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Dissolution of gold in the presence of copper ion and diethylenetriamine (DETA) 铜离子和二乙烯三胺(DETA)存在下金的溶解
IF 1.2 Q2 Earth and Planetary Sciences Pub Date : 2023-08-28 DOI: 10.1080/25726641.2023.2249703
E. A. Agorhom, C. Owusu, Lilian Gyedu
ABSTRACT Cyanidation is the most widely used technique for gold extraction worldwide. However, its efficiency in gold extraction has decreased due to gold association with base metals such as copper. Copper is known to form different complexes with cyanide depending on the pulp pH. These Cu-CN complexes deplete the pulp of free cyanide, thereby decreasing gold leaching. The study examined the application of diethylenetriamine (DETA) in cyanidation to minimise copper ions effect on gold cyanidation. Leaching tests performed in the presence of copper ions reduced gold recovery from 93% to 15% at a copper sulphate concentration of 1% and increased cyanide consumption by 10%. The introduction of DETA (between 0.2% and 1%) however restored gold recovery back to normal as the baseline without copper ions and also enabled gold extraction at a reduced cyanide strength. Based on the study, DETA could be used during gold–copper cyanide leaching to minimise the copper ion effect and enhance gold extraction.
氰化是世界上应用最广泛的黄金提取技术。然而,由于金与铜等贱金属的结合,其金提取效率降低。已知铜与氰化物形成不同的络合物,这取决于矿浆的pH。这些Cu-CN络合物耗尽了矿浆中的游离氰化物,从而减少了金的浸出。本研究考察了二亚乙基三胺(DETA)在氰化中的应用,以最大限度地减少铜离子对金氰化的影响。在铜离子存在下进行的浸出试验将硫酸铜浓度为1%时的金回收率从93%降低到15%,氰化物消耗增加了10%。然而,DETA(在0.2%和1%之间)的引入使金回收率恢复到正常,作为没有铜离子的基线,并且还能够以降低的氰化物强度提取金。根据这项研究,DETA可用于金-铜氰化浸出,以最大限度地减少铜离子的影响并提高金的提取率。
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引用次数: 0
Adsorption of tannic acid as depressant in the flotation separation of fluorite and bastnaesite 单宁酸作为抑制剂在萤石和氟碳铈矿浮选分离中的吸附
IF 1.2 Q2 Earth and Planetary Sciences Pub Date : 2023-08-07 DOI: 10.1080/25726641.2023.2243198
Chunlei Guo, Shaochun Hou, Hailong Jin, Weiwei Wang
ABSTRACT Fluorite, a strategic industrial mineral, was investigated for flotation separation from bastnaesite with tannic acid (TA) as depressant. In this study, the adsorption analysis indicates that the adsorption density of TA on bastnaesite was greater than that of fluorite. The zeta potential, Fourier transform infrared spectroscopy (FTIR), and X-ray photoelectron spectroscopy (XPS) provide the evidence that chemisorption and electrostatic attraction occurred simultaneously between TA and fluorite or bastnaesite at optimal pH, the latter also involving hydrogen bonding interactions. Furthermore, the micro-flotation and batch flotation results suggest that TA could effectively depress bastnaesite with a negligible effect on fluorite at low concentrations, and that TA attached to the surface of bastnaesite precluded the adsorption of phthalic acid (PA) as collector, whereas it could be adsorbed on the fluorite surface. These findings offer a robust theoretical foundation and valid guidance for the flotation separation of fluorite from bastnaesite in industrial processes.
