Aluminium alloy corrosion inhibition by a two-stage modified nanoporous zeolite

IF 1.5 4区 材料科学 Q4 MATERIALS SCIENCE, MULTIDISCIPLINARY Corrosion Engineering, Science and Technology Pub Date : 2022-09-23 DOI:10.1080/1478422X.2022.2125647
S. Korniy, I. Zin, O. Khlopyk, M. Holovchuk, M. Danyliak, B. Datsko, P. Lyutyy
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引用次数: 1

Abstract

ABSTRACT A two-stage synthesis of anti-corrosion pigments based on synthetic zeolites was performed. New pigments retain the zeolite framework structure in the nanopores of which the amorphised phosphate phase is formed. The pigments effectively reduce the aluminium alloy corrosion in sodium chloride solution. The most effective pigment is obtained by mechanochemical modification of zeolite with calcium cations, followed by liquid-phase treatment with zinc nitrate and sodium phosphate. The pigments induce the formation of a protective film of zinc hydroxides on intermetallic inclusions of the alloy. The formation of phosphates is possible on the anode sections. The pigments can become promising inhibitory components of primer paints used for the protection of structures made from aluminium alloys.
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两级改性纳米多孔沸石对铝合金的缓蚀作用
摘要以合成沸石为原料,进行了两段合成防腐颜料的研究。新颜料在纳米孔中保留了沸石骨架结构,其中形成了无定形磷酸盐相。该色素有效地降低了铝合金在氯化钠溶液中的腐蚀。用钙离子对沸石进行机械化学改性,然后用硝酸锌和磷酸钠进行液相处理,得到最有效的颜料。颜料诱导在合金的金属间夹杂物上形成氢氧化锌保护膜。在阳极部分可能形成磷酸盐。该颜料可作为底漆的抑制成分,用于保护铝合金结构。
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来源期刊
Corrosion Engineering, Science and Technology
Corrosion Engineering, Science and Technology 工程技术-材料科学:综合
CiteScore
3.20
自引率
5.60%
发文量
58
审稿时长
3.4 months
期刊介绍: Corrosion Engineering, Science and Technology provides broad international coverage of research and practice in corrosion processes and corrosion control. Peer-reviewed contributions address all aspects of corrosion engineering and corrosion science; there is strong emphasis on effective design and materials selection to combat corrosion and the journal carries failure case studies to further knowledge in these areas.
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