Retention of arsenic using alkali- and acid-bonded low temperature ceramics

W. Bruckard, D. Brew, E. Vance, G. Sparrow
{"title":"Retention of arsenic using alkali- and acid-bonded low temperature ceramics","authors":"W. Bruckard, D. Brew, E. Vance, G. Sparrow","doi":"10.1080/25726641.2021.1942752","DOIUrl":null,"url":null,"abstract":"ABSTRACT Immobilisation of AsIII and AsV using alkali- and acid-bonded low temperature ceramics (LTCs), respectively, has been investigated. Arsenic was loaded into these matrices as solubilised arsenic or as a solid via precipitation with a metal nitrate. Where appropriate, samples were heated to 1000°C to consolidate their microstructure and reduce their open porosity. Samples were assessed according to microstructural characterisation and standard leaching protocols. Alkali-bonded LTCs, even after the application of a thermal treatment, did not bind arsenic sufficiently to pass a TCLP protocol, whereas acid bonded LTCs showed better potential for immobilising As. At a loading of 5 wt% As2O5, a TCLP leach test on an acid bonded LTC resulted in As levels of 7 ppm, close to the regulatory limit of 5 ppm As.","PeriodicalId":43710,"journal":{"name":"Mineral Processing and Extractive Metallurgy-Transactions of the Institutions of Mining and Metallurgy","volume":null,"pages":null},"PeriodicalIF":0.9000,"publicationDate":"2021-07-27","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"Mineral Processing and Extractive Metallurgy-Transactions of the Institutions of Mining and Metallurgy","FirstCategoryId":"1085","ListUrlMain":"https://doi.org/10.1080/25726641.2021.1942752","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q3","JCRName":"MINING & MINERAL PROCESSING","Score":null,"Total":0}
引用次数: 0

Abstract

ABSTRACT Immobilisation of AsIII and AsV using alkali- and acid-bonded low temperature ceramics (LTCs), respectively, has been investigated. Arsenic was loaded into these matrices as solubilised arsenic or as a solid via precipitation with a metal nitrate. Where appropriate, samples were heated to 1000°C to consolidate their microstructure and reduce their open porosity. Samples were assessed according to microstructural characterisation and standard leaching protocols. Alkali-bonded LTCs, even after the application of a thermal treatment, did not bind arsenic sufficiently to pass a TCLP protocol, whereas acid bonded LTCs showed better potential for immobilising As. At a loading of 5 wt% As2O5, a TCLP leach test on an acid bonded LTC resulted in As levels of 7 ppm, close to the regulatory limit of 5 ppm As.
查看原文
分享 分享
微信好友 朋友圈 QQ好友 复制链接
本刊更多论文
碱-酸结合低温陶瓷对砷的保留作用
摘要研究了分别使用碱键合和酸键合低温陶瓷(LTCs)对AsIII和AsV的固定化。砷以溶解的砷或通过与金属硝酸盐沉淀而以固体的形式加载到这些基质中。在适当的情况下,将样品加热至1000°C,以巩固其微观结构并降低其开放孔隙率。根据微观结构特征和标准浸出方案对样品进行评估。碱键合的LTCs,即使在应用热处理后,也不能充分结合砷以通过TCLP方案,而酸键合的LTC显示出更好的固定As的潜力 wt%的As2O5,在酸结合LTC上进行的TCLP浸出试验导致As水平为7 ppm,接近5的监管限值 ppm As。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
求助全文
约1分钟内获得全文 去求助
来源期刊
CiteScore
3.50
自引率
0.00%
发文量
6
期刊最新文献
Dissolution of gold in the presence of copper ion and diethylenetriamine (DETA) Adsorption of tannic acid as depressant in the flotation separation of fluorite and bastnaesite Demonstration of dry magnetic separation to upgrade the Mn:Fe ratio of a ferromanganese ore sample A mathematical model of a twin-shaft parallel flow regenerative lime kiln Beneficiation of a Nigerian lepidolite ore by sulfuric acid leaching
×
引用
GB/T 7714-2015
复制
MLA
复制
APA
复制
导出至
BibTeX EndNote RefMan NoteFirst NoteExpress
×
×
提示
您的信息不完整,为了账户安全,请先补充。
现在去补充
×
提示
您因"违规操作"
具体请查看互助需知
我知道了
×
提示
现在去查看 取消
×
提示
确定
0
微信
客服QQ
Book学术公众号 扫码关注我们
反馈
×
意见反馈
请填写您的意见或建议
请填写您的手机或邮箱
已复制链接
已复制链接
快去分享给好友吧!
我知道了
×
扫码分享
扫码分享
Book学术官方微信
Book学术文献互助
Book学术文献互助群
群 号:481959085
Book学术
文献互助 智能选刊 最新文献 互助须知 联系我们:info@booksci.cn
Book学术提供免费学术资源搜索服务,方便国内外学者检索中英文文献。致力于提供最便捷和优质的服务体验。
Copyright © 2023 Book学术 All rights reserved.
ghs 京公网安备 11010802042870号 京ICP备2023020795号-1