摘要研究了战略工业矿物萤石在单宁酸(TA)抑制剂的作用下从氟碳铈矿中浮选分离。在本研究中,吸附分析表明TA在氟碳石上的吸附密度大于萤石。zeta电位、傅里叶变换红外光谱(FTIR)和x射线光电子能谱(XPS)证明了TA与萤石或氟碳铈矿在最佳pH条件下同时发生化学吸附和静电吸引,后者还涉及氢键相互作用。此外,微浮选和批量浮选结果表明,在低浓度下,TA可以有效抑制氟碳石,对萤石的影响可以忽略不计,并且TA附着在氟碳石表面阻碍了邻苯二甲酸(PA)作为捕收剂的吸附,而可以吸附在萤石表面。研究结果为氟碳铈矿与萤石的浮选分离提供了坚实的理论基础和有效的指导。
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引用次数: 0
Demonstration of dry magnetic separation to upgrade the Mn:Fe ratio of a ferromanganese ore sample 提高锰铁矿石样品锰铁比的干式磁选示范
IF 1.2 Q2 Earth and Planetary Sciences Pub Date : 2023-06-17 DOI: 10.1080/25726641.2023.2222909
M. Peterson, R. Karadkal, V. Nunna, S. Hapugoda, P. Austin
ABSTRACT Sighter Induced Roll Magnetic Separation tests were conducted on a ferromanganese ore sample to determine the potential to significantly upgrade the Mn content and Mn:Fe ratio. The sample had a Mn:Fe ratio of 1.3 and was comprised of hematite, cryptomelane, pyrolusite, quartz, goethite and braunite. Tests at 4.7, 2.3 and 1 mm top sizes revealed better separation of Fe from Mn at the 2.3 and 1 mm top sizes. This reflected the better liberation and separation characteristics of Fe oxides at 2.3 mm and both Fe and Mn oxides at 1 mm. A test on the −2.3 + 0.6 mm size fraction improved the Mn:Fe ratio to 4.6, the Mn content to 41.5 wt% with 69.4% mass recovery and 84.2% Mn recovery. Particle magnetic susceptibility was influenced by particle microporosity, and its effect on apparent density, resulting in some Mn oxides reporting to the magnetic concentrate and Fe oxides to the tails.
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引用次数: 0
A mathematical model of a twin-shaft parallel flow regenerative lime kiln 双轴平行流蓄热式石灰窑的数学模型
IF 1.2 Q2 Earth and Planetary Sciences Pub Date : 2023-06-05 DOI: 10.1080/25726641.2023.2217403
Sujit A. Jagnade, Saurabh K. Nayak, J. M. Korath, N. Viswanathan, P. Abhale
ABSTRACT Lime is an important flux used in the iron and steel-making processes. Tata Steel Jamshedpur uses a twin-shaft Parallel Flow Regenerative type kiln to calcine limestone. Previously, the kiln was operated based on the temperature measurement at only three locations. This led to suboptimal kiln performance and difficulty in maintaining lime quality. A thermal digital twin was developed using first principles to address these issues. A set of unsteady-state partial-differential equations representing the thermophysical phenomena is solved numerically using the finite volume method. The model was validated with the measured flue gas temperature and lime temperatures. The model is implemented online with the real-time operating parameters to estimate the temperature profile of solid and gas and the degree of conversion of limestone. This real-time visibility enables the operators to optimize the process and achieve lime conversion up to 94%, resulting in energy savings of 31.8 GJ/day and stable lime quality.
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引用次数: 0
Beneficiation of a Nigerian lepidolite ore by sulfuric acid leaching 尼日利亚锂云母矿的硫酸浸出选矿
IF 1.2 Q2 Earth and Planetary Sciences Pub Date : 2023-05-26 DOI: 10.1080/25726641.2023.2216612
Daud T. Olaoluwa, A. A. Baba, A. L. Oyewole
ABSTRACT The dissolution of a Nigerian lepidolite ore in sulphuric acid solution for its optimal industrial transformation was carried out. The degree of influence of the acid concentration, reaction temperature, particle diameter, and reaction time on the rate of the ore dissolution was investigated. These parameters were observed to enhance the rate of the dissolution as the acid concentration was increased from 0.1 to 1.5 mol/L, reaction temperature from room temperature (27 ± 2°C) to 75°C, particle diameter from 63 to 90 µm and reaction time from 5 to 120 min, respectively. The ore dissolution kinetics was studied using the shrinking core model, based on which the process was found to follow a diffusion-controlled mechanism as the rate-determining step. The activation energy of 18.1 kJ/mol lends support to this assertion. At optimal conditions, the formation of a pure lepidolite crystal (K2Li3Al3Si7O21F3: (96-900-0834)), recommended as a precursor for preparing industrial lithium sulphate was obtained.
