈米特指标测量了其碱性。此外,还利用 1H-核磁共振(NMR)、13C-核磁共振(13C-NMR)、气相色谱-质谱(GC-MS)和傅立叶变换红外(FTIR)技术对生物柴油进行了表征。生物柴油产率达到 98.03%,CSO 的酯交换反应生成的生物柴油质量也符合 EN 14214 和 ASTM D 6751 标准。因此,我们的研究强调了造纸工业废料在生物柴油生产中的可持续性和未来工业应用的潜力。
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引用次数: 0
Recovery of electrical power from exhaust air—role of vertical axis wind turbine 从废气中回收电力--垂直轴风力涡轮机的作用
IF 2.1 4区 环境科学与生态学 Q3 ENGINEERING, CHEMICAL Pub Date : 2024-10-19 DOI: 10.1002/ep.14502
Soumyadip Banerjee, Tanmoy Maity

This article explores the potential of regeneration of power from unnatural wind sources with the help of vertical axis wind turbines (VAWT). Researchers are searching for urban as well as industrial wind sources, which can be useful as the natural wind source to obtain electrical energy and utilize it. The wind sources considered here are the exhaust of the cooling or ventilation fans used in buildings, industries, and other places. The Darrieus VAWT extracts wind power from the exhaust air and reduces the power consumption of the concerned electrical drives. These uncommon energy sources have an inherent capability to recover a significant amount of energy without polluting the environment with less payback period. Recovered energy can be suitably converted into electrical energy and may be fed back to the power grid without any pollution, thus minimizing the total energy consumption of the building and reducing the cost operations. A detailed study of experimental models with different types of assembly and turbine models is conducted here with power outputs and operational behaviors on the existing systems. Various parameters and factors for existing and new applications are in detail that show the system has no negative impact on regular operation.

本文探讨了借助垂直轴风力涡轮机(VAWT)从非自然风源再生电力的潜力。研究人员正在寻找城市和工业风源,它们可以作为自然风源获取电能并加以利用。这里考虑的风源是建筑物、工业和其他场所使用的冷却或通风扇的排气。达里厄斯 VAWT 可从废气中提取风能,降低相关电力驱动装置的功耗。这些不常见的能源本身具有回收大量能源的能力,而且不会污染环境,投资回收期较短。回收的能量可以适当地转化为电能,并可以无污染地反馈到电网,从而最大限度地减少建筑物的总能耗,降低运营成本。这里对不同类型的组件和涡轮机模型的实验模型进行了详细研究,并对现有系统的功率输出和运行行为进行了分析。对现有和新应用的各种参数和因素进行了详细说明,表明该系统对正常运行没有负面影响。
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引用次数: 0
Degradation autocatalytic epoxidation of oleic acid derived from palm oil via in situ performic acid mechanism 通过原位执行酸机制对棕榈油中提取的油酸进行降解自催化环氧化反应
IF 2.1 4区 环境科学与生态学 Q3 ENGINEERING, CHEMICAL Pub Date : 2024-10-17 DOI: 10.1002/ep.14498
Hamzah Hafizuddin Habri, Ahmad Shauqi Abrar Shahrizan, Intan Suhada Azmi, Norhafini Hambali, Amnani Shamjuddin, Subhan Salaeh, Mohd Jumain Jalil

