A Case Study of Supramolecular Organization: One Ferrocene Substituted Iminodiacetamide and its Chloroform Solvate

IF 0.7 4区 化学 Q4 CHEMISTRY, MULTIDISCIPLINARY Croatica Chemica Acta Pub Date : 2017-12-29 DOI:10.5562/CCA3270
N. P. Juraj, J. Pennec, B. Perić, S. Kirin
{"title":"A Case Study of Supramolecular Organization: One Ferrocene Substituted Iminodiacetamide and its Chloroform Solvate","authors":"N. P. Juraj, J. Pennec, B. Perić, S. Kirin","doi":"10.5562/CCA3270","DOIUrl":null,"url":null,"abstract":"This paper describes the synthesis of an amide based conjugate of ferrocene (Fc), ethylenediamine (eda) and iminodiacetamide (imda), Fc-eda-imda (2). The compound (2) is characterized by various spectroscopic, crystallographic and thermoanalytical techniques in solid state and in solution. By crystallization of the title compound 2 from methanol or chloroform, two different crystalline forms 2a and 2b were obtained, respectively. In their X-ray single crystal structures, 2a and 2b reveal similar 2D hydrogen bonding networks, but differ by supramolecular organization, namely aromatic π – π stacking interactions in the third spatial dimension.","PeriodicalId":10822,"journal":{"name":"Croatica Chemica Acta","volume":null,"pages":null},"PeriodicalIF":0.7000,"publicationDate":"2017-12-29","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"4","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"Croatica Chemica Acta","FirstCategoryId":"92","ListUrlMain":"https://doi.org/10.5562/CCA3270","RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q4","JCRName":"CHEMISTRY, MULTIDISCIPLINARY","Score":null,"Total":0}
引用次数: 4

Abstract

This paper describes the synthesis of an amide based conjugate of ferrocene (Fc), ethylenediamine (eda) and iminodiacetamide (imda), Fc-eda-imda (2). The compound (2) is characterized by various spectroscopic, crystallographic and thermoanalytical techniques in solid state and in solution. By crystallization of the title compound 2 from methanol or chloroform, two different crystalline forms 2a and 2b were obtained, respectively. In their X-ray single crystal structures, 2a and 2b reveal similar 2D hydrogen bonding networks, but differ by supramolecular organization, namely aromatic π – π stacking interactions in the third spatial dimension.
查看原文
分享 分享
微信好友 朋友圈 QQ好友 复制链接
本刊更多论文
一个二茂铁取代亚氨基二乙酰胺及其氯仿溶剂化物的超分子组织研究
本文合成了二茂铁(Fc)、乙二胺(eda)和亚氨基二乙酰胺(imda)的酰胺基共轭物Fc-eda-imda(2)。该化合物(2)在固态和溶液中通过各种光谱、晶体学和热分析技术进行了表征。标题化合物2由甲醇或氯仿结晶,分别得到两种不同的结晶形式2a和2b。在它们的x射线单晶结构中,2a和2b显示出相似的二维氢键网络,但在超分子组织上有所不同,即在三维空间上芳香π - π堆叠相互作用。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
求助全文
约1分钟内获得全文 去求助
来源期刊
Croatica Chemica Acta
Croatica Chemica Acta 化学-化学综合
CiteScore
0.60
自引率
0.00%
发文量
3
审稿时长
18 months
期刊介绍: Croatica Chemica Acta (Croat. Chem. Acta, CCA), is an international journal of the Croatian Chemical Society publishing scientific articles of general interest to chemistry.
期刊最新文献
Spectrophotometric Determination of N-acetyl-L-Cysteine in Pharmaceutical Formulations by Flow Injection and Sequential Injection Analysis: Comparison of the Methods Comparison of Radon Adsorption on Hematite and Charcoal Activated Powder in Air Synthesis, Experimental and Theoretical Characterization of (μ4-oxo)hexakis(μ2-chloro)-tetrakis[1-(allyl)-1H-imidazole]tetracopper(II) Ecofriendly Synthesis of DHPMs using Copper-based Nano catalysts and Evaluation of Antibacterial Activity Influence of Bitartrate Ion Concentration in the Copper Electrodeposition Onto a Polycrystalline Gold Electrode
×
引用
GB/T 7714-2015
复制
MLA
复制
APA
复制
导出至
BibTeX EndNote RefMan NoteFirst NoteExpress
×
×
提示
您的信息不完整,为了账户安全,请先补充。
现在去补充
×
提示
您因"违规操作"
具体请查看互助需知
我知道了
×
提示
现在去查看 取消
×
提示
确定
0
微信
客服QQ
Book学术公众号 扫码关注我们
反馈
×
意见反馈
请填写您的意见或建议
请填写您的手机或邮箱
已复制链接
已复制链接
快去分享给好友吧!
我知道了
×
扫码分享
扫码分享
Book学术官方微信
Book学术文献互助
Book学术文献互助群
群 号:481959085
Book学术
文献互助 智能选刊 最新文献 互助须知 联系我们:info@booksci.cn
Book学术提供免费学术资源搜索服务,方便国内外学者检索中英文文献。致力于提供最便捷和优质的服务体验。
Copyright © 2023 Book学术 All rights reserved.
ghs 京公网安备 11010802042870号 京ICP备2023020795号-1