摘要对尼日利亚锂云母矿在硫酸溶液中的溶解进行了优化工业改造。研究了酸浓度、反应温度、粒径和反应时间对矿石溶解速率的影响程度。当酸浓度从0.1增加到1.5时,观察到这些参数提高了溶解速率 mol/L,室温的反应温度(27 ± 2°C)至75°C,粒径为63至90 µm,反应时间从5到120 min。使用缩芯模型研究了矿石溶解动力学,在此基础上发现该过程遵循扩散控制机制作为速率决定步骤。18.1的活化能 kJ/mol支持这一论断。在最佳条件下,获得了纯锂云母晶体(K2Li3Al3Si7O21F3:(96-900-834))的形成,该晶体被推荐为制备工业硫酸锂的前体。
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引用次数: 0
Combined hydrometallurgical route for recovery of metals from spent LIB using hydrochloric acid and phosphonium ionic liquid 盐酸-磷离子液体联合湿法冶金工艺回收废LIB金属
IF 1.2 Q2 Earth and Planetary Sciences Pub Date : 2023-05-22 DOI: 10.1080/25726641.2023.2214329
Archita Mohanty, B. Marandi, N. Devi
ABSTRACT This research explored the significance of Cyphos IL 101 in recovering metal values from waste LiMn2O4 batteries. Several leaching parameters were investigated to recover metals from the leach liquor of the battery material. The maximum leaching efficiency of Li (100%) and Mn (99.6%) was attained with 3.0 mol/L hydrochloric acid, 30°C, S/L ratio of 10 g/L, and 60 min leaching duration. The leaching process was diffusion-controlled. At pH 5.5, the separation of manganese and lithium exhibited excellent selectivity towards manganese over lithium using 0.1 mol/L Cyphos IL 101. 99.6% manganese extraction and negligible lithium extraction were obtained with two stages of counter-current extraction at A/O 1:1 predicted by the McCabe-Thiele plot. Using 0.1 mol/L hydrochloric acid, a stripping efficiency of 99.4% was attained for manganese.
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引用次数: 0
Removal of Pb+2 and Cd+2 from Aqueous Solution by Using Faujasite Faujasite去除水溶液中Pb+2和Cd+2的研究
IF 1.2 Q2 Earth and Planetary Sciences Pub Date : 2023-05-17 DOI: 10.11648/j.ijmpem.20230801.11
Fatma Mohamed Dardir, Ezzat Abdalla Ahmed, Mamdouh Farag Soliman, Mostafa Ragab Abukhadra
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引用次数: 0
Rate of removal of lead from copper matte by submerged gas injection 浸没式注气对铜锍中铅的去除率
IF 1.2 Q2 Earth and Planetary Sciences Pub Date : 2023-04-03 DOI: 10.1080/25726641.2023.2202004
S. Wright, Shouyi Sun, S. Jahanshahi
ABSTRACT New lead volatilisation rate and activity data in copper mattes containing low levels of Pb were determined through high-temperature experiments. Measurements on volatilisation rate of lead from mattes (Cu-Fe-S) were carried out at temperatures from 1200 to 1570°C by injection of nitrogen into shallow baths. The concentration of lead in the melts covered a range of 200–6 mg.kg−1. The rate data exhibited first order behaviour with respect to concentration of Pb. The deduced vapour pressure of Pb in the gas was found to be dependent on the concentration of the Pb in melts and in accord with the equilibrium data on mattes at similar temperatures. Increasing temperature had a strong influence on volatilisation rate and total partial pressure of Pb in the gas phase. Matte grade (45–83 wt%) does not have a strong influence on volatilisation rate, but increasing sulphur potential does have a marked impact in supressing the volatilisation rate.