Owing to the increasing demands for eco-friendly epoxides derived from vegetable oils, much effort has been made regarding the epoxidation of oleic acid in recent years. However, to date, there is a paucity of studies on the autocatalytic epoxidation specifically epoxidized oleic acid as it is not fully utilized. The autocatalytic epoxidation of oleic acid was carried out by using in situ generated performic acid to produce epoxidized oleic acid. Performic acid was formed by mixing formic acid (as oxygen carrier) and hydrogen peroxide (as oxygen donor). A maximum relative conversion to oxirane (RCO) achieved was 87% at optimal formic acid molar ratio to oleic acid under following conditions: (1) reaction temperature: 75°C, (2) stirring speed: 300 rpm, (3) formic acid/oleic acid molar ratio: 2.5, and (4) hydrogen peroxide/oleic acid molar ratio: 1.0. The degradation of epoxidized oleic acid after oxirane ring opening invites hydroxylation reaction take place called alcoholysis and hydrolysis. The hydroxyl value from alcoholysis was 346.9 mg KOH/g while the hydroxyl value of hydrolysis was 296.4 mg KOH/g using autocatalyzed reaction. In conclusion, high and low hydroxyl value has their own benefits as intermediate product for polymer application such as flexible polyurethane and rigid polyurethane.

由于对从植物油中提取的环保型环氧化物的需求不断增加,近年来人们在油酸的环氧化方面做出了很多努力。然而,迄今为止,有关专门环氧化油酸的自催化环氧化的研究还很少,因为它还没有得到充分利用。油酸的自催化环氧化是利用原位生成的顺丁烯二酸来生产环氧化油酸的。过甲酸是由甲酸(作为氧载体)和过氧化氢(作为氧供体)混合而成。在以下条件下,当甲酸与油酸的摩尔比达到最佳时,环氧乙烷(RCO)的最大相对转化率为 87%:(1) 反应温度:75°C;(2) 搅拌速度:300 rpm;(3) 甲酸/油酸摩尔比:2.5;(4) 过氧化氢/油酸摩尔比:1.0。环氧化油酸在环氧乙烷开环后发生羟基化反应的降解过程称为醇解和水解。醇解的羟值为 346.9 毫克 KOH/克,而使用自动催化反应水解的羟值为 296.4 毫克 KOH/克。总之,高羟值和低羟值作为聚合物应用(如柔性聚氨酯和刚性聚氨酯)的中间产品各有好处。
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引用次数: 0
Influencing factor and path research on the high-quality development of the urban mining industry 城市矿业高质量发展的影响因素及路径研究
IF 2.1 4区 环境科学与生态学 Q3 ENGINEERING, CHEMICAL Pub Date : 2024-10-17 DOI: 10.1002/ep.14491
Yusu Wang, Jinlong Liu, Luomeng Li

The recycling of urban mining is one of the means to alleviate resource bottlenecks and build an ecological industrial system in China. To study the characteristics of high-quality development of the urban mining industry, the high-quality development capacity of this industry from 2006 to 2020 is evaluated based on the entropy weighting – catastrophe progression method, and its development pattern and influencing factors are discussed. The analysis results show that: ①The high-quality development capacity of the urban mining industry declines slowly, with an average annual decline of about 0.399% from 2006 to 2020, and the overall development quality level is on average. The provinces with high-quality development are scattered from the east region of the Hu Line to the north and south regions, and non-high-quality development provinces are contiguous. ②The positive spatial correlation of the urban mining industry is significant, but the agglomeration degree in high-quality development provinces is low-high-low. According to the spatial agglomeration characteristics, the high-quality development pattern is divided into five zones. ③Among the factors driving the high-quality development of the urban mining industry, regional GDP per capita, R&D investment, the number of patent applications granted and Internet penetration rate are the core influencing factors. High-quality sustainable zone and high-quality restoration zone need to rely on the number of granted patent applications to achieve high-quality maintenance and restoration, high-quality compensation zone and high-quality stability maintenance zone need GDP per capita and R&D investment, high-quality development zone relies on Internet penetration rate to explore high-quality development potential.