通过高温实验测定了低铅铜锍中铅的挥发速率和活性。在1200 ~ 1570°C的温度范围内,通过向浅槽中注入氮气,测量了铅(Cu-Fe-S)的挥发速率。熔体中铅的浓度范围为200-6 mg.kg - 1。速率数据对铅的浓度表现为一级行为。推导出的气体中铅的蒸气压与熔体中铅的浓度有关,与相似温度下的平衡数据一致。温度升高对Pb在气相中的挥发速率和总分压有较大影响。哑光品位(45-83 wt%)对挥发率没有强烈影响,但增加硫势确实对抑制挥发率有显著影响。
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引用次数: 1
Direct copper recovery from pregnant leaching solutions (PLS), using a custom electrolytic cell, based on reactive electrodialysis (RED) 直接从浸出液(PLS)中回收铜,使用基于反应性电渗析(RED)的定制电解槽
IF 1.2 Q2 Earth and Planetary Sciences Pub Date : 2023-04-03 DOI: 10.1080/25726641.2023.2202011
José Hernández, Jaime M. Tapia
ABSTRACT This study shows the feasibility of recovering copper directly from Pregnant Leaching Solutions (PLS), using the reactive electrodialysis technique, without the need of solvent extraction. The copper PLS contained the following ion concentrations: Cu2+ 2.0–2.5 g/L; pH 1.5–1.8; 90–95 g/L; Cl− 8–10 g/L and total iron of 8–10 g/L. The copper electrowinning process is limited by the mass transport capacity of the system and by impurities that decrease the yield. To increase the selectivity and the copperproduction rate, a reactive electrodialysis (RED) cell was developed. The cell contained four compartments, two anion-exchangemembranes and a bipolar electrode to increase the production rate. This cell recovered copper and sulfuric acid at the anolytes. Thebest result was a current efficiency of 99% and specific energy consumption of 2.11 Wh/kg Cu using a current density of 80 A/m2 at 55°C and flow of 100 mL/s.
摘要:本研究展示了利用反应性电渗析技术直接从浸出液中回收铜的可行性,而无需溶剂萃取。铜PLS的离子浓度为:Cu2+ 2.0 ~ 2.5 g/L;pH值1.5 - -1.8;90 - 95 g / L;Cl−8 - 10g /L,总铁8 - 10g /L。电积铜工艺受到系统的质量传输能力和杂质降低收率的限制。为了提高反应性电渗析的选择性和产铜率,研制了反应性电渗析(RED)细胞。该电池包含四个隔间,两个阴离子交换膜和一个双极电极,以提高生产速度。该电池在阳极液中回收铜和硫酸。当电流密度为80 a /m2,温度为55℃,流速为100 mL/s时,电流效率为99%,比能耗为2.11 Wh/kg Cu。
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引用次数: 0
Formation of Pt and Pd complex oxides using lead oxide and their solubility in hydrochloric acid 用氧化铅制备Pt和Pd复合氧化物及其在盐酸中的溶解度
IF 1.2 Q2 Earth and Planetary Sciences Pub Date : 2023-04-03 DOI: 10.1080/25726641.2023.2214327
Ryoji Sanekata, T. Nagai
ABSTRACT Platinum and palladium are platinum group metals (PGMs) used in automotive catalysts. Recycling PGMs is necessary because of their low production volumes. Recycling of Pt and Pd, there is a need to develop effective methods for recovering Pt and Pd from metal based automotive catalysts and methods for acid dissolution of Pt and Pd that do not require strong oxidant. Recently, it has been shown that PGMs can be made into complex oxides, which can be dissolved in HCl without oxidant. In this study, we investigated the formation conditions of complex oxides of Pt, Pd and PbO, and their solubility in HCl. As a result, PbPt2O4 was prepared at 873–973 K, Pb2PtO4 at 873–973 K, and PbPdO2 at 773–1073 K. These complex oxides exhibited high solubility in HCl without oxidant. There were differences in solubility in Pt and Pd complex oxides.
铂和钯是用于汽车催化剂的铂族金属(PGMs)。回收PGMs是必要的,因为它们的产量低。Pt和Pd的回收利用,需要开发从金属基汽车催化剂中回收Pt和Pd的有效方法,以及不需要强氧化剂的Pt和Pd的酸溶方法。最近有研究表明,PGMs可以制成复合氧化物,无需氧化剂即可溶解于HCl中。在本研究中,我们研究了Pt, Pd和PbO的复合氧化物的形成条件及其在HCl中的溶解度。结果表明,PbPt2O4、Pb2PtO4和PbPdO2分别在873 ~ 973 K、873 ~ 973 K和773 ~ 1073 K下制备。这些复合氧化物在无氧化剂的HCl中具有较高的溶解度。在铂和钯络合物氧化物中的溶解度存在差异。
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引用次数: 0
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Mineral Processing and Extractive Metallurgy-Transactions of the Institutions of Mining and Metallurgy
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