城市矿业的循环发展是我国缓解资源瓶颈制约、构建生态产业体系的手段之一。为研究城市矿业高质量发展的特征,基于熵权-灾变递进法对城市矿业2006-2020年高质量发展能力进行了评价,并对其发展模式和影响因素进行了探讨。分析结果表明城市矿业高质量发展能力下降缓慢,2006-2020 年年均下降约 0.399%,总体发展质量水平一般。高质量发展省份由沪东地区向南北地区分散,非高质量发展省份连片。城市矿业空间正相关性显著,但高质量发展省份集聚程度低-高-低。根据空间集聚特征,将高质量发展格局划分为五个区域。推动城市矿业高质量发展的因素中,地区人均 GDP、研发投入、专利申请授权量和互联网普及率是核心影响因素。高质量可持续发展区和高质量修复区需要依靠专利申请授权量来实现高质量维护和修复,高质量补偿区和高质量维稳区需要人均 GDP 和研发投入,高质量发展区需要依靠互联网普及率来挖掘高质量发展潜力。
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引用次数: 0
Using low-cost, eco-friendly natural and modified potato peels to effectively remove Mn(II) ions from aqueous solutions 利用低成本、环保的天然和改性马铃薯皮有效去除水溶液中的锰(II)离子
IF 2.1 4区 环境科学与生态学 Q3 ENGINEERING, CHEMICAL Pub Date : 2024-10-17 DOI: 10.1002/ep.14496
Canpolat Mutlu, Yalçın Altunkaynak

The objective of this investigation is to look into the potential use of trash potato peels and processed potato peels as a solution for effectively removing Mn(II) ions extracted from aqueous solutions. The optimal working circumstances for removing Mn(II) ions from aqueous solution in PP are an initial concentration of 300 mg/L, an adsorbent dose of 0.3 g, a contact time (CT) of 100 min, and a solution pH of 6.08. The optimal working conditions for MPP were established to be an initial concentration of 300 mg/L, an adsorbent dosage of 0.15 g, a CT of 100 min, and a solution pH of 6.08. Studies were conducted at various temperatures to better understand the removal capabilities of adsorbent compounds. The removal abilities of Mn(II) ions for PP were determined to be 10.787, 13.698, and 16.556 mg/g at varied temperatures (25, 35, and 45°C), respectively. Under the same conditions, the removal capacity of MPP was determined to be 34.246, 45.045, and 51.813 mg/g. Further investigation of the adsorption kinetics revealed that the experimental results suited the pseudo-second-order model for both PP and MPP adsorbents. Thermodynamic analyses demonstrated that the endothermic process of Mn(II) metal ion adsorption onto the adsorbents occurred spontaneously. The study found that both PP and MPP were very efficient and ecologically friendly adsorbents for removing Mn(II) ions from aqueous solutions. Their demonstrated performance highlights their potential value in sustainable wastewater treatment applications, which accord with environmentally conscious behaviors.

本研究的目的是探讨垃圾马铃薯皮和加工过的马铃薯皮作为有效去除从水溶液中提取的锰(II)离子的解决方案的潜在用途。聚丙烯去除水溶液中锰(II)离子的最佳工作条件是:初始浓度为 300 毫克/升,吸附剂剂量为 0.3 克,接触时间(CT)为 100 分钟,溶液 pH 值为 6.08。MPP 的最佳工作条件为:初始浓度 300 毫克/升,吸附剂用量 0.15 克,接触时间 100 分钟,溶液 pH 值 6.08。研究在不同温度下进行,以更好地了解吸附剂化合物的去除能力。在不同温度(25、35 和 45°C)下,聚丙烯对锰(II)离子的去除能力分别为 10.787、13.698 和 16.556 mg/g。在相同条件下,MPP 的去除能力分别为 34.246、45.045 和 51.813 mg/g。对吸附动力学的进一步研究表明,实验结果符合 PP 和 MPP 吸附剂的伪二阶模型。热力学分析表明,Mn(II) 金属离子在吸附剂上的吸附过程是自发的。研究发现,PP 和 MPP 都是从水溶液中去除锰(II)离子的高效、生态友好型吸附剂。这两种吸附剂所表现出的性能突显了它们在可持续废水处理应用中的潜在价值,符合人们的环保意识。
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引用次数: 0
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